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org/10.1007/s00253- 013- 4861- 6
59. Choi YJ, Lee J, Jang YS, Lee SY (2014) Metabolic engineering of microorganisms for
the production of higher alcohols. MBio 5(5):e01524–e01514. https://doi.org/10.1128/
mBio.01524- 14
60. Jang YS, Kim B, Shin JH, Choi YJ, Choi S, Song CW, Lee J, Park HG, Lee SY (2012)
Bio-based production of C2-C6 platform chemicals. Biotechnol Bioeng 109(10):2437–2459.
https://doi.org/10.1002/bit.24599
61. Inokuma K, Liao JC, Okamoto M, Hanai T (2010) Improvement of isopropanol production by metabolically engineered Escherichia coli using gas stripping. J Biosci Bioeng
110(6):696–701. https://doi.org/10.1016/j.jbiosc.2010.07.010
62. Sada M et al (1981) US patent 4307257, 22 Dec 1981
63. Harvey BG, Meylemans HA (2011) The role of butanol in the development of sustainable
fuel technologies. J Chem Technol Biotechnol 86:2–9. https://doi.org/10.1002/jctb.2540
64. Xue C, Zhao XQ, Liu CG, Chen LJ, Bai FW (2013) Prospective and development of butanol as an advanced biofuel. Biotechnol Adv 31:1575–1584. https://doi.org/10.1016/j.
biotechadv.2013.08.004
65. Gautam M, Martin DW (2000) Combustion characteristics of higher-alcohol/gasoline blends.
Proc Inst Mech Eng A J Power Energy 214:497–511. doi:10.1243%2F0957650001538047
66. Thompson R, Behnam M, Swana J, Yang Y (2011) An analysis of net energy production
and feed-stock availability for biobutanol and bioethanol. Bioresour Technol 102:2112–2117.
https://doi.org/10.1016/j.biortech.2010.08.051
67. Singh SB, Dhar A, Agarwal AK (2015) Technical feasibility study of butanol as gasoline
blends for powering medium-duty transportation spark ignition engine. Renew Energy
76:706–716. https://doi.org/10.1016/j.renene.2014.11.095
68. Derre P (2007) Biotechnol J Rep 2:1525–1534
69. Ndaba B, Chiyanzu I, Marx S (2015) n-Butanol derived from biochemical and chemical
routes: a review. Biotechnol Rep 8:1–9. https://doi.org/10.1016/j.btre.2015.08.001
70. n-Butanol market by application (butyl acrylate, butyl acetate, glycol ethers, direct solvents,
plasticizers), and region (Asia Pacific, North America, Europe, Middle East & Africa, South
America)—Global Forecast to 2022: a report (CH1543) 2018
71. Hahn HD, Dambkes G, Rupprich N, Bahl H, Frey GD (2013) Butanols. Ullmann’s encyclopedia of industrial chemistry. doi:10.1002/14356007.a04_463.pub3
72. Spivey JJ, Groppi G, Cristiani C, Forzatti P (1997) Preparation and characterization of
hexaaluminate materials for high-temperature catalytic combustion. Catalysis 13:209. https://
doi.org/10.1039/9781847553256
73. Guerbet MCR (1899) Acad Sci Paris 128:1002–1004
74. Guerbet MCR (1909) Acad Sci Paris 149:129–132
75. Kozlowski J T, Davis RJ (2013) Heterogeneous catalysts for the Guerbet coupling of alcohols. ACS Catal 3:1588–1600. https://pubs.acs.org/doi/10.1021/cs400292f
76. Aitchison H, Wingad RL, Wass DF (2016) Homogeneous ethanol to butanol catalysis. ACS
Catal Guerbet Renewed 6:7125–7132. https://doi.org/10.1021/acscatal.6b01883
77. Wu X, Fang G, Tong Y, Jiang D, Liang Z, Leng W, Liu L, Tu P, Wang H, Ni J, Li X (2018)
Catalytic upgrading of ethanol to n-butanol: progress in catalyst development. ChemSusChem
11:71–85. https://doi.org/10.1002/cssc.201701590
78. Dowson GRM, Haddow MF, Lee J, Wingad RL, Wass DF (2013) Catalytic conversion of
ethanol into an advanced biofuel: unprecedented selectivity for n-butanol. Angew Chem Int
Ed 52:9005–9008. https://doi.org/10.1002/anie.201303723
79. Jang YS, Malaviya A, Cho C, Lee J, Lee SY (2012) Butanol production from renewable biomass by Clostridia. Bioresour Technol 123:653–663. https://doi.org/10.1016/j.
biortech.2012.07.104
R. Vinayagamoorthi et al.
58. Ammar EM, Wang Z, Yang ST (2013) Metabolic engineering of Propionibacterium freudenreichii for n-propanol production. Appl Microbiol Biotechnol 97(10):4677–4690. https://doi.
