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G.-R. Xu
74. Clough AJ, Skelton JM, Downes CA, Rosa AA, Yoo JW, Walsh A, Melot BC, Marinescu SC
(2017) Metallic conductivity in a two-dimensional cobalt dithiolene metal-organic framework.
J. Am. Chem. Soc. 139:10863–10867
75. Clough AJ, Yoo JW, Mecklenburg MH, Marinescu SC (2015) Two-dimensional metal-organic
surfaces for efficient hydrogen evolution from water. J. Am. Chem. Soc. 137:118–121
76. Zhao M, Huang Y, Peng Y, Huang Z, Ma Q, Zhang H (2018) Two-dimensional metal-organic
framework nanosheets: synthesis and applications. Chem. Soc. Rev. 47:6267–6295
77. Zhao M, Wang Y, Ma Q, Huang Y, Zhang X, Ping J, Zhang Z, Lu Q, Yu Y, Xu H (2015)
Ultrathin 2D metal-organic framework nanosheets. Adv. Mater. 27:7372–7378
78. Hermes S, Witte T, Hikov T, Zacher D, Bahnmüller S, Langstein G, Huber K, Fischer
RA (2007) Trapping metal-organic framework nanocrystals: an in-situ time-resolved light
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79. Tsuruoka T, Furukawa S, Takashima Y, Yoshida K, Isoda S, Kitagawa S (2009) Nanoporous
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80. Dmitriev A, Spillmann H, Lin N, Barth JV, Kern K (2003) Modular assembly of twodimensional metal-organic coordination networks at a metal surface. Angew. Chem. Int. Ed.
115:2774–2777
81. Wurster B, Grumelli D, Hötger D, Gutzler R, Kern K (2016) Driving the oxygen evolution
reaction by nonlinear cooperativity in bimetallic coordination catalysts. J. Am. Chem. Soc.
138:3623–3626
82. Zhu QL, Xu Q (2014) Metal-organic framework composites. Chem. Soc. Rev. 3:5468–5512
83. Zhan G, Zeng HC (2016) Synthesis and functionalization of oriented metal–organicframework nanosheets: toward a series of 2D catalysts. Adv. Funct. Mater. 26:3268–3281
84. Lu Q, Zhao M, Chen J, Chen B, Tan C, Zhang X, Huang Y, Yang J, Cao F, Yu Y (2006) In situ
synthesis of metal sulfide nanoparticles based on 2D metal-organic framework nanosheets.
Small 12:4669–4674
85. Kumar R, Jayaramulu K, Maji TK, Rao CNR (2014) Growth of 2D sheets of a MOF on
graphene surfaces to yield composites with novel gas adsorption characteristics. Dalton T
43:7383–7386
86. Roth WJ, Nachtigall P, Morris RE, Cejka J (2014) Two-dimensional zeolites: current status
and perspectives. Chem. Rev. 114:4807–4837
87. Luo Y, Wang Z, Jin S, Zhang B, Sun H, Yuan X, Yang W (2016) Synthesis and crystal growth
mechanism of ZSM-22 zeolite nanosheets. Cryst. Eng. Comm. 18:5611–5615
88. Chen HL, Li SW, Wang YM (2015) Synthesis and catalytic properties of multilayered MELtype titanosilicate nanosheets. J. Mater. Chem. A 3:5889–5990
89. Choi M, Na K, Kim J, Sakamoto Y, Terasaki O, Ryoo R (2009) Stable single-unit-cell
nanosheets of zeolite MFI as active and long-lived catalysts. Nature 461:246–249
90. Ren L, Guo Q, Kumar P, Orazov M, Xu D, Alhassan SM, Mkhoyan KA, Davis ME, Tsapatsis
M (2015) Self-pillared, single-unit-cell sn-mfi zeolite nanosheets and their use for glucose
and lactose isomerization. Angew Chem Int Ed 54:10848–10851
91. Hu S, Shan J, Zhang Q, Wang Y, Liu Y, Gong Y, Wu Z, Dou T (2012) Selective formation
of propylene from methanol over high-silica nanosheets of MFI zeolite. Appl. Catal. A.
445:215–220
92. Na K, Jo C, Kim J, Ahn WS, Ryoo R (2011) MFI titanosilicate nanosheets with single-unit-cell
thickness as an oxidation catalyst using peroxides. ACS Catal. 1:901–907
93. Varoon K, Zhang X, Elyassi B, Brewer DD, Gettel M, Kumar S, Lee JA, Maheshwari S,
Mittal A, Sung CY (2011) Dispersible exfoliated zeolite nanosheets and their application as
a selective membrane. Science 334:72–75
94. Kumar P, Agrawal KV, Tsapatsis M, Mkhoyan KA (2015) Quantification of thickness and
wrinkling of exfoliated two-dimensional zeolite nanosheets. Nat. Commun. 6:7128
95. Zhu B, Li B, Zou L, Hill AJ, Zhao D, Lin JY, Duke M (2013) Wiley Online Library
96. Jeon MY, Kim D, Kumar P, Lee PS, Rangnekar N, Bai P, Shete M, Elyassi B, Lee HS,
Narasimharao K (2017) Ultra-selective high-flux membranes from directly synthesized zeolite
nanosheets. Nature 543:690–694
G.-R. Xu
74. Clough AJ, Skelton JM, Downes CA, Rosa AA, Yoo JW, Walsh A, Melot BC, Marinescu SC
(2017) Metallic conductivity in a two-dimensional cobalt dithiolene metal-organic framework.
