Formation of Manganese-Containing PEO Coatings on Aluminum Alloys
357
one process conversion coatings with developed surface and a high content of
manganese. The incorporation of manganese oxides into the composition of
Al 2 O 3 matrix contributes to the enhancement of catalytic activity of mixed oxide
systems.
2. The phase composition and morphology of mixed oxide covers surface have
been analyzed. The highly branched micro-porous and globular surface of
Al 2 O 3 ·MnO x coatings applied onto aluminum alloys is characterized by uniform
distribution of manganese which content reaches up to 36 wt%. The control of
composition and surface state of conversion mixed coatings has been achieved
by varying the PEO regimes.
3. The mixed manganese-aluminum oxide conversion coatings on the aluminum
alloys are characterized by a high corrosion resistance and catalytic activity.
Therefore, mixed oxide systems applied on the aluminum alloys are promising
in the environmental technologies for both air and water media purification.
Acknowledgements This research was conducted within the confines of the project (Registration
Number 0119U002568) with the support of the Ministry of Education and Science of Ukraine.
References
1. Heck RM, Farrauto RJ, Gulati ST (2009) Catalytic air pollution control: commercial
technology. Wiley, p 544
2. Stiles AB (1987) Catalyst supports and supported catalysts: theoretical and applied concepts.
Butterworth, Stoneham, MA
3. Yerokhin AL, Nie X, Leyland A, Matthews A, Dowey SJ (1999) Plasma electrolysis for surface
engineering. Surface Coat Technol 122(2–3):73–93
4. https://doi.org/10.1016/s0257-8972(99)00441-7
5. Gupta P, Tenhundfeld G, Daigle EO, Ryabkov D (2007) Electrolytic plasma technology: science
and engineering—an overview. Surf Coat Technol 201(21):8746–8760
6. Rudnev VS, Lukiyanchuk IV, Vasilyeva MS, Medkov MA, Adigamova MV, Sergienko VI
(2016) Aluminum- and titanium-supported plasma electrolytic multicomponent coatings with
magnetic, catalytic, biocide or biocompatible properties. Surf Coat Technol 307(Part C):1219–
1235
7. Rakoch AG, Khokhlov VV, Bautin VA, Lebedeva NA, Magurova YuV, Bardin IV (2006) Model
concepts on the mechanism of microarc oxidation of metal materials and the control over this
process. Prot Met 42(2):158–169
8. Sakhnenko ND, Ved MV, Vestfrid YuV, Stepanova II (1996) Predicting the catalytic activity
of metal oxide systems in treatment of exhaust gases to remove nitrogen oxides. Russ J Appl
Chem 69(9):1346–1350
9. Sakhnenko N, Ved M, Karakurkchi A, Galak A. (2016) A study of synthesis and properties of
manganese-containing oxide coatings on alloy VT1–0. East Eur J Enterpr Technol 3/5(81):37–
43
10. Sakhnenko M, Karakurkchi A, Galak A, Menshov S, Matykin O (2017) Examining the formation and properties of TiO 2 oxide coatings with metals of iron triad. East Eur J Enterpr Technol
2(11/86):4–10
357
one process conversion coatings with developed surface and a high content of
manganese. The incorporation of manganese oxides into the composition of
Al 2 O 3 matrix contributes to the enhancement of catalytic activity of mixed oxide
systems.
2. The phase composition and morphology of mixed oxide covers surface have
been analyzed. The highly branched micro-porous and globular surface of
Al 2 O 3 ·MnO x coatings applied onto aluminum alloys is characterized by uniform
distribution of manganese which content reaches up to 36 wt%. The control of
composition and surface state of conversion mixed coatings has been achieved
by varying the PEO regimes.
3. The mixed manganese-aluminum oxide conversion coatings on the aluminum
alloys are characterized by a high corrosion resistance and catalytic activity.
Therefore, mixed oxide systems applied on the aluminum alloys are promising
in the environmental technologies for both air and water media purification.
Acknowledgements This research was conducted within the confines of the project (Registration
Number 0119U002568) with the support of the Ministry of Education and Science of Ukraine.
References
1. Heck RM, Farrauto RJ, Gulati ST (2009) Catalytic air pollution control: commercial
technology. Wiley, p 544
2. Stiles AB (1987) Catalyst supports and supported catalysts: theoretical and applied concepts.
Butterworth, Stoneham, MA
3. Yerokhin AL, Nie X, Leyland A, Matthews A, Dowey SJ (1999) Plasma electrolysis for surface
engineering. Surface Coat Technol 122(2–3):73–93
4. https://doi.org/10.1016/s0257-8972(99)00441-7
5. Gupta P, Tenhundfeld G, Daigle EO, Ryabkov D (2007) Electrolytic plasma technology: science
and engineering—an overview. Surf Coat Technol 201(21):8746–8760
6. Rudnev VS, Lukiyanchuk IV, Vasilyeva MS, Medkov MA, Adigamova MV, Sergienko VI
(2016) Aluminum- and titanium-supported plasma electrolytic multicomponent coatings with
magnetic, catalytic, biocide or biocompatible properties. Surf Coat Technol 307(Part C):1219–
1235
7. Rakoch AG, Khokhlov VV, Bautin VA, Lebedeva NA, Magurova YuV, Bardin IV (2006) Model
concepts on the mechanism of microarc oxidation of metal materials and the control over this
process. Prot Met 42(2):158–169
8. Sakhnenko ND, Ved MV, Vestfrid YuV, Stepanova II (1996) Predicting the catalytic activity
of metal oxide systems in treatment of exhaust gases to remove nitrogen oxides. Russ J Appl
Chem 69(9):1346–1350
9. Sakhnenko N, Ved M, Karakurkchi A, Galak A. (2016) A study of synthesis and properties of
manganese-containing oxide coatings on alloy VT1–0. East Eur J Enterpr Technol 3/5(81):37–
43
10. Sakhnenko M, Karakurkchi A, Galak A, Menshov S, Matykin O (2017) Examining the formation and properties of TiO 2 oxide coatings with metals of iron triad. East Eur J Enterpr Technol
2(11/86):4–10
