dynamic viscosity function from dynamic modulus measurement. In the latter case,
correctly interpreting results is still an active research subject but relatively simple
modeling approaches can be used to offer in a glance an overall view of the
viscoelastic properties of interest for processing and applications.
References
1. Tschoegl NW (1989) The phenomenological theory of linear viscoelastic behavior. Springer,
Berlin. ISBN 3-540619173-9
2. Ferry JD (1980) Viscoelastic properties of polymers, 3rd ed.. Wiley, New York. ISBN
0-471-04894-1
3. Tanaka Y (2001) Structural characterization of natural polyisoprenes: solve the mystery of
Natural Rubber based on structural study. Rubb Chem Technol 74:355–375
4. Leblanc JL (2004) Dynamic testing of intrinsically nonlinear viscoelastic materials – D.I.K.,
Kautschuk-Herbst-Kolloquium 2004 – Hannover, November 11–13, 2004 – Proceedings, pp
19À29
5. Leblanc JL (2008) Large amplitude oscillatory shear experiments to investigate the nonlinear
viscoelastic properties of highly loaded carbon black rubber compounds without curatives.
J Appl Polym Sci 109:1271–1293
6. Macosko CW (1994) Rheology: Principles, measurements and applications. VCH Publishers,
Inc., New York. ISBN 1-56081-579-5
7. Collyer AA. In Clegg DW (Ed) (1998) Rheological measurement, 2nd ed. Chapman & Hall,
London. ISBN 0 412 720302 2
8. Middleman S (1969) Transient response of an elastomer to large shearing and stretching
seformations. Trans Soc Rheol 13:123–139
9. Furuta I, Lobe VM, White JL (1976) Experimental study of the rheological properties of
butadiene-styrene gum elastomers and compounds. J Non-Newtonian Fluid Mech 1:207–222
10. Goldstein C (1974) Transient and steady shear behavior of SBR polymers. Trans Soc Rheol
18:357–369
11. Barre `s C, Leblanc JL (2000) Recent developments in shear rheometry of uncured rubber
compounds. I. Design, construction and validation of a sliding cylinder rheometer. Polym
Testing 19:177–191
12. Barre `s C, Leblanc JL, Guilet S (2001) Recent developments in shear rheometry of uncured
rubber compounds. I. Use of the sliding cylinder rheometer to probe sample anisotropy. Polym
Testing 20:329–338
13. Toki S, White JL (1982) Rheological and solid wall boundary condition characterization of
unvulcanized elastomers and their compounds. J Appl Polym Sci 27:3171–3184
14. Leblanc JL (2007) Non-linear viscoelastic characterization of natural rubber gum through
large amplitude harmonic experiments. J Rubb Res 10(2):63–88
15. Giacomin AJ, Dealy JM (1998) Using large-amplitude oscillatory shear, Chapter 11, 327–356
(1998). In: Collyer AA, Clegg DW (eds) Rheological measurements, 2nd edn. Kluwer
Academic Publishers, Dordrecht, Netherlands
16. Atalik K, Keunings R (2004) On the occurrence of even harmonics in the shear response of
viscoelastic fluids in large amplitude oscillatory shear. J Non-Newtonian Fluid Mech
122:107–116
17. Klein OC, Spiess HW, Calin A, Balan C, Wilhelm M (2007) Separation of the nonlinear
oscillatory response into a superposition of linear, strain hardening, strain softening, and wall
slip responses. Macromolecules 40:4250–4259
18. Montes S, White JL (1982) A comparative rheological investigation of natural and synthetic
cis-1,4 polyisoprenes and their Carbon Black compounds. Rubb Chem Technol 55:1354–1369
A Multiparametric Approach of the Nonlinear Viscoelasticity of Rubber Materials
299
correctly interpreting results is still an active research subject but relatively simple
modeling approaches can be used to offer in a glance an overall view of the
viscoelastic properties of interest for processing and applications.
References
1. Tschoegl NW (1989) The phenomenological theory of linear viscoelastic behavior. Springer,
Berlin. ISBN 3-540619173-9
2. Ferry JD (1980) Viscoelastic properties of polymers, 3rd ed.. Wiley, New York. ISBN
0-471-04894-1
3. Tanaka Y (2001) Structural characterization of natural polyisoprenes: solve the mystery of
Natural Rubber based on structural study. Rubb Chem Technol 74:355–375
4. Leblanc JL (2004) Dynamic testing of intrinsically nonlinear viscoelastic materials – D.I.K.,
Kautschuk-Herbst-Kolloquium 2004 – Hannover, November 11–13, 2004 – Proceedings, pp
19À29
5. Leblanc JL (2008) Large amplitude oscillatory shear experiments to investigate the nonlinear
viscoelastic properties of highly loaded carbon black rubber compounds without curatives.
J Appl Polym Sci 109:1271–1293
6. Macosko CW (1994) Rheology: Principles, measurements and applications. VCH Publishers,
Inc., New York. ISBN 1-56081-579-5
7. Collyer AA. In Clegg DW (Ed) (1998) Rheological measurement, 2nd ed. Chapman & Hall,
London. ISBN 0 412 720302 2
8. Middleman S (1969) Transient response of an elastomer to large shearing and stretching
seformations. Trans Soc Rheol 13:123–139
9. Furuta I, Lobe VM, White JL (1976) Experimental study of the rheological properties of
butadiene-styrene gum elastomers and compounds. J Non-Newtonian Fluid Mech 1:207–222
10. Goldstein C (1974) Transient and steady shear behavior of SBR polymers. Trans Soc Rheol
18:357–369
11. Barre `s C, Leblanc JL (2000) Recent developments in shear rheometry of uncured rubber
compounds. I. Design, construction and validation of a sliding cylinder rheometer. Polym
Testing 19:177–191
12. Barre `s C, Leblanc JL, Guilet S (2001) Recent developments in shear rheometry of uncured
rubber compounds. I. Use of the sliding cylinder rheometer to probe sample anisotropy. Polym
Testing 20:329–338
13. Toki S, White JL (1982) Rheological and solid wall boundary condition characterization of
unvulcanized elastomers and their compounds. J Appl Polym Sci 27:3171–3184
14. Leblanc JL (2007) Non-linear viscoelastic characterization of natural rubber gum through
large amplitude harmonic experiments. J Rubb Res 10(2):63–88
15. Giacomin AJ, Dealy JM (1998) Using large-amplitude oscillatory shear, Chapter 11, 327–356
(1998). In: Collyer AA, Clegg DW (eds) Rheological measurements, 2nd edn. Kluwer
Academic Publishers, Dordrecht, Netherlands
16. Atalik K, Keunings R (2004) On the occurrence of even harmonics in the shear response of
viscoelastic fluids in large amplitude oscillatory shear. J Non-Newtonian Fluid Mech
122:107–116
17. Klein OC, Spiess HW, Calin A, Balan C, Wilhelm M (2007) Separation of the nonlinear
oscillatory response into a superposition of linear, strain hardening, strain softening, and wall
slip responses. Macromolecules 40:4250–4259
18. Montes S, White JL (1982) A comparative rheological investigation of natural and synthetic
cis-1,4 polyisoprenes and their Carbon Black compounds. Rubb Chem Technol 55:1354–1369
A Multiparametric Approach of the Nonlinear Viscoelasticity of Rubber Materials
299