Chapter 29
Structural Study of the Modified
Cu 0.4 Co 0.4 Ni 0.4 Mn 1.8 O 4
and Cu 0.1 Ni 0.8 Co 0.2 Mn 1.9 O 4 Ceramics
Using Combined Methods
H. Klym, I. Hadzaman, A. Ingram, O. Shpotyuk, I. Karbovnyk, Yu. Kostiv,
I. Vasylchyshyn, and D. Chalyy
29.1 Introduction
Temperature-sensitive spinel ceramics based on transition metal manganites with
topologically disordered structures is one of the perspective materials for temperature sensors and other practical applications [1–3]. The main structural elements in
these materials are grain, grain boundaries, and pores depending on technological
procedure of ceramic sintering [4, 5]. Understanding of correlation between grainporous and free-void structures as well as physical properties of such materials
is still in focus of scientific and commercial interests for scientists across the
globe [6, 7].
In ceramics, depending on the sintering temperature, shrinkage of the atomic
structure occurs, eventually leading to more or less complex pore topology [8–10].
H. Klym () · Y. Kostiv · I. Vasylchyshyn
Lviv Polytechnic National University, Lviv, Ukraine
e-mail: halyna.i.klym@lpnu.ua
I. Hadzaman
Drohobych State Pedagogical University, Drohobych, Ukraine
A. Ingram
Opole University of Technology, Opole, Poland
O. Shpotyuk
Vlokh Institute of Physical Optics, Lviv, Ukraine
Jan Dlugosz University in Czestochowa, Czestochowa, Poland
I. Karbovnyk
Ivan Franko National University of Lviv, Lviv, Ukraine
D. Chalyy
Lviv State University of Life Safety, Lviv, Ukraine
© Springer International Publishing AG, part of Springer Nature 2018
O. Fesenko, L. Yatsenko (eds.), Nanochemistry, Biotechnology, Nanomaterials,
and Their Applications, Springer Proceedings in Physics 214,
https://doi.org/10.1007/978-3-319-92567-7_29
459
Structural Study of the Modified
Cu 0.4 Co 0.4 Ni 0.4 Mn 1.8 O 4
and Cu 0.1 Ni 0.8 Co 0.2 Mn 1.9 O 4 Ceramics
Using Combined Methods
H. Klym, I. Hadzaman, A. Ingram, O. Shpotyuk, I. Karbovnyk, Yu. Kostiv,
I. Vasylchyshyn, and D. Chalyy
29.1 Introduction
Temperature-sensitive spinel ceramics based on transition metal manganites with
topologically disordered structures is one of the perspective materials for temperature sensors and other practical applications [1–3]. The main structural elements in
these materials are grain, grain boundaries, and pores depending on technological
procedure of ceramic sintering [4, 5]. Understanding of correlation between grainporous and free-void structures as well as physical properties of such materials
is still in focus of scientific and commercial interests for scientists across the
globe [6, 7].
In ceramics, depending on the sintering temperature, shrinkage of the atomic
structure occurs, eventually leading to more or less complex pore topology [8–10].
H. Klym () · Y. Kostiv · I. Vasylchyshyn
Lviv Polytechnic National University, Lviv, Ukraine
e-mail: halyna.i.klym@lpnu.ua
I. Hadzaman
Drohobych State Pedagogical University, Drohobych, Ukraine
A. Ingram
Opole University of Technology, Opole, Poland
O. Shpotyuk
Vlokh Institute of Physical Optics, Lviv, Ukraine
Jan Dlugosz University in Czestochowa, Czestochowa, Poland
I. Karbovnyk
Ivan Franko National University of Lviv, Lviv, Ukraine
D. Chalyy
Lviv State University of Life Safety, Lviv, Ukraine
© Springer International Publishing AG, part of Springer Nature 2018
O. Fesenko, L. Yatsenko (eds.), Nanochemistry, Biotechnology, Nanomaterials,
and Their Applications, Springer Proceedings in Physics 214,
https://doi.org/10.1007/978-3-319-92567-7_29
459