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147. Yang M, Fan D, Wei Y, Tian P, Liu Z (2019) Recent progress in methanol- to-olefins (MTO)
catalysts. Adv Mater 31(50):1902181. https://doi.org/10.1002/adma.201902181
148. Gogate MR (2019) Methanol-to-olefins process technology: current status and future prospects. Pet Sci Technol 37(5):559–565. https://doi.org/10.1080/10916466.2018.1555589
149. Dahl IM, Kolboe S (1996) On the reaction mechanism for hydrocarbon formation from methanol over SAPO-34: 2. Isotopic labeling studies of the co-reaction of propene and methanol.
J Catal 161(1):304–309. https://doi.org/10.1006/jcat.1996.0188
150. Xu, S, Zhi, Y, Han, J, Zhang, W, Wu, X, Sun, T, Wei, Y, Liu, Z, Advances in catalysis for
methanol- to-olefins conversion, Adv Catal, 61:38–118 doi:10.1016/bs.acat.2017.10.002 2017
151. Tian P, Wei Y, Ye M, Liu Z (2015) Methanol-to-olefins (MTO): from fundamentals to commercialization. ACS Catal 5(3):1922–1938. https://doi.org/10.1021/acscatal.5b00007
152. Chang CD (1984) Methanol conversion to light olefins. Catal Rev Sci Eng 26(3–4):323–344.
https://doi.org/10.1080/01614948408064716
153. Koempel, H, Liebner, W (2007) Lurgi’s methanol to propylene (MTP
® ), report on a successful commercialisation, in Natural gas conversion VIII F.B. Noronha, Schmal M, EF SousaAguiar Amsterdam, Elsevier.V:262–267
154. Streb S, Göhna H (2000) Mega methanol. Paving the way for new downstream industries.
World methanol conference, Copenhagen, 8–10 Nov 2000
155. Rothaemel M, Holtmann HD (2001) MTP, methanol to propylene – Lurgi’s way, DGMKconference “creating value from light olefins – production and conversion, Hamburg, 10–12
Oct 2001
156. Rothaemel M (2016) Methanol-to-propylene (MTP
® ): a proven technology for on-purpose
propylene production NGCS 11 conference, Tromso, Norway, 6–9 Jun. doi:10.13140/
RG.2.2.31772.49283
157. Jasper S, Mahmoud M, El-Halwagi A (2015) Techno-economic comparison between two
methanol-to-propylene processes. PRO 3:684–698. https://doi.org/10.3390/pr3030684
158. Amghizar I, Laurien A, Vandewalle KM, Van Geem Guy MB (2017) New trends in olefin
production. Engineering 3:171–178. https://doi.org/10.1016/J.ENG.2017.02.006
159. Adkins H, Perkins PP (1925) Dehydration of alcohol over alumina. J Am Chem Soc
47:1163–1167. https://doi.org/10.1021/ja01681a036
160. Kochar NK, Merims R, Padia AS (1981) Ethylene from ethanol. Chem Eng Prog 6:66–70
161. Fathi-Afshar F, Rudd DF (1980) Biomass ethanol as a chemical feedstock in the United
States. Biotechnol Bioeng XXII:677–679
162. Fan D, Dai D-J, Wu H-S (2013) Ethylene formation by catalytic dehydration of ethanol with
industrial considerations. Materials 6:101–115. https://doi.org/10.3390/ma6010101
163. Tsao U, Zasloff H.B (1979) Production of ethylene from ethanol, US patent, 4134926A
164. Mohsenzadeh A, Zamani A, Mohammad TJ (2017) Bio-ethylene production from ethanol: a review and techno-economical evaluation. Chem Bio Eng Rev 4:1–18. https://doi.
org/10.1002/cben.201600025
165. Hulea V (2018) Toward platform chemicals from bio-based ethylene: heterogeneous catalysts
and processes. ACS Catal 8:3263–−327. https://doi.org/10.1021/acscatal.7b04294
166. Sun J, Wang Y (2014) Recent advances in catalytic conversion of ethanol to chemicals. ACS
Catal 4:1078–1090. https://doi.org/10.1021/cs4011343
167. Al-Ali AlMa’adeed M, Krupa I (2016) Polyolefin compounds and materials: fundamentals
and industrial applications. Springer, Berlin
168. Al-Jarallah AM, Anabtawi JA, Siddiqui MAB, Aitani AM, Alsa’doun AW (1992)
Part 1 dimerization of ethylene to butene-1. Catal Today 14:1–−121. https://doi.
org/10.1016/0920- 5861(92)80128- A
169. McGuinness DS (2011) Olefin oligomerization via metallacycles: dimerization, trimerization, tetramerization, and beyond. Chem Rev 111:2321–2341. https://doi.org/10.1021/
cr100217q
R. Vinayagamoorthi et al.
147. Yang M, Fan D, Wei Y, Tian P, Liu Z (2019) Recent progress in methanol- to-olefins (MTO)
catalysts. Adv Mater 31(50):1902181. https://doi.org/10.1002/adma.201902181
148. Gogate MR (2019) Methanol-to-olefins process technology: current status and future prospects. Pet Sci Technol 37(5):559–565. https://doi.org/10.1080/10916466.2018.1555589
149. Dahl IM, Kolboe S (1996) On the reaction mechanism for hydrocarbon formation from methanol over SAPO-34: 2. Isotopic labeling studies of the co-reaction of propene and methanol.
