Index
A
(–)-A26771B, 389, 390
Acetylaranotin, 316
Acortatarin A
Pd-catalyzed spirocyclization approach,
203–205
Sudhakar synthesis, 199
Tan synthesis, 214
(+)-Acutiphycin, 386
Acylketenes, intramolecular capture
dioxolenone, 386–387
macrocyclic lactones
14-member, 388
15-member, 389
16-member, 389–390
Ag-catalyzed cyclization, 215
Aldol reaction, 156, 169
Alduronic acid lactones, 134, 135
Aliphatic spiroacetals
cephalosporolides E and F, 193
iron(0)-tricarbonyl diene complex, 196
spirofungin A, 193, 194
spongistatin-1, 194, 195
Alkene-mediated cyclizations,
tetrahydropyrans
bryostatins, 56, 57
leucascandrolide A, 56–58
phorboxazoles, 57–59
stereochemical outcomes, 56, 57
Alkyl alkynyl ethers, ketene source
description, 385–386
16-membered macrocyclic lactones, 386
Alkyne-Prins cyclization, 13
Amphidinolide J, 404–405
(–)-Amphidinolide P, 389, 390
Anionic cyclization, 298–300
Anomeric conformers, 190
Antibiotics, 146
Anti-tumor activity, 144–145
Aplysiatoxin, 417
Aryl C-glycosides, 6, 7
3-Aryl-δ-lactones, 108–109
Aspergillide A and B, 394
Asymmetric total synthesis, 154, 156, 157
Avermectins, 411, 412
Aza-C-disaccharide, 180–182
B
Banyaside, 176, 177
Berkelic acid
Ag(I)-catalyzed HDA cascade approach,
240, 242
Ag(I)-initiated bio-inspired synthesis,
241, 243
formal synthesis, 208
oxa-Michael initiated cascade approaches,
230, 231
Bicyclic ketone, 148
Bicyclo[4.1.0] heptanes, cyclopropanation
and ring opening, 284–279
Bis(benzannulated) spiroacetals
Ir/SpinPHOX catalysts, 200, 201
paecilospirone, 199, 200
purpuromycin, 202, 203
spirocyclization, 201, 203
(+)-Brefeldin C, 397–398, 420, 421
Brevetoxin A, 329, 334
C
(–)-Callipeltoside A, 388
Cantharidin, 144–145
Caprolactone, enol phosphate, 316–317
J. Cossy (ed.), Synthesis of Saturated Oxygenated Heterocycles II, Topics in
Heterocyclic Chemistry 36, DOI 10.1007/978-3-642-41470-1,
© Springer-Verlag Berlin Heidelberg 2014
429
A
(–)-A26771B, 389, 390
Acetylaranotin, 316
Acortatarin A
Pd-catalyzed spirocyclization approach,
203–205
Sudhakar synthesis, 199
Tan synthesis, 214
(+)-Acutiphycin, 386
Acylketenes, intramolecular capture
dioxolenone, 386–387
macrocyclic lactones
14-member, 388
15-member, 389
16-member, 389–390
Ag-catalyzed cyclization, 215
Aldol reaction, 156, 169
Alduronic acid lactones, 134, 135
Aliphatic spiroacetals
cephalosporolides E and F, 193
iron(0)-tricarbonyl diene complex, 196
spirofungin A, 193, 194
spongistatin-1, 194, 195
Alkene-mediated cyclizations,
tetrahydropyrans
bryostatins, 56, 57
leucascandrolide A, 56–58
phorboxazoles, 57–59
stereochemical outcomes, 56, 57
Alkyl alkynyl ethers, ketene source
description, 385–386
16-membered macrocyclic lactones, 386
Alkyne-Prins cyclization, 13
Amphidinolide J, 404–405
(–)-Amphidinolide P, 389, 390
Anionic cyclization, 298–300
Anomeric conformers, 190
Antibiotics, 146
Anti-tumor activity, 144–145
Aplysiatoxin, 417
Aryl C-glycosides, 6, 7
3-Aryl-δ-lactones, 108–109
Aspergillide A and B, 394
Asymmetric total synthesis, 154, 156, 157
Avermectins, 411, 412
Aza-C-disaccharide, 180–182
B
Banyaside, 176, 177
Berkelic acid
Ag(I)-catalyzed HDA cascade approach,
240, 242
Ag(I)-initiated bio-inspired synthesis,
241, 243
formal synthesis, 208
oxa-Michael initiated cascade approaches,
230, 231
Bicyclic ketone, 148
Bicyclo[4.1.0] heptanes, cyclopropanation
and ring opening, 284–279
Bis(benzannulated) spiroacetals
Ir/SpinPHOX catalysts, 200, 201
paecilospirone, 199, 200
purpuromycin, 202, 203
spirocyclization, 201, 203
(+)-Brefeldin C, 397–398, 420, 421
Brevetoxin A, 329, 334
C
(–)-Callipeltoside A, 388
Cantharidin, 144–145
Caprolactone, enol phosphate, 316–317
J. Cossy (ed.), Synthesis of Saturated Oxygenated Heterocycles II, Topics in
Heterocyclic Chemistry 36, DOI 10.1007/978-3-642-41470-1,
© Springer-Verlag Berlin Heidelberg 2014
429