Nanostructural Changes in a Ni/NiO Cermet During …
229
11. Karmhag R, Niklasson GA, Nygren M (1999) Oxidation kinetics of small nickel particles. J
Appl Phys 85:1186–1191
12. Karmhag R, Niklasson GA, Nygren M (2001) Oxidation kinetics of nickel nanoparticles. J
Appl Phys 89:3012–3017
13. Atkinson A (1985) Transport processes during the growth of oxide films at elevated temperature.
Rev Mod Phys 57:437–470
14. Podhurs’ka VY, Vasyliv BD, Ostash OP et al (2014) Structural transformations in the NiOcontaining anode of ceramic fuel cells in the course of its reduction and oxidation. Mater Sci
49(6):805–811
15. Vasyliv BD (2010) Improvement of the electric conductivity of the material of anode in a fuel
cell by the cyclic redox thermal treatment. Mater Sci 46(2):260–264
16. Radovic M, Lara-Curzio E (2004) Mechanical properties of tape cast nickel-based anode
materials for solid oxide fuel cells before and after reduction in hydrogen. Acta Mater
52:5747–5756
17. Vasyliv BD (2009) A procedure for the investigation of mechanical and physical properties of
ceramics under the conditions of biaxial bending of a disk specimen according to the ring–ring
scheme. Mater Sci 45(4):571–575
18. Wang Y, Walter ME, Sabolsky K et al (2006) Effects of powder sizes and reduction parameters
on the strength of Ni–YSZ anodes. Solid State Ionics 177:1517–1527
19. Van der Pauw LJ (1958) A method of measuring specific resistivity and hall effect of discs of
arbitrary shape. Philips Res Rep 13:1–9
20. Clemmer RMC, Corbin SF (2009) The influence of pore and Ni morphology on the electrical
conductivity of porous Ni/YSZ composite anodes for use in solid oxide fuel cell applications.
Solid State Ionics 180:721–730
21. Vasyliv BD, Podhurs’ka VY, Ostash OP et al (2013) Influence of reducing and oxidizing
media on the physicomechanical properties of ScCeSZ–NiO and YSZ–NiO ceramics. Mater
Sci 49(2):135–144
22. Vasyliv BD, Ostash OP, Podhurska VY et al (2013) Method of treatment of NiO-containing
anodes for a solid oxide fuel cell. Patent of Ukraine No. 78992. Published on 10.04.13, Bulletin
No. 7 (in Ukrainian)
23. Podhurska V, Vasyliv B (2012) Influence of NiO reduction on microstructure and properties
of porous Ni–ZrO 2 substrates. In: Proceedings of the 3rd international conference on oxide
materials for electronic engineering (OMEE-2012), Lviv, Ukraine, 3–7 Sept 2012
24. Vasyliv B, Podhurska V, Ostash O (2017) Preconditioning of the YSZ-NiO fuel cell anode in
hydrogenous atmospheres containing water vapor. Nanoscale Res Lett 12:265. https://doi.org/
10.1186/s11671-017-2038-4
25. Ettler M, Blaβ G, Menzler NH (2007) Characterization of Ni–YSZ-cermets with respect to
redox stability. Fuel Cells 5:349–355
26. Zhang Y, Liu B, Tu B et al (2009) Understanding of redox behavior of Ni–YSZ cermets. Solid
State Ionics 180:1580–1586
27. Faes A, Nakajo A, Hessler-Wyser A et al (2009) Redox study of anode-supported solid oxide
fuel cell. J Power Sources 193:55–64
28. Waldbillig D, Wood A, Ivey DG (2005) Electrochemical and microstructural characterization
of the redox tolerance of solid oxide fuel cell anodes. J Power Sources 145:206–215
29. Wood A, Waldbillig D (2011) Preconditioning treatment to enhance redox tolerance of solid
oxide fuel cells. US Patent 8,029,946 B2, 4 Oct 2011
30. Peraldi R, Monceau D, Pieraggi B (2002) Correlations between growth kinetics and microstructure for scales formed by high-temperature oxidation of pure nickel. I. Morphologies and
microstructures. Oxid Met 58:249–273
31. Podhurska V, Vasyliv B, Ostash O et al (2016) Influence of treatment temperature on microstructure and properties of YSZ–NiO anode materials. Nanoscale Res Lett 11:93. https://doi.org/