J Catal 161(1):304–309. https://doi.org/10.1006/jcat.1996.0188
150. Xu, S, Zhi, Y, Han, J, Zhang, W, Wu, X, Sun, T, Wei, Y, Liu, Z, Advances in catalysis for
methanol- to-olefins conversion, Adv Catal, 61:38–118 doi:10.1016/bs.acat.2017.10.002 2017
151. Tian P, Wei Y, Ye M, Liu Z (2015) Methanol-to-olefins (MTO): from fundamentals to commercialization. ACS Catal 5(3):1922–1938. https://doi.org/10.1021/acscatal.5b00007
152. Chang CD (1984) Methanol conversion to light olefins. Catal Rev Sci Eng 26(3–4):323–344.
https://doi.org/10.1080/01614948408064716
153. Koempel, H, Liebner, W (2007) Lurgi’s methanol to propylene (MTP
® ), report on a successful commercialisation, in Natural gas conversion VIII F.B. Noronha, Schmal M, EF SousaAguiar Amsterdam, Elsevier.V:262–267
154. Streb S, Göhna H (2000) Mega methanol. Paving the way for new downstream industries.
World methanol conference, Copenhagen, 8–10 Nov 2000
155. Rothaemel M, Holtmann HD (2001) MTP, methanol to propylene – Lurgi’s way, DGMKconference “creating value from light olefins – production and conversion, Hamburg, 10–12
Oct 2001
156. Rothaemel M (2016) Methanol-to-propylene (MTP
® ): a proven technology for on-purpose
propylene production NGCS 11 conference, Tromso, Norway, 6–9 Jun. doi:10.13140/
RG.2.2.31772.49283
157. Jasper S, Mahmoud M, El-Halwagi A (2015) Techno-economic comparison between two
methanol-to-propylene processes. PRO 3:684–698. https://doi.org/10.3390/pr3030684
158. Amghizar I, Laurien A, Vandewalle KM, Van Geem Guy MB (2017) New trends in olefin
production. Engineering 3:171–178. https://doi.org/10.1016/J.ENG.2017.02.006
159. Adkins H, Perkins PP (1925) Dehydration of alcohol over alumina. J Am Chem Soc
47:1163–1167. https://doi.org/10.1021/ja01681a036
160. Kochar NK, Merims R, Padia AS (1981) Ethylene from ethanol. Chem Eng Prog 6:66–70
161. Fathi-Afshar F, Rudd DF (1980) Biomass ethanol as a chemical feedstock in the United
States. Biotechnol Bioeng XXII:677–679
162. Fan D, Dai D-J, Wu H-S (2013) Ethylene formation by catalytic dehydration of ethanol with
industrial considerations. Materials 6:101–115. https://doi.org/10.3390/ma6010101
163. Tsao U, Zasloff H.B (1979) Production of ethylene from ethanol, US patent, 4134926A
164. Mohsenzadeh A, Zamani A, Mohammad TJ (2017) Bio-ethylene production from ethanol: a review and techno-economical evaluation. Chem Bio Eng Rev 4:1–18. https://doi.
org/10.1002/cben.201600025
165. Hulea V (2018) Toward platform chemicals from bio-based ethylene: heterogeneous catalysts
and processes. ACS Catal 8:3263–−327. https://doi.org/10.1021/acscatal.7b04294
166. Sun J, Wang Y (2014) Recent advances in catalytic conversion of ethanol to chemicals. ACS
Catal 4:1078–1090. https://doi.org/10.1021/cs4011343
167. Al-Ali AlMa’adeed M, Krupa I (2016) Polyolefin compounds and materials: fundamentals
and industrial applications. Springer, Berlin
168. Al-Jarallah AM, Anabtawi JA, Siddiqui MAB, Aitani AM, Alsa’doun AW (1992)
Part 1 dimerization of ethylene to butene-1. Catal Today 14:1–−121. https://doi.
org/10.1016/0920- 5861(92)80128- A
169. McGuinness DS (2011) Olefin oligomerization via metallacycles: dimerization, trimerization, tetramerization, and beyond. Chem Rev 111:2321–2341. https://doi.org/10.1021/
cr100217q
R. Vinayagamoorthi et al.