Structure and Properties of Polyaniline Micro- and Nano …
521
the SEM images, which suggests the formation of chemical compounds. Consequently, the metal fragment is included in the polymer chain or covalently, or in
coordination with the polymer ligands (Pt, Pd). Part of the metal enters the composite
in the form of nanoparticles (Au, Ag) uniformly distributed in the polymer matrix.
Depending on the nature of the inclusion of the metal in the polymer matrix, and the
metal center affects both the type of bond and the degree of polymerization.
References
1. Arancis R, Joy N, Aparna P, Vijayan R (2014) Polymer grafted inorganic nanoparticles,
preparation, properties, and applications: a Review. Polym Rev 54:268–347
2. Erokhin V, Ram MK, Yavuz Ö (2008) The new frontiers of organic and composite
nanotechnology. Elsevier, Amsterdam, Boston
3. Hu C-W, Yamada Y, Yoshimura K (2017) A new type of gasochromic material: conducting
polymers with catalytic nanoparticles. Chem Commun 53(22):3242–3245
4. Kumar CSSR (eds) (2007) Nanomaterials for medical diagnosis and therapy. Nanotechnologies
for the life sciences, vol 10. Wiley-VCH Verlag GmbH
5. Olenych IB, Aksimentyeva OI, Tsizh B, Horbenko Yu (2018) Transport and relaxation of
charge in organic-inorganic nanocomposites. Acta Phys Pol, A 133(4):851–855
6. Pandey S (2016) Highly sensitive and selective chemiresistor gas/vapor sensors based on
polyaniline nanocomposite: a comprehensive review. J Sci Adv Mater Devices 1:431–453
7. Dong X, Zhang X, Wu X, Cui H, Chen D (2016) Investigation of gas-sensing property of
acid-deposited polyaniline thin-film sensors for detecting H 2 S and SO 2 . Sensors 16:1888–2003
8. Aksimentyeva OI, Savchyn VP, Dyakonov VP, Piechota S, Horbenko YY, Opainych IY (2014)
Modification of polymer-magnetic nanoparticles by luminescent and conducting substances.
Mol Cryst Liq Cryst 590:35–42
9. Reshenhyak O, Zaitcev V (eds) (2017) Computational and experimental analysis of functional
materials. Apple Academic Press, Toronto
10. Sudha JD, Sivakala S, Prasanth R et al (2009) Development of electromagnetic shielding
materials from the conductive blends of polyaniline and polyaniline-clay nanocomposite-EVA:
preparation and properties. Compos Sci Technol 69:358–364
11. Stejskal J, Gilbert RG (2002) Polyaniline. Preparation of a conducting polymer. Pure Appl
Chem 74:857–867
12. Chiang JC, Mac Diarmid AG (1986) Polyaniline: protonic acid doping of the emeraldine form
to the metallic regime. Synth Met 13:193–205
13. Stejskal J, Exnerova M, Moravkova Z et al (2012) Oxidative stability of polyaniline. Polym
Degrad Stab 97:1026–1033
14. Le T-H, Kim Y, Yoon H (2017) Electrical and electrochemical properties of conducting
polymers. Polymers 9(4):150
15. Posudievsky OY, Kurys YI, Pokhodenko VD (2004) 2-Phosphormolibdic acid doped
polyaniline-V 2 O 5 composite. Synth Metals 144:107–111
16. Mallick K, Witcomb MJ, Dinsmore A et al (2005) Polymerization of aniline by auric acid:
formation of gold decorated polyaniline nanoballs. Macromol Rapid Commun 26:232–235
17. Huang K, Zhang Y, Huang K, Long Y et al (2006) Preparation of highly conductive, selfassembled gold/polyaniline nanocables and polyaniline nanotubes. Chem A Eur J 12:5314–
5319
18. Guoand L, Peng Z (2008) One-pot synthesis of carbon nanotube-polyaniline-gold nanoparticle and carbon nanotube-gold nanoparticle composites by using aromatic amine chemistry.
