589
362. Gonzalez Maldonado GM, Assary RS, Dumesic JA, Curtiss LA (2012) Experimental and
theoretical studies of the acid-catalyzed conversion of furfuryl alcohol to levulinic acid in
aqueous solution. Energy Environ Sci 5:6981–6989. https://doi.org/10.1039/C2EE03465D
363. Xue Z, Liu Q, Wang J, Mu T (2018) Valorization of levulinic acid over non-noble metal
catalysts: challenges and opportunities. Green Chem 20:4391–4408. https://doi.org/10.1039/
x0xx00000x
364. Ahmad E, Alam MI, Pant KK, Ali Haider M (2018) Catalytic and mechanistic insights into the
production of ethyl levulinate from bio renewable feedstocks. Green Chem 18:4804–4823.
https://doi.org/10.1039/C6GC01523A
365. Demolis A, Essayem N, Rataboul E (2014) Synthesis and applications of alkyl levulinates.
ACS Sust Chem Eng 2:1338–1352. https://doi.org/10.1021/sc500082n
366. Haan RJ, Lange J-P (2011) US Patent Appl., 20110035991A1
367. Haan RJ, Lange J-P (2009) World Patatent, WO 2009077606 A2
368. Lange J-P, Heide E, Buijtenen J, Price R (2012) Furfural-a promising platform for lignocellulosic biofuels. ChemSusChem 5:150–166. https://doi.org/10.1002/cssc.201100648
369. Yang S, Hao Y, Wang J, Wang H, Zheng Y, Tian H, Liu Y, Sun B (2017) Selective catalytic
dehydration of furfuryl alcohol to 2,2′-difurfuryl ether using a polyoxometalate catalyst. Sci
Rep 7:12954. https://doi.org/10.1038/s41598- 017- 13472- 3
370. Meng Q, Zheng H, Zhu Y, Li Y (2016) Study on the reaction pathway in decarbonylation
of biomass-derived 5-hydroxymethylfurfural over Pd-based catalyst. J Mol Catal A Chem
421:76–82. https://doi.org/10.1016/j.molcata.2016.05.012
371. Kim T, Assary RS, Pauls RE, Marshall CL, Curtiss LA, Stair PC (2014) Thermodynamics
and reaction pathways of furfuryl alcohol oligomer formation. Catal Commun 46:66–70.
https://doi.org/10.1016/j.catcom.2013.11.030
372. Yi B, Rajagopalan R, Foley HC, Kim UJ, Liu X, Eklund PC (2006) Catalytic polymerization and facile grafting of poly (furfuryl alcohol) to single-wall carbon nanotube: preparation of nanocomposite carbon. J Am Chem Soc 128:11307–11313. https://doi.org/10.1021/
ja063518x
373. Kumar R, Rajesh A (2012) Process for preparing polyfurfuryl alcohol products, WO
2012/123902 Al, 20 Sep 2012
374. van Buijtenen J, Lange JP, Price RJ (2011) United States Pat., 2011/0173877
375. Moreau C, Belgacem MN, Gandini A (2004) Recent catalytic advances in the chemistry of
substituted furans from carbohydrates and in the ensuing polymers. Top Catal 27:11–30.
https://doi.org/10.1023/B:TOCA.0000013537.13540.0e
376. Pranger LA, Nunnery GA, Tannenbaum R (2012) Mechanism of the nanoparticle- catalyzed
polymerization of furfuryl alcohol and the thermal and mechanical properties of the resulting nanocomposites. Compos Part B 2012(43):1139–1146. https://doi.org/10.1016/j.
compositesb.2011.08.010
377. Takei T, Iguchi N, Haruta M (2010) Synthesis of acetaldehyde, acetic acid, and others by the
dehydrogenation and oxidation of ethanol. Catal Surv Jpn 15:80–88. https://doi.org/10.1007/
s10563- 011- 9112- 1
378. Gallo JMR, Bueno JMC, Schuchardt U (2014) Catalytic transformations of ethanol for biorefineries. J Braz Chem Soc 25:2229–2243. https://doi.org/10.5935/0103- 5053.20140272
379. Pease RN, Yung CC (1924) The catalytic dehydration of ethyl alcohol and ether by alumina.
J Am Chem Soc 46:390–340
380. Varisli D, Dogu T, Dogu G (2007) Ethylene and diethyl-ether production by dehydration
reaction of ethanol over different heteropoly acid catalysts. Chem Eng Sci 62:5349–5352.
https://doi.org/10.1016/j.ces.2007.01.017
381. Sato AG, Volanti DP, de Freitas IC, Longo E, Bueno JMC (2012) Site-selective ethanol conversion over supported copper catalysts. Catal Commun 26:122–126. https://doi.org/10.1016/j.
