32 Grain Porous Structure and Exploitation Properties of Humidity-Sensitive. . .
517
12. Armatas GS, Salmas CE, Louloudi MG, Androutsopoulos P, Pomonis PJ (2003) Relationships among pore size, connectivity, dimensionality of capillary condensation, and
pore structure tortuosity of functionalized mesoporous silica. Langmuir 19:3128–3136.
https://doi.org/10.1021/la020261h
13. Kashi MA, Ramazani A, Abbasian H, Khayyatian A (2012) Capacitive humidity sensors based
on large diameter porous alumina prepared by high current anodization. Sensors Actuators A
174:69–74. https://doi.org/10.1016/j.sna.2011.11.033
14. Klym H, Ingram A, Hadzaman I, Shpotyuk O (2014) Evolution of porous structure and
free-volume entities in magnesium aluminate spinel ceramics. Ceram Int 40(6):8561–8567.
https://doi.org/10.1016/j.ceramint.2014.01.070
15. Klym H, Ingram A, Shpotyuk O, Hadzaman I, Solntsev V (2016) Water-vapor sorption
processes in nanoporous MgO-Al 2 O 3 ceramics: the PAL spectroscopy study. Nanoscale Res
Lett 11(1):1. https://doi.org/10.1186/s11671-016-1352-6
16. Klym H, Ingram A, Shpotyuk O, Hadzaman I, Hotra O, Kostiv Y (2016) Nanostructural freevolume effects in humidity-sensitive MgO-Al 2 O 3 ceramics for sensor applications. J Mater
Eng Perform 25(3):866–873. https://doi.org/10.1007/s11665-016-1931-9
17. Klym H, Hadzaman I, Shpotyuk O (2015) Influence of sintering temperature on pore
structure and electrical properties of technologically modified MgO-Al 2 O 3 ceramics. Mater
Sci 21(1):92–95 https://doi.org/10.5755/j01.ms.21.1.5189
18. Klym H, Shpotyuk O, Ingram A, Calvez L, Hadzaman I, Yu K, Ivanusa A, Chalyy D (2017)
Influence of free volumes on functional properties of modified chalcogenide glasses and oxide
ceramics. Springer Proc Phys 195:479–493. https://doi.org/10.1007/978-3-319-56422-7_36
19. Shpotyuk O, Balitska V, Brunner M, Hadzaman I, Klym H (2015) Thermally-induced
electronic relaxation in structurally-modified Cu 0.1 Ni 0.8 Co 0.2 Mn 1.9 O 4 spinel ceramics. Phys
B Condens Matter 459:116–121 https://doi.org/10.1016/j.physb.2014.11.023
20. Shpotyuk O, Brunner M, Hadzaman I, Balitska V, Klym H (2016) Analytical description of
degradation-relaxation transformations in nanoinhomogeneous spinel ceramics. Nanoscale Res
Lett 11(1):499. https://doi.org/10.1186/s11671-016-1722-0
21. Klym H, Balitska V, Shpotyuk O, Hadzaman I (2014) Degradation transformation in
spinel-type functional thick-film ceramic materials. Microelectron Reliab 54(12):2843–2848
https://doi.org/10.1016/j.microrel.2014.07.137
22. Hadzaman I, Klym H, Shpotyuk O (2014) Nanostructured oxyspinel multilayers for
novel high-efficient conversion and control. Int J Nanotechnol 11(9–10-11):843–853.
https://doi.org/10.1504/IJNT.2014.063793
23. Rodriguez-Carvajal J (2001) Recent developments of the program FULLPROF, Commission
on Powder Diffraction (IUCr). Newsletter 26:12–19
24. Roisnel T, Rodriguez-Carvajal J (2000) WinPLOTR: a windows tool for powder diffraction
patterns analysis, materials, science forum. In: Proceedings of the seventh European powder
diffraction conference, Barcelona
25. Hill RJ, Howard CJ (1987) Quantitative phase analysis from neutron powder
diffraction data using the Rietveld method. J Appl Crystallogr 20:467–474.
https://doi.org/10.1107/S0021889887086199
26. Bondarchuk A, Shpotyuk O, Glot A, Klym H (2012) Current saturation in In 2 O 3 -SrO
ceramics: a role of oxidizing atmosphere. Revista mexicana de física 58(4):313–316. http://
www.scielo.org.mx/pdf/rmf/v58n4/v58n4a5.pdf
27. Karbovnyk I, Bolesta I, Rovetskii I, Velgosh S, Klym H (2014) Studies of CdI 2 -Bi 3 microstructures with optical methods, atomic force microscopy and positron annihilation spectroscopy.
