2-Hydroxyethylmethacrylate + vinyl-phenyl-boronic acid + oligoethylene glycol
dimethacrylate
Water
APS + TMEDA
À12
Preparation of affinity matrix for
the boronate affinity
chromatography
[158]
N-Vinyl-caprolactam + oligoethylene glycol diacrylate
Water/dimethylsulfoxide
mixtures
APS + TMEDA
À12
Preparation of temperatureresponsive cryogels, study of
their properties and the wide
pore morphology
[159]
II. Initiation with radiation
2-Hydroxyethylmethacrylate
Water
γ-rays
À24 to
À196 Preparation of carriers for the
immobilization of enzymes
and cells, study of the
properties and morphology
of resulting cryogels as
dependent on the cryopoly
merization conditions
[93–98,
160,
161]
2-Hydroxyethylmethacrylate + acrolein
Water
γ-rays
À14 to
À78 Preparation of aldehyde-bearing
carriers for the immobilization of proteins
[99, 162]
2-Hydroxyethylmethacrylate +
N-vinyl-pyrrolidone
Water
γ-rays
À78
Preparation of polymeric carriers
for the immobilization of
cells
[163]
2-Hydroxyethylmethacrylate + glycidyl
methacrylate
Water
γ-rays
À78
Preparation of epoxide-bearing
carriers for the immobilization of enzymes
[164]
Diacrylates or dimethacrylates of
oligoethylene glycols
Water
γ-rays
À78
Preparation and study of physicochemical properties and
macroporous morphology of
respective cryogels
[95, 165]
Methoxyoligoethylene glycol methacrylates Water
γ-rays
À78
Preparation of polymeric carriers
for the immobilization of
cells, study of properties and
porosity of the resulting
cryogels
[166, 167]
(continued)
A Brief History of Polymeric Cryogels
13