87. Barrett BJ, Iluc VM (2014) Coordination of a hemilabile pincer ligand with an olefinic
backbone to mid-to-late transition metals. Inorg Chem 53:7248–7259
88. Barrett BJ, Iluc VM (2014) Group 10 metal complexes supported by pincer ligands with an
olefinic backbone. Organometallics 33:2565–2574
89. Bennett MA, Clark PW (1976) Tridentate chelate π-bonded complexes of rhodium(I), iridium
(I), and iridium(III) and chelate σ-bonded complexes of nickel(II), palladium(II), and platinum
(II) formed by intramolecular hydrogen abstraction reactions. J Organomet Chem
110:367–381
90. Baratta W, Herdtweck E, Martinuzzi P, Rigo P (2001) CarbonÀcarbon double bond formation
from two o-methyl groups in osmium phosphine complexes. Organometallics 20:305–308
91. Campos J, Ortega-Moreno L, Conejero S, Peloso R, López-Serrano J, Maya C, Carmona E
(2015) Reactivity of cationic Agostic and Carbene structures derived from platinum
(II) metallacycles. Chem Eur J 21:8883–8896
92. Barrett BJ, Iluc VM (2017) Metal-ligand cooperation between palladium and a diphosphine
ligand with an olefinic backbone. Inorg Chim Acta 460:35–42
93. Bennett MA, Johnson RN, Tomkins IB (1976) Additions to metal atom and to coordinated
ligand in complexes of rhodium(I) and iridium(I) formed by a tridentate olefinic ditertiary
phosphine: chelate olefin complexes and σ-alkyls of rhodium(III) and iridium(III). J
Organomet Chem 118:205–232
94. Jing Q, Sandoval CA, Wang Z, Ding K (2006) Complete chiral induction from Enantiopure
1,2-diamines to benzophenone-based achiral Bisphosphane ligands in Noyori-type RuII catalysts. Eur J Org Chem 2006:3606–3616
95. Saes BWH, Verhoeven DGA, Lutz M, Klein Gebbink RJM, Moret ME (2015) Coordination of
a diphosphine–ketone ligand to Ni(0), Ni(I), and Ni(II): reduction-induced coordination.
Organometallics 34:2710–2713
96. Verhoeven DGA, van Wiggen MAC, Kwakernaak J, Lutz M, Klein Gebbink RJM, Moret ME
(2018) Periodic trends in the binding of a phosphine-tethered ketone ligand to Fe, Co, Ni, and
Cu. Chem Eur J 24:5163–5172
97. Sung S, Wang Q, Krämer T, Young RD (2018) Synthesis and reactivity of a PCcarbeneP
cobalt(i) complex: the missing link in the cobalt PXP pincer series (X ¼ B, C, N). Chem Sci
9:8234–8241
98. Rothstein PE, Comanescu CC, Iluc VM (2017) Formation of palladium η2-bound
Chalcogenoketones across a Pd+ÀCÀ bond. Chem Eur J 23:16948–16952
99. Sung S, Boon JK, Lee JJC, Rajabi NA, Macgregor SA, Krämer T, Young RD (2017)
Convergent (De)hydrogenative pathways via a rhodium α-hydroxylalkyl complex. Organometallics 36:1609–1617
100. Orsino AF, Gutiérrez del Campo M, Lutz M, Moret M-E (2019) Enhanced catalytic activity of
nickel complexes of an adaptive diphosphine–benzophenone ligand in alkyne
cyclotrimerization. ACS Catal 9:2458–2481
101. Orsino AF, Moret M-E (2020) Nickel-catalyzed alkyne cyclotrimerization assisted by a
hemilabile acceptor ligand: a computational study. Organometallics 39:1998–2010
102. Sung S, Young RD (2017) Facile generation of iridium PCcarbeneP pincer complexes via
water elimination from an alcohol proligand. Dalton Trans 46:15407–15414
103. Sung S, Joachim T, Krämer T, Young RD (2017) Protonolysis of an α-hydroxyl ligand for the
generation of a PCcarbeneP pincer complex and subsequent reactivity studies. Organometallics 36:3117–3124
104. Doyle LE, Piers WE, Borau-Garcia J (2015) Ligand cooperation in the formal hydrogenation
of N2O using a PCsp2P iridium pincer complex. J Am Chem Soc 137:2187–2190
105. Doyle LE, Piers WE, Borau-Garcia J, Sgro MJ, Spasyuk DM (2016) Mechanistic studies on
the addition of hydrogen to iridaepoxide complexes with subsequent elimination of water.