Langmuir 24:8971–8975
521
the SEM images, which suggests the formation of chemical compounds. Consequently, the metal fragment is included in the polymer chain or covalently, or in
coordination with the polymer ligands (Pt, Pd). Part of the metal enters the composite
in the form of nanoparticles (Au, Ag) uniformly distributed in the polymer matrix.
Depending on the nature of the inclusion of the metal in the polymer matrix, and the
metal center affects both the type of bond and the degree of polymerization.
References
1. Arancis R, Joy N, Aparna P, Vijayan R (2014) Polymer grafted inorganic nanoparticles,
preparation, properties, and applications: a Review. Polym Rev 54:268–347
2. Erokhin V, Ram MK, Yavuz Ö (2008) The new frontiers of organic and composite
nanotechnology. Elsevier, Amsterdam, Boston
3. Hu C-W, Yamada Y, Yoshimura K (2017) A new type of gasochromic material: conducting
polymers with catalytic nanoparticles. Chem Commun 53(22):3242–3245
4. Kumar CSSR (eds) (2007) Nanomaterials for medical diagnosis and therapy. Nanotechnologies
for the life sciences, vol 10. Wiley-VCH Verlag GmbH
5. Olenych IB, Aksimentyeva OI, Tsizh B, Horbenko Yu (2018) Transport and relaxation of
charge in organic-inorganic nanocomposites. Acta Phys Pol, A 133(4):851–855
6. Pandey S (2016) Highly sensitive and selective chemiresistor gas/vapor sensors based on
polyaniline nanocomposite: a comprehensive review. J Sci Adv Mater Devices 1:431–453
7. Dong X, Zhang X, Wu X, Cui H, Chen D (2016) Investigation of gas-sensing property of
acid-deposited polyaniline thin-film sensors for detecting H 2 S and SO 2 . Sensors 16:1888–2003
8. Aksimentyeva OI, Savchyn VP, Dyakonov VP, Piechota S, Horbenko YY, Opainych IY (2014)
Modification of polymer-magnetic nanoparticles by luminescent and conducting substances.
Mol Cryst Liq Cryst 590:35–42
9. Reshenhyak O, Zaitcev V (eds) (2017) Computational and experimental analysis of functional
materials. Apple Academic Press, Toronto
10. Sudha JD, Sivakala S, Prasanth R et al (2009) Development of electromagnetic shielding
materials from the conductive blends of polyaniline and polyaniline-clay nanocomposite-EVA:
preparation and properties. Compos Sci Technol 69:358–364
11. Stejskal J, Gilbert RG (2002) Polyaniline. Preparation of a conducting polymer. Pure Appl
Chem 74:857–867
12. Chiang JC, Mac Diarmid AG (1986) Polyaniline: protonic acid doping of the emeraldine form
to the metallic regime. Synth Met 13:193–205
13. Stejskal J, Exnerova M, Moravkova Z et al (2012) Oxidative stability of polyaniline. Polym
Degrad Stab 97:1026–1033
14. Le T-H, Kim Y, Yoon H (2017) Electrical and electrochemical properties of conducting
polymers. Polymers 9(4):150
15. Posudievsky OY, Kurys YI, Pokhodenko VD (2004) 2-Phosphormolibdic acid doped
polyaniline-V 2 O 5 composite. Synth Metals 144:107–111
16. Mallick K, Witcomb MJ, Dinsmore A et al (2005) Polymerization of aniline by auric acid:
formation of gold decorated polyaniline nanoballs. Macromol Rapid Commun 26:232–235
17. Huang K, Zhang Y, Huang K, Long Y et al (2006) Preparation of highly conductive, selfassembled gold/polyaniline nanocables and polyaniline nanotubes. Chem A Eur J 12:5314–
5319
18. Guoand L, Peng Z (2008) One-pot synthesis of carbon nanotube-polyaniline-gold nanoparticle and carbon nanotube-gold nanoparticle composites by using aromatic amine chemistry.
Langmuir 24:8971–8975