29 Structural Study of the Modified Cu 0.4 Co 0.4 Ni 0.4 Mn 1.8 O 4 . . .
473
4. Shpotyuk O, Balitska V, Brunner M, Hadzaman I, Klym H (2015) Thermally-induced
electronic relaxation in structurally-modified Cu 0.1 Ni 0.8 Co 0.2 Mn 1.9 O 4 spinel ceramics. Phys
B Condens Matter 459:116–121 https://doi.org/10.1016/j.physb.2014.11.023
5. Klym H, Hadzaman I, Shpotyuk O (2015) Influence of sintering temperature on pore
structure and electrical properties of technologically modified MgO-Al 2 O 3 ceramics. Mater
Sci 21(1):92–95 https://doi.org/10.5755/j01.ms.21.1.5189
6. Setter N (2001) Electroceramics: looking ahead. J Eur Ceram Soc 21(10):1279–1293.
https://doi.org/10.1016/S0955-2219(01)00217-5
7. Rousset A, Tenailleau C, Dufour P, Bordeneuve H, Pasquet I, Guillemet-Fritsch S, Schuurman
S (2013) Electrical properties of Mn 3−x Co x O 4 (0≤ x≤ 3) ceramics: an interesting system
for negative temperature coefficient thermistors. Int J Appl Ceram Technol 10(1):175–185.
https://doi.org/10.1111/j.1744-7402.2011.02723.x
8. Bondarchuk A, Shpotyuk O, Glot A, Klym H (2012) Current saturation in In 2 O 3 -SrO
ceramics: a role of oxidizing atmosphere. Revista mexicana de física 58(4):313–316 http://
www.scielo.org.mx/pdf/rmf/v58n4/v58n4a5.pdf
9. Deng ZY, Fukasawa T, Ando M, Zhang GJ, Ohji T (2001) Microstructure and mechanical properties of porous alumina ceramics fabricated by the decomposition of aluminum hydroxide. J
Am Ceram Soc 84(11):2638–2644. https://doi.org/10.1111/j.1151-2916.2001.tb01065.x
10. Ohji T, Fukushima M (2012) Macro-porous ceramics: processing and properties. Int Mater Rev
57(2):115–131 https://doi.org/10.1179/1743280411Y.0000000006
11. Klym H, Ingram A, Shpotyuk O, Hadzaman I, Hotra O, Kostiv Y (2016) Nanostructural freevolume effects in humidity-sensitive MgO-Al 2 O 3 ceramics for sensor applications. J Mater
Eng Perform 25(3):866–873. https://doi.org/10.1007/s11665-016-1931-9
12. Shpotyuk O, Brunner M, Hadzaman I, Balitska V, Klym H (2016) Analytical description of
degradation-relaxation transformations in nanoinhomogeneous spinel ceramics. Nanoscale Res
Lett 11(1):499. https://doi.org/10.1186/s11671-016-1722-0
13. Klym H, Balitska V, Shpotyuk O, Hadzaman I (2014) Degradation transformation in
spinel-type functional thick-film ceramic materials. Microelectron Reliab 54(12):2843–2848
https://doi.org/10.1016/j.microrel.2014.07.137
14. Krause-Rehberg R, Leipner HS (1999) Positron annihilation in semiconductors. Defect studies.
Springer-Verlag, Berlin/Heidelberg/New York, p 378
15. Shpotyuk O, Filipecki J (2003) Free volume in vitreous chalcogenide semiconductors: possibilities of positron annihilation lifetime study. Wyd-wo WSP w Czestochowie, Czestochowa
16. Klym H, Ingram A, Shpotyuk O, Filipecki J, Hadzaman I (2011) Structural studies of
spinel manganite ceramics with positron annihilation lifetime spectroscopy. J Phys Conf Ser
289(1):012010 http://iopscience.iop.org/article/10.1088/1742-6596/289/1/012010/meta
17. Klym H, Ingram A, Shpotyuk O, Filipecki J (2010) PALS as characterization tool in application
to humidity-sensitive electroceramics. In: 27th international conference on microelectronics
proceedings (MIEL), pp 239–242. https://doi.org/10.1109/MIEL.2010.5490492
18. Klym H, Ingram A, Shpotyuk O, Hadzaman I, Solntsev V (2016) Water-vapor sorption
processes in nanoporous MgO-Al 2 O 3 ceramics: the PAL spectroscopy study. Nanoscale Res
Lett 11(1):1. https://doi.org/10.1186/s11671-016-1352-6
19. Shpotyuk O, Filipecki J, Ingram A, Golovchak R, Vakiv M, Klym H, Balitska V,
Shpotyuk M, Kozdras A (2015) Positronics of subnanometer atomistic imperfections in
solids as a high-informative structure characterization tool. Nanoscale Res Lett 10(1):1–5.
https://doi.org/10.1186/s11671-015-0764-z
20. Klym H, Ingram A, Shpotyuk O, Hadzaman I, Solntsev V, Hotra O, Popov
AI (2016) Positron annihilation characterization of free volume in micro-and
macro-modified Cu 0.4 Co 0.4 Ni 0.4 Mn 1.8 O 4 ceramics. Low Temp Phys 42(7):601–605
https://doi.org/10.1063/1.4959021
21. Karbovnyk I, Bolesta I, Rovetskii I, Velgosh S, Klym H (2014) Studies of CdI 2 -Bi 3 microstructures with optical methods, atomic force microscopy and positron annihilation spectroscopy.
