45. Schneider S, Meiners J, Askevold B (2012) Cooperative aliphatic PNP Amido pincer ligands –
versatile building blocks for coordination chemistry and catalysis. Eur J Inorg Chem
2012:412–429
46. Alig L, Fritz M, Schneider S (2019) First-row transition metal (De)hydrogenation catalysis
based on functional pincer ligands. Chem Rev 119:2681–2751
47. van der Vlugt JI, Reek JNH (2009) Neutral tridentate PNP ligands and their hybrid analogues:
versatile non-innocent scaffolds for homogeneous catalysis. Angew Chem Int Ed
48:8832–8846
48. Budweg S, Junge K, Beller M (2020) Catalytic oxidations by dehydrogenation of alkanes,
alcohols and amines with defined (non)-noble metal pincer complexes. Cat Sci Technol
10:3825–3842
49. Tondreau AM, Atienza CCH, Weller KJ, Nye SA, Lewis KM, Delis JGP, Chirik PJ (2012)
Iron catalysts for selective anti-Markovnikov alkene hydrosilylation using tertiary silanes.
Science 335:567
50. Green MLH (1995) A new approach to the formal classification of covalent compounds of the
elements. J Organomet Chem 500:127–148
51. Hill AF, Owen GR, White AJP, Williams DJ (1999) The sting of the scorpion: a
metallaboratrane. Angew Chem Int Ed 38:2759–2761
52. Bontemps S, Bouhadir G, Gu W, Mercy M, Chen CH, Foxman BM, Maron L, Ozerov OV,
Bourissou D (2008) Metallaboratranes derived from a triphosphanyl–borane: intrinsic C3
symmetry supported by a Z-type ligand. Angew Chem Int Ed 47:1481–1484
53. Bourissou D, Bouhadir G (2016) Ambiphilic ligands: unusual coordination and reactivity
arising from Lewis acid moieties. In: Stradiotto M, Lundgren RJ (eds) Ligand design in metal
chemistry: reactivity and catalysis. Wiley, New York, pp 237–269
54. Bontemps S, Bouhadir G, Dyer PW, Miqueu K, Bourissou D (2007) Quasi-Thermoneutral P
! B interactions within Di- and tri-phosphine boranes. Inorg Chem 46:5149–5151
55. Sircoglou M, Bontemps S, Bouhadir G et al (2008) Group 10 and 11 metal boratranes (Ni, Pd,
Pt, CuCl, AgCl, AuCl, and Au+) derived from a triphosphineÀborane. J Am Chem Soc
130:16729–16738
56. Bontemps S, Gornitzka H, Bouhadir G, Saffon N, Miqueu K, Gu W, Mercy M, Chen CH,
Foxman BM, Maron L, Ozerov OV, Bourissou D (2006) Rhodium(I) complexes of a PBP
ambiphilic ligand: evidence for a metal!borane interaction. Angew Chem Int Ed
45:1611–1614
57. Harman WH, Peters JC (2012) Reversible H2 addition across a nickel–borane unit as a
promising strategy for catalysis. J Am Chem Soc 134:5080–5082
58. Sircoglou M, Bontemps S, Mercy M, Miqueu K, Ladeira S, Saffon N, Maron L, Bouhadir G,
Bourissou D (2010) Copper(I) complexes derived from mono- and diphosphino-boranes:
Cu!B interactions supported by arene coordination. Inorg Chem 49:3983–3990
59. Schindler T, Lux M, Peters M, Scharf LT, Osseili H, Maron L, Tauchert ME (2015) Synthesis
and reactivity of palladium complexes featuring a diphosphinoborane ligand. Organometallics
34:1978–1984
60. Cao Y, Shih W-C, Bhuvanesh N, Ozerov OV (2019) Silver halide complexes of a borane/bis
(phosphine) ligand. Dalton Trans 48:9959–9961
61. Sircoglou M, Bontemps S, Mercy M, Saffon N, Takahashi M, Bouhadir G, Maron L,
Bourissou D (2007) Transition-metal complexes featuring Z-type ligands: agreement or
discrepancy between geometry and dn configuration? Angew Chem Int Ed 46:8583–8586
62. Tauchert ME, Steinhoff P (2016) A T-shape diphosphinoborane palladium(0) complex.
Beilstein J Org Chem 12:1573–1576
63. Inagaki F, Matsumoto C, Okada Y, Maruyama N, Mukai C (2015) Air-stable cationic gold
(I) catalyst featuring a Z-type ligand: promoting enyne cyclizations. Angew Chem Int Ed
