497
51. García-Sancho C, Cecilia JA, Mérida-Robles JM, González JS, Moreno-Tost R, InfantesMolina A, Maireles-Torres P (2018) Effect of the treatment with H 3 PO 4 on the catalytic
activity of Nb 2 O 5 supported on Zr-doped mesoporous silica catalyst. Case study: glycerol
dehydration. Appl Catal B Environ 221:158–168
52. Fernandes A, Ribeiro MF, Lourenço JP (2017) Gas-phase dehydration of glycerol over hierarchical silicoaluminophosphate SAPO-40. Catal Commun 95:16–20
53. Lopez-Pedrajas S, Estevez R, Navarro R, Luna D, Bautista FM (2016) Catalytic behaviour of
mesoporous metal phosphates in the gas-phase glycerol transformation. J Mol Catal A Chem
421:92–101
54. Lourenço JP, Fernandes A, Bertolo RA, Ribeiro MF (2015) Gas-phase dehydration of glycerol over thermally stable SAPO-40 catalyst. RSC Adv 5:10667–10674
55. Deleplanque J, Dubois JL, Devaux JF, Ueda W (2010) Production of acrolein and acrylic acid
through dehydration and oxydehydration of glycerol with mixed oxide catalysts. Catal Tod
157:351–358
56. Suprun W, Lutecki M, Haber T, Papp H (2009) Acidic catalysts for the dehydration of glycerol: activity and deactivation. J Mol Catal A Chem 309:71–78
57. Chai SH, Wang HP, Liang Y, Xu BQ (2008) Sustainable production of acrolein: gas-phase
dehydration of glycerol over 12-tungstophosphoric acid supported on ZrO 2 and SiO 2 . Green
Chem 10:1087–1093
58. Viswanadham B, Nagaraju N, Rohitha CN, Vishwanathan V, Chary KVR (2017) Synthesis,
characterization and catalytic dehydration of glycerol to acrolein over phosphotungstic acid
supported Y-zeolite catalysts. Catal Lett 148:397–406
59. Chai SH, Wang HP, Liang Y, Xu BQ (2009) Sustainable production of acrolein: preparation
and characterization of zirconia-supported 12-tungstophosphoric acid catalyst for gas-phase
dehydration of glycerol. Appl Catal A Gen 353:213–222
60. Haider MH, Dummer NF, Zhang D, Miedziak P, Davies TE, Taylor SH, Willock DJ, Knight
DW, Chadwick D, Hutchings GJ (2012) Rubidium- and caesium-doped silicotungstic acid
catalysts supported on alumina for the catalytic dehydration of glycerol to acrolein. J Catal
286:206–213
61. Tsukuda E, Sato S, Takahashi R, Sodesawa T (2007) Production of acrolein from glycerol
over silica-supported heteropoly acids. Catal Commun 8:1349–1353
62. Atia H, Armbruster U, Martin A (2011) Influence of alkaline metal on performance of supported silicotungstic acid catalysts in glycerol dehydration towards acrolein. Appl Catal A
Gen 393:331–339
63. Liu L, Wang B, Du Y, Borgna Y (2015) Supported H 4 SiW 12 O 40 /Al 2 O 3 solid acid catalysts
for dehydration of glycerol to acrolein: evolution of catalyst structure and performance with
calcination temperature. Appl Catal A Gen 489:32–41
64. Talebian-Kiakalaieh A, Amin NAS (2015) Supported silicotungstic acid on zirconia catalyst
for gas phase dehydration of glycerol to acrolein. Catal Today 256:315–324
65. Talebian-Kiakalaieh A, Amin NAS, Zakaria ZY (2016) Gas phase selective conversion of
glycerol to acrolein over supported silicotungstic acid catalyst. J Ind Eng Chem 34:300–312
66. Gu Y, Liu S, Li C, Cui Q (2013) Selective conversion of glycerol to acrolein over supported
nickel sulfate catalysts. J Catal 301:93–102
67. Huang L, Qin F, Huang Z, Zhuang Y, Ma J, Xu H, Shen W (2017) Metal organic frameworkmediated synthesis of small-sized γ-alumina as highly active catalyst for dehydration of glycerol to acrolein. ChemCatChem 10:381–386
68. Zhou CH, Li GL, Zhuang XY, Wang PP, Tong DS, Yang HM, Lin CX, Li L, Zhang H, Ji SF,
Yu WH (2017) Roles of texture and acidity of acid-activated sepiolite catalysts in gas-phase
catalytic dehydration of glycerol to acrolein. Mol Catal 434:219–231
69. Xie Q, Li S, Gong R, Zheng G, Wang Y, Xu P, Duan Y, Yu S, Lu M, Ji W, Nie Y, Ji J (2019)
Microwave-assisted catalytic dehydration of glycerol for sustainable production of acrolein
over a microwave absorbing catalyst. Appl Catal B Environ 243:455–462
Catalytic Conversion of Biomass-Derived Glycerol to Value-Added Chemicals