org/10.1007/s00253- 013- 4861- 6
59. Choi YJ, Lee J, Jang YS, Lee SY (2014) Metabolic engineering of microorganisms for
the production of higher alcohols. MBio 5(5):e01524–e01514. https://doi.org/10.1128/
mBio.01524- 14
60. Jang YS, Kim B, Shin JH, Choi YJ, Choi S, Song CW, Lee J, Park HG, Lee SY (2012)
Bio-based production of C2-C6 platform chemicals. Biotechnol Bioeng 109(10):2437–2459.
https://doi.org/10.1002/bit.24599
61. Inokuma K, Liao JC, Okamoto M, Hanai T (2010) Improvement of isopropanol production by metabolically engineered Escherichia coli using gas stripping. J Biosci Bioeng
110(6):696–701. https://doi.org/10.1016/j.jbiosc.2010.07.010
62. Sada M et al (1981) US patent 4307257, 22 Dec 1981
63. Harvey BG, Meylemans HA (2011) The role of butanol in the development of sustainable
fuel technologies. J Chem Technol Biotechnol 86:2–9. https://doi.org/10.1002/jctb.2540
64. Xue C, Zhao XQ, Liu CG, Chen LJ, Bai FW (2013) Prospective and development of butanol as an advanced biofuel. Biotechnol Adv 31:1575–1584. https://doi.org/10.1016/j.
biotechadv.2013.08.004
65. Gautam M, Martin DW (2000) Combustion characteristics of higher-alcohol/gasoline blends.
Proc Inst Mech Eng A J Power Energy 214:497–511. doi:10.1243%2F0957650001538047
66. Thompson R, Behnam M, Swana J, Yang Y (2011) An analysis of net energy production
and feed-stock availability for biobutanol and bioethanol. Bioresour Technol 102:2112–2117.
https://doi.org/10.1016/j.biortech.2010.08.051
67. Singh SB, Dhar A, Agarwal AK (2015) Technical feasibility study of butanol as gasoline
blends for powering medium-duty transportation spark ignition engine. Renew Energy
76:706–716. https://doi.org/10.1016/j.renene.2014.11.095
68. Derre P (2007) Biotechnol J Rep 2:1525–1534
69. Ndaba B, Chiyanzu I, Marx S (2015) n-Butanol derived from biochemical and chemical
routes: a review. Biotechnol Rep 8:1–9. https://doi.org/10.1016/j.btre.2015.08.001
70. n-Butanol market by application (butyl acrylate, butyl acetate, glycol ethers, direct solvents,
plasticizers), and region (Asia Pacific, North America, Europe, Middle East & Africa, South
America)—Global Forecast to 2022: a report (CH1543) 2018
71. Hahn HD, Dambkes G, Rupprich N, Bahl H, Frey GD (2013) Butanols. Ullmann’s encyclopedia of industrial chemistry. doi:10.1002/14356007.a04_463.pub3
72. Spivey JJ, Groppi G, Cristiani C, Forzatti P (1997) Preparation and characterization of
hexaaluminate materials for high-temperature catalytic combustion. Catalysis 13:209. https://
doi.org/10.1039/9781847553256
73. Guerbet MCR (1899) Acad Sci Paris 128:1002–1004
74. Guerbet MCR (1909) Acad Sci Paris 149:129–132
75. Kozlowski J T, Davis RJ (2013) Heterogeneous catalysts for the Guerbet coupling of alcohols. ACS Catal 3:1588–1600. https://pubs.acs.org/doi/10.1021/cs400292f
76. Aitchison H, Wingad RL, Wass DF (2016) Homogeneous ethanol to butanol catalysis. ACS
Catal Guerbet Renewed 6:7125–7132. https://doi.org/10.1021/acscatal.6b01883
77. Wu X, Fang G, Tong Y, Jiang D, Liang Z, Leng W, Liu L, Tu P, Wang H, Ni J, Li X (2018)
Catalytic upgrading of ethanol to n-butanol: progress in catalyst development. ChemSusChem
11:71–85. https://doi.org/10.1002/cssc.201701590
78. Dowson GRM, Haddow MF, Lee J, Wingad RL, Wass DF (2013) Catalytic conversion of
ethanol into an advanced biofuel: unprecedented selectivity for n-butanol. Angew Chem Int
Ed 52:9005–9008. https://doi.org/10.1002/anie.201303723
79. Jang YS, Malaviya A, Cho C, Lee J, Lee SY (2012) Butanol production from renewable biomass by Clostridia. Bioresour Technol 123:653–663. https://doi.org/10.1016/j.
biortech.2012.07.104
R. Vinayagamoorthi et al.