catcom.2012.05.008
382. Obora Y (2014) Recent advances in α-alkylation reactions using alcohols with hydrogen borrowing methodologies. ACS Catal 4:3972–3981. https://doi.org/10.1021/cs501269d
Catalytic Conversion of Alcohols into Value-Added Products
362. Gonzalez Maldonado GM, Assary RS, Dumesic JA, Curtiss LA (2012) Experimental and
theoretical studies of the acid-catalyzed conversion of furfuryl alcohol to levulinic acid in
aqueous solution. Energy Environ Sci 5:6981–6989. https://doi.org/10.1039/C2EE03465D
363. Xue Z, Liu Q, Wang J, Mu T (2018) Valorization of levulinic acid over non-noble metal
catalysts: challenges and opportunities. Green Chem 20:4391–4408. https://doi.org/10.1039/
x0xx00000x
364. Ahmad E, Alam MI, Pant KK, Ali Haider M (2018) Catalytic and mechanistic insights into the
production of ethyl levulinate from bio renewable feedstocks. Green Chem 18:4804–4823.
https://doi.org/10.1039/C6GC01523A
365. Demolis A, Essayem N, Rataboul E (2014) Synthesis and applications of alkyl levulinates.
ACS Sust Chem Eng 2:1338–1352. https://doi.org/10.1021/sc500082n
366. Haan RJ, Lange J-P (2011) US Patent Appl., 20110035991A1
367. Haan RJ, Lange J-P (2009) World Patatent, WO 2009077606 A2
368. Lange J-P, Heide E, Buijtenen J, Price R (2012) Furfural-a promising platform for lignocellulosic biofuels. ChemSusChem 5:150–166. https://doi.org/10.1002/cssc.201100648
369. Yang S, Hao Y, Wang J, Wang H, Zheng Y, Tian H, Liu Y, Sun B (2017) Selective catalytic
dehydration of furfuryl alcohol to 2,2′-difurfuryl ether using a polyoxometalate catalyst. Sci
Rep 7:12954. https://doi.org/10.1038/s41598- 017- 13472- 3
370. Meng Q, Zheng H, Zhu Y, Li Y (2016) Study on the reaction pathway in decarbonylation
of biomass-derived 5-hydroxymethylfurfural over Pd-based catalyst. J Mol Catal A Chem
421:76–82. https://doi.org/10.1016/j.molcata.2016.05.012
371. Kim T, Assary RS, Pauls RE, Marshall CL, Curtiss LA, Stair PC (2014) Thermodynamics
and reaction pathways of furfuryl alcohol oligomer formation. Catal Commun 46:66–70.
https://doi.org/10.1016/j.catcom.2013.11.030
372. Yi B, Rajagopalan R, Foley HC, Kim UJ, Liu X, Eklund PC (2006) Catalytic polymerization and facile grafting of poly (furfuryl alcohol) to single-wall carbon nanotube: preparation of nanocomposite carbon. J Am Chem Soc 128:11307–11313. https://doi.org/10.1021/
ja063518x
373. Kumar R, Rajesh A (2012) Process for preparing polyfurfuryl alcohol products, WO
2012/123902 Al, 20 Sep 2012
374. van Buijtenen J, Lange JP, Price RJ (2011) United States Pat., 2011/0173877
375. Moreau C, Belgacem MN, Gandini A (2004) Recent catalytic advances in the chemistry of
substituted furans from carbohydrates and in the ensuing polymers. Top Catal 27:11–30.
https://doi.org/10.1023/B:TOCA.0000013537.13540.0e
376. Pranger LA, Nunnery GA, Tannenbaum R (2012) Mechanism of the nanoparticle- catalyzed
polymerization of furfuryl alcohol and the thermal and mechanical properties of the resulting nanocomposites. Compos Part B 2012(43):1139–1146. https://doi.org/10.1016/j.
compositesb.2011.08.010
377. Takei T, Iguchi N, Haruta M (2010) Synthesis of acetaldehyde, acetic acid, and others by the
dehydrogenation and oxidation of ethanol. Catal Surv Jpn 15:80–88. https://doi.org/10.1007/
s10563- 011- 9112- 1
378. Gallo JMR, Bueno JMC, Schuchardt U (2014) Catalytic transformations of ethanol for biorefineries. J Braz Chem Soc 25:2229–2243. https://doi.org/10.5935/0103- 5053.20140272
379. Pease RN, Yung CC (1924) The catalytic dehydration of ethyl alcohol and ether by alumina.
J Am Chem Soc 46:390–340
380. Varisli D, Dogu T, Dogu G (2007) Ethylene and diethyl-ether production by dehydration
reaction of ethanol over different heteropoly acid catalysts. Chem Eng Sci 62:5349–5352.
https://doi.org/10.1016/j.ces.2007.01.017
381. Sato AG, Volanti DP, de Freitas IC, Longo E, Bueno JMC (2012) Site-selective ethanol conversion over supported copper catalysts. Catal Commun 26:122–126. https://doi.org/10.1016/j.
catcom.2012.05.008
382. Obora Y (2014) Recent advances in α-alkylation reactions using alcohols with hydrogen borrowing methodologies. ACS Catal 4:3972–3981. https://doi.org/10.1021/cs501269d
Catalytic Conversion of Alcohols into Value-Added Products