46
A. S. Kazemi and M. A. Abdol
An ideal membrane combines high water permeability and high selectivity. This
combination has proven difficult to accomplish and therefore referred as permeability–selectivity trade-off [66, 67]. Investigations on novel active layers for desalination membranes pursue to improve the water permeability and water–solute selectivity [15]. Process modeling for seawater RO desalination shows that increased
water permeability above currently achievable levels (2–3 Lm
−2 h
−1 bar
−1 ); would
negligibly decrease energy requirements and capital costs [68, 69], opposing the
previous claim of Cohen-Tanugi and Grossman [68]. Such a conflict, irrespective of
the membrane permeability, is mainly due to current RO system designs that desalinate seawater using a single membrane stage fed by a high-pressure pump [14, 19].
Note that the use of hydraulic pressure is the main element of the energy consumption by the RO stage. Therefore, instead of realizing higher water permeability, a
more effective goal for novel desalination membrane materials research would be to
achieve improved selectivity for water over all dissolved solutes [15].
2.2 Modules for Current RO Membrane Testing
A typical RO set-up has a simple layout, consisting of feed water input, feed
pre-treatment unit, high-pressure pump, modules for the RO membrane and, in
some configurations, post-treatment stages [70]. There are four different types of
RO membrane modules that are used for desalination processes: plate and frame,
tubular, hollow fiber and spiral-wound [1]. Figure 1 shows the schematics of these
modules. Plate-and-frame is an old RO module made up of layers of supported plane
Fig. 1 Schematics of a plate and frame, b tubular, c, d hollow fiber and e, f spiral-wound modules
used for water treatments. d and f are reproduced with permission from [78]. Copyright © 2012
Elsevier Inc
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