106
Y. S. Dzyazko et al.
6 Conclusions
The composites containing inorganic ion exchangers and GO are promising multifunctional materials: they are able to adsorb both inorganic ionic species and organic
ions and molecules. This is due to the combination of hydrophilic and hydrophobic
properties of GO. As found by means of MSCP, GO demonstrates “superhydrophilicity” similar to ion exchange polymers: larger porosity is achieved in water than that
in ideally wetting octane. Except ion exchange ability, the inorganic support provides
large size of granule. Thus, it is possible to use the composites for the filling of adsorption columns. A number of GO-containing adsorbents possess magnetic properties.
It means that they can be easily separated from liquids and solids.
References
1. Xu M, Liang T, Shi M (2013) Graphene-like two-dimensional materials. Chem Rev 113:3766–
3798
2. Anasori B, Lukatskaya MR, Gogotsi Y (2017) 2D metal carbides and nitrides (MXenes) for
energy storage. Nat Rev Mater 2:16098. https://doi.org/10.1038/natrevmats.2016.98
3. Geim AK, Novoselov KS (2007) The rise of graphene. Nat Mater 6(3):183–191
4. Geim AK (2009) Graphene: status and prospects. Science 324(5934):1530–1534
5. Zhao J, Liu L, Li F (2015) Graphene oxide: physics and applications. Springer, Heidelberg
6. Stobinski L, Lesiaka B. Malolepszy A et al (2014) Graphene oxide and reduced graphene
oxide studied by the XRD, TEM and electron spectroscopy methods. J Electr Spectr Rel Phen
195:145–154
7. Brodie BC (1860) Sur le poids atomique du graphite. Ann Chim Phys 59:466–472
8. Staudenmaier L (1898) Verfahren zur Darstellung der Graphitsaure. Ber Deut Chem Ges
31:1481–1487
9. Hummers WS, Offeman RE (1958) Preparation of graphitic oxide. J Am Chem Soc 80:1339–
1339
10. Dimiev AM, Khannanov A, Vakhitov I et al (2018) Revisiting the mechanism of oxidative
unzipping of multiwall carbon nanotubes to graphene nanoribbons. ACS Nano 12(4):3985–
3993
11. Higginbotham AL, Kosynkin DV, Sinitskii A (2010) Lower-defect graphene oxide nanoribbons
from multiwalled carbon nanotubes. ACS Nano 4(4):2059–2069
12. Dreyer DR, Park S, Bielawski CW et al (2010) The chemistry of graphene oxide. Chem Soc
Rev 39(1):228–240
13. Li Z, Chen F, Yuan L et al (2012) Uranium(VI) adsorption on graphene oxide nanosheets from
aqueous solutions. Chem Eng J 210:539–546
14. Mi X, Huang G, Xie W et al (2012) Preparation of graphene oxide aerogel and its adsorption
for Cu 2+ ions. Carbon 50(13):4856–4864
15. Dzyazko YS, Ogenko VM, Volfkovich YM et al (2018) Composite consisting of hydrated
zirconium dioxide and grapheme oxide for removal of organic and inorganic components from
water. Chem Phys Technol Surf 9(4):417–431
16. Konicki W, Aleksandrzak M, Moszy´ nski D et al (2017) Adsorption of anionic azo-dyes from
aqueous solutions onto graphene oxide: Equilibrium, kinetic and thermodynamic studies. J
Colloid Interface Sci 496:188–200
17. Wang H, Chen P (2015) Adsorption and coadsorption of organic pollutants and a heavy metal
by graphene oxide and reduced graphene materials. Chem Eng J 281:379–388
Y. S. Dzyazko et al.
6 Conclusions
The composites containing inorganic ion exchangers and GO are promising multifunctional materials: they are able to adsorb both inorganic ionic species and organic
ions and molecules. This is due to the combination of hydrophilic and hydrophobic
properties of GO. As found by means of MSCP, GO demonstrates “superhydrophilicity” similar to ion exchange polymers: larger porosity is achieved in water than that
in ideally wetting octane. Except ion exchange ability, the inorganic support provides
large size of granule. Thus, it is possible to use the composites for the filling of adsorption columns. A number of GO-containing adsorbents possess magnetic properties.
It means that they can be easily separated from liquids and solids.
References
1. Xu M, Liang T, Shi M (2013) Graphene-like two-dimensional materials. Chem Rev 113:3766–
3798
2. Anasori B, Lukatskaya MR, Gogotsi Y (2017) 2D metal carbides and nitrides (MXenes) for
energy storage. Nat Rev Mater 2:16098. https://doi.org/10.1038/natrevmats.2016.98
3. Geim AK, Novoselov KS (2007) The rise of graphene. Nat Mater 6(3):183–191
4. Geim AK (2009) Graphene: status and prospects. Science 324(5934):1530–1534
5. Zhao J, Liu L, Li F (2015) Graphene oxide: physics and applications. Springer, Heidelberg
6. Stobinski L, Lesiaka B. Malolepszy A et al (2014) Graphene oxide and reduced graphene
oxide studied by the XRD, TEM and electron spectroscopy methods. J Electr Spectr Rel Phen
195:145–154
7. Brodie BC (1860) Sur le poids atomique du graphite. Ann Chim Phys 59:466–472
8. Staudenmaier L (1898) Verfahren zur Darstellung der Graphitsaure. Ber Deut Chem Ges
31:1481–1487
9. Hummers WS, Offeman RE (1958) Preparation of graphitic oxide. J Am Chem Soc 80:1339–
1339
10. Dimiev AM, Khannanov A, Vakhitov I et al (2018) Revisiting the mechanism of oxidative
unzipping of multiwall carbon nanotubes to graphene nanoribbons. ACS Nano 12(4):3985–
3993
11. Higginbotham AL, Kosynkin DV, Sinitskii A (2010) Lower-defect graphene oxide nanoribbons
from multiwalled carbon nanotubes. ACS Nano 4(4):2059–2069
12. Dreyer DR, Park S, Bielawski CW et al (2010) The chemistry of graphene oxide. Chem Soc
Rev 39(1):228–240
13. Li Z, Chen F, Yuan L et al (2012) Uranium(VI) adsorption on graphene oxide nanosheets from
aqueous solutions. Chem Eng J 210:539–546
14. Mi X, Huang G, Xie W et al (2012) Preparation of graphene oxide aerogel and its adsorption
for Cu 2+ ions. Carbon 50(13):4856–4864
15. Dzyazko YS, Ogenko VM, Volfkovich YM et al (2018) Composite consisting of hydrated
zirconium dioxide and grapheme oxide for removal of organic and inorganic components from
water. Chem Phys Technol Surf 9(4):417–431
16. Konicki W, Aleksandrzak M, Moszy´ nski D et al (2017) Adsorption of anionic azo-dyes from
aqueous solutions onto graphene oxide: Equilibrium, kinetic and thermodynamic studies. J
Colloid Interface Sci 496:188–200
17. Wang H, Chen P (2015) Adsorption and coadsorption of organic pollutants and a heavy metal
by graphene oxide and reduced graphene materials. Chem Eng J 281:379–388