171
Table 8.1 Structure of the flammability retardant (FR) used, phosphorus percentage in polymer
and flammability results
Type of epoxy resin
Structure of FR
Phosphorus
wt. (%)
LOI UL94 References
4,4′-diaminodiphenyl
sulfone-cured DGEBA
(DDS-DGEBA)
2.49
30 V-0
Wang and
Lin (1999,
2001)
DDS-DGEBA
2.4
32 V-0
Wang and
Lee (2000)
DDS-cured 2,7-diglycidyloxynaphthalene (DDS-N2)
2.6
33 V-0
Wang and
Lee (2000)
DDS-cured 1,1′-bis
(2,7-diglycidyloxy-1-naphthyl)
methane (DDS-N4)
1.4
35 V-0
Wang and
Lee (2000)
DDS-DGEBA
1.7
–
V-0
Lin et al.
(2000)
DDS/9,10-dihydro-9-oxa-10phosphaphenanthrene 10-oxide
+ itaconic acid-cured DGEBA
(DGEBA-DDS/DOPOITA)
1.73
–
V-0
Lin et al.
(2000)
o-cresol formaldehyde novolac
epoxy resin (CNE) cured with
DDS (CNE-DDS)
3.63
33 V-0
Wang and
Lin (2001)
Dicyandiamide-cured CNE
(CNE-DICY)
1.86
34 V-0
Wang and
Lin (2001)
3.83
38 V-0
Diglycidylether bisphenol-A
10-phosphaphenanthrene-10oxide +4-hydroxyl
benzoaldehyde
(BE188-DOPO-PN)
5.20
34 V-0
Liu (2001)
(continued)
8 Flame Retardancy of Reactive and Functional Polymers
Table 8.1 Structure of the flammability retardant (FR) used, phosphorus percentage in polymer
and flammability results
Type of epoxy resin
Structure of FR
Phosphorus
wt. (%)
LOI UL94 References
4,4′-diaminodiphenyl
sulfone-cured DGEBA
(DDS-DGEBA)
2.49
30 V-0
Wang and
Lin (1999,
2001)
DDS-DGEBA
2.4
32 V-0
Wang and
Lee (2000)
DDS-cured 2,7-diglycidyloxynaphthalene (DDS-N2)
2.6
33 V-0
Wang and
Lee (2000)
DDS-cured 1,1′-bis
(2,7-diglycidyloxy-1-naphthyl)
methane (DDS-N4)
1.4
35 V-0
Wang and
Lee (2000)
DDS-DGEBA
1.7
–
V-0
Lin et al.
(2000)
DDS/9,10-dihydro-9-oxa-10phosphaphenanthrene 10-oxide
+ itaconic acid-cured DGEBA
(DGEBA-DDS/DOPOITA)
1.73
–
V-0
Lin et al.
(2000)
o-cresol formaldehyde novolac
epoxy resin (CNE) cured with
DDS (CNE-DDS)
3.63
33 V-0
Wang and
Lin (2001)
Dicyandiamide-cured CNE
(CNE-DICY)
1.86
34 V-0
Wang and
Lin (2001)
3.83
38 V-0
Diglycidylether bisphenol-A
10-phosphaphenanthrene-10oxide +4-hydroxyl
benzoaldehyde
(BE188-DOPO-PN)
5.20
34 V-0
Liu (2001)
(continued)
8 Flame Retardancy of Reactive and Functional Polymers
