587
326. Rahmat N, Abdullah AZ, Mohamed AR (2010) Recent progress on innovative and potential
technologies for glycerol transformation into fuel additives: a critical review. Renew Sust
Energ Rev 14:987–1000. https://doi.org/10.1016/j.rser.2009.11.010
327. García JI, García-Marín H, Pires E (2014) Glycerol based solvents: synthesis, properties and
applications. Green Chem 16:1007–1033. https://doi.org/10.1039/C3GC41857J
328. Usai E, Gualdi E, Solinas V, Battistel E (2010) Simultaneous enzymatic synthesis of
FAME and triacetyl glycerol from triglycerides and methyl acetate. Bioresour Technol
101:7707–7712. https://doi.org/10.1016/j.biortech.2010.05.044
329. Morales G, Paniagua M, Melero JA, Vicente G, Ochoa C (2011) Sulfonic acid- functionalized
catalysts for the valorization of glycerol via transesterification with methyl acetate. Ind Eng
Chem Res 50:5898–5906. https://doi.org/10.1021/ie102357c
330. Silva LN, Gonçalves VL, Mota CJ (2010) Catalytic acetylation of glycerol with acetic anhydride. Catal Commun 11:1036–1039. https://doi.org/10.1016/j.catcom.2010.05.007
331. Gonzalez-Arellano C, De S, Luque R (2014) Selective glycerol transformations to high
value-added products catalysed by aluminosilicate-supported iron oxide nanoparticles. Catal
Sci Technol 4:4242–4249. https://doi.org/10.1039/C4CY00714J
332. Sandesh S, Kristachar PKR, Manjunathan P, Halgeri AB, Shanbhag GV (2016) Synthesis of
biodiesel and acetins by transesterification reactions using novel CaSn (OH) 6 heterogeneous
base catalyst. Appl Catal A Gen 523:1–11. https://doi.org/10.1016/j.apcata.2016.05.006
333. Gonçalves M, Souza VC, Galhardo TS, Mantovani M, Figueiredo FVC, Mandelli D, Carvalho
WA (2013) Glycerol conversion catalyzed by carbons prepared from agro industrial wastes.
Ind Engg Chem Res 52:2832–2839. https://doi.org/10.1021/ie303072d
334. Viswanadham N, Saxena SK (2013) Etherification of glycerol for improved production of
oxygenates. Fuel 103:980–986. https://doi.org/10.1016/j.fuel.2012.06.057
335. Cornejo A, Barrio I, Campoy M, Lázaro J, Navarrete B (2017) Oxygenated fuel additives
from glycerol valorization. Main production pathways and effects on fuel properties and
engine performance: a critical review. Renew Sust Energ Rev 79:1400–1413. https://doi.
org/10.1016/j.rser.2017.04.005
336. Mota CJ, da Silva CXA, Rosenbach N Jr, Costa J, da Silva FV (2010) Glycerin derivatives
as fuel additives: the addition of glycerol/acetone ketal (solketal) in gasolines. Energy Fuel
24:2733–2736. https://doi.org/10.1021/ef9015735
337. Vicente G, Melero JA, Morales G, Paniagua M, Martín E (2010) Acetalization of bioglycerol with acetone to produce solketal over sulfonic mesostructured silicas. Green Chem
12:899–907. https://doi.org/10.1039/B923681C
338. De Torres M, Jimenez-Oses G, Mayoral JA, Pires E, Santos M (2012) Glycerol ketals:
synthesis and profits in biodiesel blends. Fuel 94:614–616. https://doi.org/10.1016/j.
fuel.2011.11.062
339. Nanda MR, Yuan Z, Qin W, Ghaziaskar HS, Poirier M-A, Xu CC (2014) A new continuousflow process for catalytic conversion of glycerol to oxygenated fuel additive: catalyst screening. Appl Energy 123:75–81. https://doi.org/10.1016/j.apenergy.2014.02.055
340. Nanda MR, Yuan Z, Qin W, Ghaziaskar HS, Poirier M-A, Xu CC (2014) Catalytic conversion
of glycerol to oxygenated fuel additive in a continuous flow reactor: process optimization.
