42
H. Zhu et al.
Table 12 [5.6.11]-Chaetoglobosins
Compound
Origin
References
Cytochalasin G (322)
Nigrosabulum sp. (CMI 171,019)
[149]
Cytochalasin X (323)
Pseudeurotium zonatum
[150]
Cytochalasin Y (324)
Pseudeurotium zonatum
[150]
Cytochalasin Z (325)
Pseudeurotium zonatum
[150]
Table 13 Seco- and other chaetoglobosins
Compound
Origin
References
Armochaetoglobin A (326)
Chaetomium globosum TW1-1
[124]
Armochaetoglobin B (327)
Chaetomium globosum TW1-1
[124]
Armochaetoglobin C (328)
Chaetomium globosum TW1-1
[124]
Armochaetoglobin D (329)
Chaetomium globosum TW1-1
[124]
Armochaetoglobin E (330)
Chaetomium globosum TW1-1
[124]
Armochaetoglasin B (331)
Chaetomium globosum TW1-1
[10]
Armochaetoglasin C (332)
Chaetomium globosum TW1-1
[10]
Yamchaetoglobosin A (333)
Chaetomium globosum YNH-16
[151]
Table 14 Mero-chaetoglobosins
Compound
Origin
References
MBJ-0038 (334)
Chaetomium sp. f24230
[152]
MBJ-0039 (335)
Chaetomium sp. f24230
[152]
MBJ-0040 (336)
Chaetomium sp. f24230
[152]
Cytochathiazine A (337)
coculture of Aspergillus flavipes and
Chaetomium globosum
[154]
Cytochathiazine B (338)
coculture of Aspergillus flavipes and
Chaetomium globosum
[154]
Cytochathiazine C (339)
coculture of Aspergillus flavipes and
Chaetomium globosum
[154]
Aureochaeglobosin A (340)
Chaetomium globosum
[153]
Aureochaeglobosin B (341)
Chaetomium globosum
[153]
Aureochaeglobosin C (342)
Chaetomium globosum
[153]
and their planar structures were determined mainly through chemical reactions. In
1976, Silverton and coworkers [104] completed the first X-ray diffraction analysis of
chaetoglobosin A (210) and determined its relative configuration, and further X-ray
analysis by the same group in 1978 confirmed its absolute configuration [105]. After
that, a series of chaetoglobosins have been elucidated [106–109], and biosynthesis
studies on these compounds were also carried out [109].