Chem Sci 7:921–931
106. Doyle LE, Piers WE, Bi DW (2017) Cationic PCP iridaepoxide and carbene complexes for
facile water elimination and activation processes. Dalton Trans 46:4346–4354
68
M. R. Tiddens and M.-E. Moret
backbone to mid-to-late transition metals. Inorg Chem 53:7248–7259
88. Barrett BJ, Iluc VM (2014) Group 10 metal complexes supported by pincer ligands with an
olefinic backbone. Organometallics 33:2565–2574
89. Bennett MA, Clark PW (1976) Tridentate chelate π-bonded complexes of rhodium(I), iridium
(I), and iridium(III) and chelate σ-bonded complexes of nickel(II), palladium(II), and platinum
(II) formed by intramolecular hydrogen abstraction reactions. J Organomet Chem
110:367–381
90. Baratta W, Herdtweck E, Martinuzzi P, Rigo P (2001) CarbonÀcarbon double bond formation
from two o-methyl groups in osmium phosphine complexes. Organometallics 20:305–308
91. Campos J, Ortega-Moreno L, Conejero S, Peloso R, López-Serrano J, Maya C, Carmona E
(2015) Reactivity of cationic Agostic and Carbene structures derived from platinum
(II) metallacycles. Chem Eur J 21:8883–8896
92. Barrett BJ, Iluc VM (2017) Metal-ligand cooperation between palladium and a diphosphine
ligand with an olefinic backbone. Inorg Chim Acta 460:35–42
93. Bennett MA, Johnson RN, Tomkins IB (1976) Additions to metal atom and to coordinated
ligand in complexes of rhodium(I) and iridium(I) formed by a tridentate olefinic ditertiary
phosphine: chelate olefin complexes and σ-alkyls of rhodium(III) and iridium(III). J
Organomet Chem 118:205–232
94. Jing Q, Sandoval CA, Wang Z, Ding K (2006) Complete chiral induction from Enantiopure
1,2-diamines to benzophenone-based achiral Bisphosphane ligands in Noyori-type RuII catalysts. Eur J Org Chem 2006:3606–3616
95. Saes BWH, Verhoeven DGA, Lutz M, Klein Gebbink RJM, Moret ME (2015) Coordination of
a diphosphine–ketone ligand to Ni(0), Ni(I), and Ni(II): reduction-induced coordination.
Organometallics 34:2710–2713
96. Verhoeven DGA, van Wiggen MAC, Kwakernaak J, Lutz M, Klein Gebbink RJM, Moret ME
(2018) Periodic trends in the binding of a phosphine-tethered ketone ligand to Fe, Co, Ni, and
Cu. Chem Eur J 24:5163–5172
97. Sung S, Wang Q, Krämer T, Young RD (2018) Synthesis and reactivity of a PCcarbeneP
cobalt(i) complex: the missing link in the cobalt PXP pincer series (X ¼ B, C, N). Chem Sci
9:8234–8241
98. Rothstein PE, Comanescu CC, Iluc VM (2017) Formation of palladium η2-bound
Chalcogenoketones across a Pd+ÀCÀ bond. Chem Eur J 23:16948–16952
99. Sung S, Boon JK, Lee JJC, Rajabi NA, Macgregor SA, Krämer T, Young RD (2017)
Convergent (De)hydrogenative pathways via a rhodium α-hydroxylalkyl complex. Organometallics 36:1609–1617
100. Orsino AF, Gutiérrez del Campo M, Lutz M, Moret M-E (2019) Enhanced catalytic activity of
nickel complexes of an adaptive diphosphine–benzophenone ligand in alkyne
cyclotrimerization. ACS Catal 9:2458–2481
101. Orsino AF, Moret M-E (2020) Nickel-catalyzed alkyne cyclotrimerization assisted by a
hemilabile acceptor ligand: a computational study. Organometallics 39:1998–2010
102. Sung S, Young RD (2017) Facile generation of iridium PCcarbeneP pincer complexes via
water elimination from an alcohol proligand. Dalton Trans 46:15407–15414
103. Sung S, Joachim T, Krämer T, Young RD (2017) Protonolysis of an α-hydroxyl ligand for the
generation of a PCcarbeneP pincer complex and subsequent reactivity studies. Organometallics 36:3117–3124
104. Doyle LE, Piers WE, Borau-Garcia J (2015) Ligand cooperation in the formal hydrogenation
of N2O using a PCsp2P iridium pincer complex. J Am Chem Soc 137:2187–2190
105. Doyle LE, Piers WE, Borau-Garcia J, Sgro MJ, Spasyuk DM (2016) Mechanistic studies on
the addition of hydrogen to iridaepoxide complexes with subsequent elimination of water.
Chem Sci 7:921–931
106. Doyle LE, Piers WE, Bi DW (2017) Cationic PCP iridaepoxide and carbene complexes for
facile water elimination and activation processes. Dalton Trans 46:4346–4354
68
M. R. Tiddens and M.-E. Moret