Fuel 128:113–119. https://doi.org/10.1016/j.fuel.2014.02.068
341. Umbarkar SB, Kotbagi TV, Biradar AV, Pasricha R, Chanale J, Dongare MK, Mamede A-S,
Lancelot C, Payen E (2009) Acetalization of glycerol using mesoporous MoO 3 /SiO 2 solid
acid catalyst. J Mol Catal A Chem 310:150–158
342. Amin T-K, Amin NAS, Najaafi N, Tarighi S (2018) A review on the catalytic acetalization
of bio-renewable glycerol to fuel additives. Front Chem 6:573. https://doi.org/10.3389/
fchem.2018.00573
343. Ma T, Ding J, Shao R, Xu W, Yun Z (2017) Dehydration of glycerol to acrolein over Wells–
Dawson and Keggin type phospho tungstic acids supported on MCM-41 catalysts. Chem Eng
J 316: 797–806. http://doi:10.1016/j.cej.2017.02.018
344. Gu Y, Liu S, Li C, Cui Q (2013) Selective conversion of glycerol to acrolein over supported
nickel sulfate catalysts. J Catal 301:93–102. https://doi.org/10.1016/j.jcat.2013.01.019
Catalytic Conversion of Alcohols into Value-Added Products
326. Rahmat N, Abdullah AZ, Mohamed AR (2010) Recent progress on innovative and potential
technologies for glycerol transformation into fuel additives: a critical review. Renew Sust
Energ Rev 14:987–1000. https://doi.org/10.1016/j.rser.2009.11.010
327. García JI, García-Marín H, Pires E (2014) Glycerol based solvents: synthesis, properties and
applications. Green Chem 16:1007–1033. https://doi.org/10.1039/C3GC41857J
328. Usai E, Gualdi E, Solinas V, Battistel E (2010) Simultaneous enzymatic synthesis of
FAME and triacetyl glycerol from triglycerides and methyl acetate. Bioresour Technol
101:7707–7712. https://doi.org/10.1016/j.biortech.2010.05.044
329. Morales G, Paniagua M, Melero JA, Vicente G, Ochoa C (2011) Sulfonic acid- functionalized
catalysts for the valorization of glycerol via transesterification with methyl acetate. Ind Eng
Chem Res 50:5898–5906. https://doi.org/10.1021/ie102357c
330. Silva LN, Gonçalves VL, Mota CJ (2010) Catalytic acetylation of glycerol with acetic anhydride. Catal Commun 11:1036–1039. https://doi.org/10.1016/j.catcom.2010.05.007
331. Gonzalez-Arellano C, De S, Luque R (2014) Selective glycerol transformations to high
value-added products catalysed by aluminosilicate-supported iron oxide nanoparticles. Catal
Sci Technol 4:4242–4249. https://doi.org/10.1039/C4CY00714J
332. Sandesh S, Kristachar PKR, Manjunathan P, Halgeri AB, Shanbhag GV (2016) Synthesis of
biodiesel and acetins by transesterification reactions using novel CaSn (OH) 6 heterogeneous
base catalyst. Appl Catal A Gen 523:1–11. https://doi.org/10.1016/j.apcata.2016.05.006
333. Gonçalves M, Souza VC, Galhardo TS, Mantovani M, Figueiredo FVC, Mandelli D, Carvalho
WA (2013) Glycerol conversion catalyzed by carbons prepared from agro industrial wastes.
Ind Engg Chem Res 52:2832–2839. https://doi.org/10.1021/ie303072d
334. Viswanadham N, Saxena SK (2013) Etherification of glycerol for improved production of
oxygenates. Fuel 103:980–986. https://doi.org/10.1016/j.fuel.2012.06.057
335. Cornejo A, Barrio I, Campoy M, Lázaro J, Navarrete B (2017) Oxygenated fuel additives
from glycerol valorization. Main production pathways and effects on fuel properties and
engine performance: a critical review. Renew Sust Energ Rev 79:1400–1413. https://doi.
org/10.1016/j.rser.2017.04.005
336. Mota CJ, da Silva CXA, Rosenbach N Jr, Costa J, da Silva FV (2010) Glycerin derivatives
as fuel additives: the addition of glycerol/acetone ketal (solketal) in gasolines. Energy Fuel
24:2733–2736. https://doi.org/10.1021/ef9015735
337. Vicente G, Melero JA, Morales G, Paniagua M, Martín E (2010) Acetalization of bioglycerol with acetone to produce solketal over sulfonic mesostructured silicas. Green Chem
12:899–907. https://doi.org/10.1039/B923681C
338. De Torres M, Jimenez-Oses G, Mayoral JA, Pires E, Santos M (2012) Glycerol ketals:
synthesis and profits in biodiesel blends. Fuel 94:614–616. https://doi.org/10.1016/j.
fuel.2011.11.062
339. Nanda MR, Yuan Z, Qin W, Ghaziaskar HS, Poirier M-A, Xu CC (2014) A new continuousflow process for catalytic conversion of glycerol to oxygenated fuel additive: catalyst screening. Appl Energy 123:75–81. https://doi.org/10.1016/j.apenergy.2014.02.055
340. Nanda MR, Yuan Z, Qin W, Ghaziaskar HS, Poirier M-A, Xu CC (2014) Catalytic conversion
of glycerol to oxygenated fuel additive in a continuous flow reactor: process optimization.
Fuel 128:113–119. https://doi.org/10.1016/j.fuel.2014.02.068
341. Umbarkar SB, Kotbagi TV, Biradar AV, Pasricha R, Chanale J, Dongare MK, Mamede A-S,
Lancelot C, Payen E (2009) Acetalization of glycerol using mesoporous MoO 3 /SiO 2 solid
acid catalyst. J Mol Catal A Chem 310:150–158
342. Amin T-K, Amin NAS, Najaafi N, Tarighi S (2018) A review on the catalytic acetalization
of bio-renewable glycerol to fuel additives. Front Chem 6:573. https://doi.org/10.3389/
fchem.2018.00573
343. Ma T, Ding J, Shao R, Xu W, Yun Z (2017) Dehydration of glycerol to acrolein over Wells–
Dawson and Keggin type phospho tungstic acids supported on MCM-41 catalysts. Chem Eng
J 316: 797–806. http://doi:10.1016/j.cej.2017.02.018
344. Gu Y, Liu S, Li C, Cui Q (2013) Selective conversion of glycerol to acrolein over supported
nickel sulfate catalysts. J Catal 301:93–102. https://doi.org/10.1016/j.jcat.2013.01.019
Catalytic Conversion of Alcohols into Value-Added Products