10.1186/s11671-016-1306-z
32. Yu JH, Park GW, Lee S et al (2007) Microstructural effects on the electrical and mechanical
properties of Ni–YSZ cermet for SOFC anode. J Power Sources 163:926–932
229
11. Karmhag R, Niklasson GA, Nygren M (1999) Oxidation kinetics of small nickel particles. J
Appl Phys 85:1186–1191
12. Karmhag R, Niklasson GA, Nygren M (2001) Oxidation kinetics of nickel nanoparticles. J
Appl Phys 89:3012–3017
13. Atkinson A (1985) Transport processes during the growth of oxide films at elevated temperature.
Rev Mod Phys 57:437–470
14. Podhurs’ka VY, Vasyliv BD, Ostash OP et al (2014) Structural transformations in the NiOcontaining anode of ceramic fuel cells in the course of its reduction and oxidation. Mater Sci
49(6):805–811
15. Vasyliv BD (2010) Improvement of the electric conductivity of the material of anode in a fuel
cell by the cyclic redox thermal treatment. Mater Sci 46(2):260–264
16. Radovic M, Lara-Curzio E (2004) Mechanical properties of tape cast nickel-based anode
materials for solid oxide fuel cells before and after reduction in hydrogen. Acta Mater
52:5747–5756
17. Vasyliv BD (2009) A procedure for the investigation of mechanical and physical properties of
ceramics under the conditions of biaxial bending of a disk specimen according to the ring–ring
scheme. Mater Sci 45(4):571–575
18. Wang Y, Walter ME, Sabolsky K et al (2006) Effects of powder sizes and reduction parameters
on the strength of Ni–YSZ anodes. Solid State Ionics 177:1517–1527
19. Van der Pauw LJ (1958) A method of measuring specific resistivity and hall effect of discs of
arbitrary shape. Philips Res Rep 13:1–9
20. Clemmer RMC, Corbin SF (2009) The influence of pore and Ni morphology on the electrical
conductivity of porous Ni/YSZ composite anodes for use in solid oxide fuel cell applications.
Solid State Ionics 180:721–730
21. Vasyliv BD, Podhurs’ka VY, Ostash OP et al (2013) Influence of reducing and oxidizing
media on the physicomechanical properties of ScCeSZ–NiO and YSZ–NiO ceramics. Mater
Sci 49(2):135–144
22. Vasyliv BD, Ostash OP, Podhurska VY et al (2013) Method of treatment of NiO-containing
anodes for a solid oxide fuel cell. Patent of Ukraine No. 78992. Published on 10.04.13, Bulletin
No. 7 (in Ukrainian)
23. Podhurska V, Vasyliv B (2012) Influence of NiO reduction on microstructure and properties
of porous Ni–ZrO 2 substrates. In: Proceedings of the 3rd international conference on oxide
materials for electronic engineering (OMEE-2012), Lviv, Ukraine, 3–7 Sept 2012
24. Vasyliv B, Podhurska V, Ostash O (2017) Preconditioning of the YSZ-NiO fuel cell anode in
hydrogenous atmospheres containing water vapor. Nanoscale Res Lett 12:265. https://doi.org/
10.1186/s11671-017-2038-4
25. Ettler M, Blaβ G, Menzler NH (2007) Characterization of Ni–YSZ-cermets with respect to
redox stability. Fuel Cells 5:349–355
26. Zhang Y, Liu B, Tu B et al (2009) Understanding of redox behavior of Ni–YSZ cermets. Solid
State Ionics 180:1580–1586
27. Faes A, Nakajo A, Hessler-Wyser A et al (2009) Redox study of anode-supported solid oxide
fuel cell. J Power Sources 193:55–64
28. Waldbillig D, Wood A, Ivey DG (2005) Electrochemical and microstructural characterization
of the redox tolerance of solid oxide fuel cell anodes. J Power Sources 145:206–215
29. Wood A, Waldbillig D (2011) Preconditioning treatment to enhance redox tolerance of solid
oxide fuel cells. US Patent 8,029,946 B2, 4 Oct 2011
30. Peraldi R, Monceau D, Pieraggi B (2002) Correlations between growth kinetics and microstructure for scales formed by high-temperature oxidation of pure nickel. I. Morphologies and
microstructures. Oxid Met 58:249–273
31. Podhurska V, Vasyliv B, Ostash O et al (2016) Influence of treatment temperature on microstructure and properties of YSZ–NiO anode materials. Nanoscale Res Lett 11:93. https://doi.org/
10.1186/s11671-016-1306-z
32. Yu JH, Park GW, Lee S et al (2007) Microstructural effects on the electrical and mechanical
properties of Ni–YSZ cermet for SOFC anode. J Power Sources 163:926–932