Mater Sci Pol 32(3):391–395. https://doi.org/10.2478/s13536-014-0215-z
28. Klym H, Ingram A, Shpotyuk O, Filipecki J, Hadzaman I (2011) Structural studies of
spinel manganite ceramics with positron annihilation lifetime spectroscopy. J Phys Conf Ser
289(1):012010 http://iopscience.iop.org/article/10.1088/1742-6596/289/1/012010/meta
29. Klym H, Ingram A, Shpotyuk O, Filipecki J (2010) PALS as characterization tool in application
to humidity-sensitive electroceramics. In: 27th International Conference on Microelectronics
Proceedings (MIEL), pp 239–242. https://doi.org/10.1109/MIEL.2010.5490492
517
12. Armatas GS, Salmas CE, Louloudi MG, Androutsopoulos P, Pomonis PJ (2003) Relationships among pore size, connectivity, dimensionality of capillary condensation, and
pore structure tortuosity of functionalized mesoporous silica. Langmuir 19:3128–3136.
https://doi.org/10.1021/la020261h
13. Kashi MA, Ramazani A, Abbasian H, Khayyatian A (2012) Capacitive humidity sensors based
on large diameter porous alumina prepared by high current anodization. Sensors Actuators A
174:69–74. https://doi.org/10.1016/j.sna.2011.11.033
14. Klym H, Ingram A, Hadzaman I, Shpotyuk O (2014) Evolution of porous structure and
free-volume entities in magnesium aluminate spinel ceramics. Ceram Int 40(6):8561–8567.
https://doi.org/10.1016/j.ceramint.2014.01.070
15. Klym H, Ingram A, Shpotyuk O, Hadzaman I, Solntsev V (2016) Water-vapor sorption
processes in nanoporous MgO-Al 2 O 3 ceramics: the PAL spectroscopy study. Nanoscale Res
Lett 11(1):1. https://doi.org/10.1186/s11671-016-1352-6
16. Klym H, Ingram A, Shpotyuk O, Hadzaman I, Hotra O, Kostiv Y (2016) Nanostructural freevolume effects in humidity-sensitive MgO-Al 2 O 3 ceramics for sensor applications. J Mater
Eng Perform 25(3):866–873. https://doi.org/10.1007/s11665-016-1931-9
17. Klym H, Hadzaman I, Shpotyuk O (2015) Influence of sintering temperature on pore
structure and electrical properties of technologically modified MgO-Al 2 O 3 ceramics. Mater
Sci 21(1):92–95 https://doi.org/10.5755/j01.ms.21.1.5189
18. Klym H, Shpotyuk O, Ingram A, Calvez L, Hadzaman I, Yu K, Ivanusa A, Chalyy D (2017)
Influence of free volumes on functional properties of modified chalcogenide glasses and oxide
ceramics. Springer Proc Phys 195:479–493. https://doi.org/10.1007/978-3-319-56422-7_36
19. Shpotyuk O, Balitska V, Brunner M, Hadzaman I, Klym H (2015) Thermally-induced
electronic relaxation in structurally-modified Cu 0.1 Ni 0.8 Co 0.2 Mn 1.9 O 4 spinel ceramics. Phys
B Condens Matter 459:116–121 https://doi.org/10.1016/j.physb.2014.11.023
20. Shpotyuk O, Brunner M, Hadzaman I, Balitska V, Klym H (2016) Analytical description of
degradation-relaxation transformations in nanoinhomogeneous spinel ceramics. Nanoscale Res
Lett 11(1):499. https://doi.org/10.1186/s11671-016-1722-0
21. Klym H, Balitska V, Shpotyuk O, Hadzaman I (2014) Degradation transformation in
spinel-type functional thick-film ceramic materials. Microelectron Reliab 54(12):2843–2848
https://doi.org/10.1016/j.microrel.2014.07.137
22. Hadzaman I, Klym H, Shpotyuk O (2014) Nanostructured oxyspinel multilayers for
novel high-efficient conversion and control. Int J Nanotechnol 11(9–10-11):843–853.
https://doi.org/10.1504/IJNT.2014.063793
23. Rodriguez-Carvajal J (2001) Recent developments of the program FULLPROF, Commission
on Powder Diffraction (IUCr). Newsletter 26:12–19
24. Roisnel T, Rodriguez-Carvajal J (2000) WinPLOTR: a windows tool for powder diffraction
patterns analysis, materials, science forum. In: Proceedings of the seventh European powder
diffraction conference, Barcelona
25. Hill RJ, Howard CJ (1987) Quantitative phase analysis from neutron powder
diffraction data using the Rietveld method. J Appl Crystallogr 20:467–474.
https://doi.org/10.1107/S0021889887086199
26. Bondarchuk A, Shpotyuk O, Glot A, Klym H (2012) Current saturation in In 2 O 3 -SrO
ceramics: a role of oxidizing atmosphere. Revista mexicana de física 58(4):313–316. http://
www.scielo.org.mx/pdf/rmf/v58n4/v58n4a5.pdf
27. Karbovnyk I, Bolesta I, Rovetskii I, Velgosh S, Klym H (2014) Studies of CdI 2 -Bi 3 microstructures with optical methods, atomic force microscopy and positron annihilation spectroscopy.
Mater Sci Pol 32(3):391–395. https://doi.org/10.2478/s13536-014-0215-z
28. Klym H, Ingram A, Shpotyuk O, Filipecki J, Hadzaman I (2011) Structural studies of
spinel manganite ceramics with positron annihilation lifetime spectroscopy. J Phys Conf Ser
289(1):012010 http://iopscience.iop.org/article/10.1088/1742-6596/289/1/012010/meta
29. Klym H, Ingram A, Shpotyuk O, Filipecki J (2010) PALS as characterization tool in application
to humidity-sensitive electroceramics. In: 27th International Conference on Microelectronics
Proceedings (MIEL), pp 239–242. https://doi.org/10.1109/MIEL.2010.5490492