J. Am. Chem. Soc. 139:10863–10867
75. Clough AJ, Yoo JW, Mecklenburg MH, Marinescu SC (2015) Two-dimensional metal-organic
surfaces for efficient hydrogen evolution from water. J. Am. Chem. Soc. 137:118–121
76. Zhao M, Huang Y, Peng Y, Huang Z, Ma Q, Zhang H (2018) Two-dimensional metal-organic
framework nanosheets: synthesis and applications. Chem. Soc. Rev. 47:6267–6295
77. Zhao M, Wang Y, Ma Q, Huang Y, Zhang X, Ping J, Zhang Z, Lu Q, Yu Y, Xu H (2015)
Ultrathin 2D metal-organic framework nanosheets. Adv. Mater. 27:7372–7378
78. Hermes S, Witte T, Hikov T, Zacher D, Bahnmüller S, Langstein G, Huber K, Fischer
RA (2007) Trapping metal-organic framework nanocrystals: an in-situ time-resolved light
scattering study on the crystal growth of mof-5 in solution. J. Am. Chem. Soc. 129:5324–5325
79. Tsuruoka T, Furukawa S, Takashima Y, Yoshida K, Isoda S, Kitagawa S (2009) Nanoporous
nanorods fabricated by coordination modulation and oriented attachment growth. Angew.
Chem. Int. Ed. 48:4739–4743
80. Dmitriev A, Spillmann H, Lin N, Barth JV, Kern K (2003) Modular assembly of twodimensional metal-organic coordination networks at a metal surface. Angew. Chem. Int. Ed.
115:2774–2777
81. Wurster B, Grumelli D, Hötger D, Gutzler R, Kern K (2016) Driving the oxygen evolution
reaction by nonlinear cooperativity in bimetallic coordination catalysts. J. Am. Chem. Soc.
138:3623–3626
82. Zhu QL, Xu Q (2014) Metal-organic framework composites. Chem. Soc. Rev. 3:5468–5512
83. Zhan G, Zeng HC (2016) Synthesis and functionalization of oriented metal–organicframework nanosheets: toward a series of 2D catalysts. Adv. Funct. Mater. 26:3268–3281
84. Lu Q, Zhao M, Chen J, Chen B, Tan C, Zhang X, Huang Y, Yang J, Cao F, Yu Y (2006) In situ
synthesis of metal sulfide nanoparticles based on 2D metal-organic framework nanosheets.
Small 12:4669–4674
85. Kumar R, Jayaramulu K, Maji TK, Rao CNR (2014) Growth of 2D sheets of a MOF on
graphene surfaces to yield composites with novel gas adsorption characteristics. Dalton T
43:7383–7386
86. Roth WJ, Nachtigall P, Morris RE, Cejka J (2014) Two-dimensional zeolites: current status
and perspectives. Chem. Rev. 114:4807–4837
87. Luo Y, Wang Z, Jin S, Zhang B, Sun H, Yuan X, Yang W (2016) Synthesis and crystal growth
mechanism of ZSM-22 zeolite nanosheets. Cryst. Eng. Comm. 18:5611–5615
88. Chen HL, Li SW, Wang YM (2015) Synthesis and catalytic properties of multilayered MELtype titanosilicate nanosheets. J. Mater. Chem. A 3:5889–5990
89. Choi M, Na K, Kim J, Sakamoto Y, Terasaki O, Ryoo R (2009) Stable single-unit-cell
nanosheets of zeolite MFI as active and long-lived catalysts. Nature 461:246–249
90. Ren L, Guo Q, Kumar P, Orazov M, Xu D, Alhassan SM, Mkhoyan KA, Davis ME, Tsapatsis
M (2015) Self-pillared, single-unit-cell sn-mfi zeolite nanosheets and their use for glucose
and lactose isomerization. Angew Chem Int Ed 54:10848–10851
91. Hu S, Shan J, Zhang Q, Wang Y, Liu Y, Gong Y, Wu Z, Dou T (2012) Selective formation
of propylene from methanol over high-silica nanosheets of MFI zeolite. Appl. Catal. A.
445:215–220
92. Na K, Jo C, Kim J, Ahn WS, Ryoo R (2011) MFI titanosilicate nanosheets with single-unit-cell
thickness as an oxidation catalyst using peroxides. ACS Catal. 1:901–907
93. Varoon K, Zhang X, Elyassi B, Brewer DD, Gettel M, Kumar S, Lee JA, Maheshwari S,
Mittal A, Sung CY (2011) Dispersible exfoliated zeolite nanosheets and their application as
a selective membrane. Science 334:72–75
94. Kumar P, Agrawal KV, Tsapatsis M, Mkhoyan KA (2015) Quantification of thickness and
wrinkling of exfoliated two-dimensional zeolite nanosheets. Nat. Commun. 6:7128
95. Zhu B, Li B, Zou L, Hill AJ, Zhao D, Lin JY, Duke M (2013) Wiley Online Library
96. Jeon MY, Kim D, Kumar P, Lee PS, Rangnekar N, Bai P, Shete M, Elyassi B, Lee HS,
Narasimharao K (2017) Ultra-selective high-flux membranes from directly synthesized zeolite
nanosheets. Nature 543:690–694