51. García-Sancho C, Cecilia JA, Mérida-Robles JM, González JS, Moreno-Tost R, InfantesMolina A, Maireles-Torres P (2018) Effect of the treatment with H 3 PO 4 on the catalytic
activity of Nb 2 O 5 supported on Zr-doped mesoporous silica catalyst. Case study: glycerol
dehydration. Appl Catal B Environ 221:158–168
52. Fernandes A, Ribeiro MF, Lourenço JP (2017) Gas-phase dehydration of glycerol over hierarchical silicoaluminophosphate SAPO-40. Catal Commun 95:16–20
53. Lopez-Pedrajas S, Estevez R, Navarro R, Luna D, Bautista FM (2016) Catalytic behaviour of
mesoporous metal phosphates in the gas-phase glycerol transformation. J Mol Catal A Chem
421:92–101
54. Lourenço JP, Fernandes A, Bertolo RA, Ribeiro MF (2015) Gas-phase dehydration of glycerol over thermally stable SAPO-40 catalyst. RSC Adv 5:10667–10674
55. Deleplanque J, Dubois JL, Devaux JF, Ueda W (2010) Production of acrolein and acrylic acid
through dehydration and oxydehydration of glycerol with mixed oxide catalysts. Catal Tod
157:351–358
56. Suprun W, Lutecki M, Haber T, Papp H (2009) Acidic catalysts for the dehydration of glycerol: activity and deactivation. J Mol Catal A Chem 309:71–78
57. Chai SH, Wang HP, Liang Y, Xu BQ (2008) Sustainable production of acrolein: gas-phase
dehydration of glycerol over 12-tungstophosphoric acid supported on ZrO 2 and SiO 2 . Green
Chem 10:1087–1093
58. Viswanadham B, Nagaraju N, Rohitha CN, Vishwanathan V, Chary KVR (2017) Synthesis,
characterization and catalytic dehydration of glycerol to acrolein over phosphotungstic acid
supported Y-zeolite catalysts. Catal Lett 148:397–406
59. Chai SH, Wang HP, Liang Y, Xu BQ (2009) Sustainable production of acrolein: preparation
and characterization of zirconia-supported 12-tungstophosphoric acid catalyst for gas-phase
dehydration of glycerol. Appl Catal A Gen 353:213–222
60. Haider MH, Dummer NF, Zhang D, Miedziak P, Davies TE, Taylor SH, Willock DJ, Knight
DW, Chadwick D, Hutchings GJ (2012) Rubidium- and caesium-doped silicotungstic acid
catalysts supported on alumina for the catalytic dehydration of glycerol to acrolein. J Catal
286:206–213
61. Tsukuda E, Sato S, Takahashi R, Sodesawa T (2007) Production of acrolein from glycerol
over silica-supported heteropoly acids. Catal Commun 8:1349–1353
62. Atia H, Armbruster U, Martin A (2011) Influence of alkaline metal on performance of supported silicotungstic acid catalysts in glycerol dehydration towards acrolein. Appl Catal A
Gen 393:331–339
63. Liu L, Wang B, Du Y, Borgna Y (2015) Supported H 4 SiW 12 O 40 /Al 2 O 3 solid acid catalysts
for dehydration of glycerol to acrolein: evolution of catalyst structure and performance with
calcination temperature. Appl Catal A Gen 489:32–41
64. Talebian-Kiakalaieh A, Amin NAS (2015) Supported silicotungstic acid on zirconia catalyst
for gas phase dehydration of glycerol to acrolein. Catal Today 256:315–324
65. Talebian-Kiakalaieh A, Amin NAS, Zakaria ZY (2016) Gas phase selective conversion of
glycerol to acrolein over supported silicotungstic acid catalyst. J Ind Eng Chem 34:300–312
66. Gu Y, Liu S, Li C, Cui Q (2013) Selective conversion of glycerol to acrolein over supported
nickel sulfate catalysts. J Catal 301:93–102
67. Huang L, Qin F, Huang Z, Zhuang Y, Ma J, Xu H, Shen W (2017) Metal organic frameworkmediated synthesis of small-sized γ-alumina as highly active catalyst for dehydration of glycerol to acrolein. ChemCatChem 10:381–386
68. Zhou CH, Li GL, Zhuang XY, Wang PP, Tong DS, Yang HM, Lin CX, Li L, Zhang H, Ji SF,
Yu WH (2017) Roles of texture and acidity of acid-activated sepiolite catalysts in gas-phase
catalytic dehydration of glycerol to acrolein. Mol Catal 434:219–231
69. Xie Q, Li S, Gong R, Zheng G, Wang Y, Xu P, Duan Y, Yu S, Lu M, Ji W, Nie Y, Ji J (2019)
Microwave-assisted catalytic dehydration of glycerol for sustainable production of acrolein
over a microwave absorbing catalyst. Appl Catal B Environ 243:455–462
Catalytic Conversion of Biomass-Derived Glycerol to Value-Added Chemicals