9.3 Electrochemically Assisted Synthesis of Miscellaneous …
317
Fig. 9.4 ZnO particles synthesized from various media by the electrochemically assisted precipitation method. SEM images: solvent is a ethanol, b water–ethanol mixture (7:3), and c water.
d TEM image of a particle synthesized in the water–ethanol mixture, revealing the internal spherical subgrains of the rombohedral particle. Reprinted from [61]. Copyright (2017), with permission
from Elsevier
particle diameter that undergoes a transformation with time and larger nanoparticles
and nanorods are formed with 30 diameter and 100 length. The application of more
dilute thioglycerol solution (0.01 M) leads directly to the spherical particles with a
diameter of about 50 nm and a crystalline form corresponding to a covellite-type
hexagonal phase.
References
1. Rodríguez-Sánchez L, Blanco MC, López-Quintela MA (2000) J Phys Chem B 104:9683–9688
2. Rodríguez-Sánchez ML, Rodríguez MJ, Blanco MC, Rivas J, López-Quintela MA (2005) J
Phys Chem B 109:1183–1191
3. Vilar-Vidal N, Blanco MC, López-Quintela MA, Rivas J, Serra C (2010) J Phys Chem C
114:15924–15930
4. Reetz MT, Helbig W (1994) J Am Chem Soc 116:7401–7402
5. Yu YY, Chang SS, Lee CL, Wang CRC (1997) J Phys Chem B 101:6661–6664
6. Huang CJ, Chiu PH, Wang JH, Chen KL, Linn JJ, Yang CF (2006) J Electrochem Soc
153:D193–D198
317
Fig. 9.4 ZnO particles synthesized from various media by the electrochemically assisted precipitation method. SEM images: solvent is a ethanol, b water–ethanol mixture (7:3), and c water.
d TEM image of a particle synthesized in the water–ethanol mixture, revealing the internal spherical subgrains of the rombohedral particle. Reprinted from [61]. Copyright (2017), with permission
from Elsevier
particle diameter that undergoes a transformation with time and larger nanoparticles
and nanorods are formed with 30 diameter and 100 length. The application of more
dilute thioglycerol solution (0.01 M) leads directly to the spherical particles with a
diameter of about 50 nm and a crystalline form corresponding to a covellite-type
hexagonal phase.
References
1. Rodríguez-Sánchez L, Blanco MC, López-Quintela MA (2000) J Phys Chem B 104:9683–9688
2. Rodríguez-Sánchez ML, Rodríguez MJ, Blanco MC, Rivas J, López-Quintela MA (2005) J
Phys Chem B 109:1183–1191
3. Vilar-Vidal N, Blanco MC, López-Quintela MA, Rivas J, Serra C (2010) J Phys Chem C
114:15924–15930
4. Reetz MT, Helbig W (1994) J Am Chem Soc 116:7401–7402
5. Yu YY, Chang SS, Lee CL, Wang CRC (1997) J Phys Chem B 101:6661–6664
6. Huang CJ, Chiu PH, Wang JH, Chen KL, Linn JJ, Yang CF (2006) J Electrochem Soc
153:D193–D198