Mater Sci Poland 32(3):391–395. https://doi.org/10.2478/s13536-014-0215-z
473
4. Shpotyuk O, Balitska V, Brunner M, Hadzaman I, Klym H (2015) Thermally-induced
electronic relaxation in structurally-modified Cu 0.1 Ni 0.8 Co 0.2 Mn 1.9 O 4 spinel ceramics. Phys
B Condens Matter 459:116–121 https://doi.org/10.1016/j.physb.2014.11.023
5. Klym H, Hadzaman I, Shpotyuk O (2015) Influence of sintering temperature on pore
structure and electrical properties of technologically modified MgO-Al 2 O 3 ceramics. Mater
Sci 21(1):92–95 https://doi.org/10.5755/j01.ms.21.1.5189
6. Setter N (2001) Electroceramics: looking ahead. J Eur Ceram Soc 21(10):1279–1293.
https://doi.org/10.1016/S0955-2219(01)00217-5
7. Rousset A, Tenailleau C, Dufour P, Bordeneuve H, Pasquet I, Guillemet-Fritsch S, Schuurman
S (2013) Electrical properties of Mn 3−x Co x O 4 (0≤ x≤ 3) ceramics: an interesting system
for negative temperature coefficient thermistors. Int J Appl Ceram Technol 10(1):175–185.
https://doi.org/10.1111/j.1744-7402.2011.02723.x
8. Bondarchuk A, Shpotyuk O, Glot A, Klym H (2012) Current saturation in In 2 O 3 -SrO
ceramics: a role of oxidizing atmosphere. Revista mexicana de física 58(4):313–316 http://
www.scielo.org.mx/pdf/rmf/v58n4/v58n4a5.pdf
9. Deng ZY, Fukasawa T, Ando M, Zhang GJ, Ohji T (2001) Microstructure and mechanical properties of porous alumina ceramics fabricated by the decomposition of aluminum hydroxide. J
Am Ceram Soc 84(11):2638–2644. https://doi.org/10.1111/j.1151-2916.2001.tb01065.x
10. Ohji T, Fukushima M (2012) Macro-porous ceramics: processing and properties. Int Mater Rev
57(2):115–131 https://doi.org/10.1179/1743280411Y.0000000006
11. Klym H, Ingram A, Shpotyuk O, Hadzaman I, Hotra O, Kostiv Y (2016) Nanostructural freevolume effects in humidity-sensitive MgO-Al 2 O 3 ceramics for sensor applications. J Mater
Eng Perform 25(3):866–873. https://doi.org/10.1007/s11665-016-1931-9
12. Shpotyuk O, Brunner M, Hadzaman I, Balitska V, Klym H (2016) Analytical description of
degradation-relaxation transformations in nanoinhomogeneous spinel ceramics. Nanoscale Res
Lett 11(1):499. https://doi.org/10.1186/s11671-016-1722-0
13. Klym H, Balitska V, Shpotyuk O, Hadzaman I (2014) Degradation transformation in
spinel-type functional thick-film ceramic materials. Microelectron Reliab 54(12):2843–2848
https://doi.org/10.1016/j.microrel.2014.07.137
14. Krause-Rehberg R, Leipner HS (1999) Positron annihilation in semiconductors. Defect studies.
Springer-Verlag, Berlin/Heidelberg/New York, p 378
15. Shpotyuk O, Filipecki J (2003) Free volume in vitreous chalcogenide semiconductors: possibilities of positron annihilation lifetime study. Wyd-wo WSP w Czestochowie, Czestochowa
16. Klym H, Ingram A, Shpotyuk O, Filipecki J, Hadzaman I (2011) Structural studies of
spinel manganite ceramics with positron annihilation lifetime spectroscopy. J Phys Conf Ser
289(1):012010 http://iopscience.iop.org/article/10.1088/1742-6596/289/1/012010/meta
17. Klym H, Ingram A, Shpotyuk O, Filipecki J (2010) PALS as characterization tool in application
to humidity-sensitive electroceramics. In: 27th international conference on microelectronics
proceedings (MIEL), pp 239–242. https://doi.org/10.1109/MIEL.2010.5490492
18. Klym H, Ingram A, Shpotyuk O, Hadzaman I, Solntsev V (2016) Water-vapor sorption
processes in nanoporous MgO-Al 2 O 3 ceramics: the PAL spectroscopy study. Nanoscale Res
Lett 11(1):1. https://doi.org/10.1186/s11671-016-1352-6
19. Shpotyuk O, Filipecki J, Ingram A, Golovchak R, Vakiv M, Klym H, Balitska V,
Shpotyuk M, Kozdras A (2015) Positronics of subnanometer atomistic imperfections in
solids as a high-informative structure characterization tool. Nanoscale Res Lett 10(1):1–5.
https://doi.org/10.1186/s11671-015-0764-z
20. Klym H, Ingram A, Shpotyuk O, Hadzaman I, Solntsev V, Hotra O, Popov
AI (2016) Positron annihilation characterization of free volume in micro-and
macro-modified Cu 0.4 Co 0.4 Ni 0.4 Mn 1.8 O 4 ceramics. Low Temp Phys 42(7):601–605
https://doi.org/10.1063/1.4959021
21. Karbovnyk I, Bolesta I, Rovetskii I, Velgosh S, Klym H (2014) Studies of CdI 2 -Bi 3 microstructures with optical methods, atomic force microscopy and positron annihilation spectroscopy.
Mater Sci Poland 32(3):391–395. https://doi.org/10.2478/s13536-014-0215-z