54:818–822
64. Murakami R, Inagaki F (2019) Recent topics of gold catalyst featuring Z-type ligands.
Tetrahedron Lett 60:151231
66
M. R. Tiddens and M.-E. Moret
versatile building blocks for coordination chemistry and catalysis. Eur J Inorg Chem
2012:412–429
46. Alig L, Fritz M, Schneider S (2019) First-row transition metal (De)hydrogenation catalysis
based on functional pincer ligands. Chem Rev 119:2681–2751
47. van der Vlugt JI, Reek JNH (2009) Neutral tridentate PNP ligands and their hybrid analogues:
versatile non-innocent scaffolds for homogeneous catalysis. Angew Chem Int Ed
48:8832–8846
48. Budweg S, Junge K, Beller M (2020) Catalytic oxidations by dehydrogenation of alkanes,
alcohols and amines with defined (non)-noble metal pincer complexes. Cat Sci Technol
10:3825–3842
49. Tondreau AM, Atienza CCH, Weller KJ, Nye SA, Lewis KM, Delis JGP, Chirik PJ (2012)
Iron catalysts for selective anti-Markovnikov alkene hydrosilylation using tertiary silanes.
Science 335:567
50. Green MLH (1995) A new approach to the formal classification of covalent compounds of the
elements. J Organomet Chem 500:127–148
51. Hill AF, Owen GR, White AJP, Williams DJ (1999) The sting of the scorpion: a
metallaboratrane. Angew Chem Int Ed 38:2759–2761
52. Bontemps S, Bouhadir G, Gu W, Mercy M, Chen CH, Foxman BM, Maron L, Ozerov OV,
Bourissou D (2008) Metallaboratranes derived from a triphosphanyl–borane: intrinsic C3
symmetry supported by a Z-type ligand. Angew Chem Int Ed 47:1481–1484
53. Bourissou D, Bouhadir G (2016) Ambiphilic ligands: unusual coordination and reactivity
arising from Lewis acid moieties. In: Stradiotto M, Lundgren RJ (eds) Ligand design in metal
chemistry: reactivity and catalysis. Wiley, New York, pp 237–269
54. Bontemps S, Bouhadir G, Dyer PW, Miqueu K, Bourissou D (2007) Quasi-Thermoneutral P
! B interactions within Di- and tri-phosphine boranes. Inorg Chem 46:5149–5151
55. Sircoglou M, Bontemps S, Bouhadir G et al (2008) Group 10 and 11 metal boratranes (Ni, Pd,
Pt, CuCl, AgCl, AuCl, and Au+) derived from a triphosphineÀborane. J Am Chem Soc
130:16729–16738
56. Bontemps S, Gornitzka H, Bouhadir G, Saffon N, Miqueu K, Gu W, Mercy M, Chen CH,
Foxman BM, Maron L, Ozerov OV, Bourissou D (2006) Rhodium(I) complexes of a PBP
ambiphilic ligand: evidence for a metal!borane interaction. Angew Chem Int Ed
45:1611–1614
57. Harman WH, Peters JC (2012) Reversible H2 addition across a nickel–borane unit as a
promising strategy for catalysis. J Am Chem Soc 134:5080–5082
58. Sircoglou M, Bontemps S, Mercy M, Miqueu K, Ladeira S, Saffon N, Maron L, Bouhadir G,
Bourissou D (2010) Copper(I) complexes derived from mono- and diphosphino-boranes:
Cu!B interactions supported by arene coordination. Inorg Chem 49:3983–3990
59. Schindler T, Lux M, Peters M, Scharf LT, Osseili H, Maron L, Tauchert ME (2015) Synthesis
and reactivity of palladium complexes featuring a diphosphinoborane ligand. Organometallics
34:1978–1984
60. Cao Y, Shih W-C, Bhuvanesh N, Ozerov OV (2019) Silver halide complexes of a borane/bis
(phosphine) ligand. Dalton Trans 48:9959–9961
61. Sircoglou M, Bontemps S, Mercy M, Saffon N, Takahashi M, Bouhadir G, Maron L,
Bourissou D (2007) Transition-metal complexes featuring Z-type ligands: agreement or
discrepancy between geometry and dn configuration? Angew Chem Int Ed 46:8583–8586
62. Tauchert ME, Steinhoff P (2016) A T-shape diphosphinoborane palladium(0) complex.
Beilstein J Org Chem 12:1573–1576
63. Inagaki F, Matsumoto C, Okada Y, Maruyama N, Mukai C (2015) Air-stable cationic gold
(I) catalyst featuring a Z-type ligand: promoting enyne cyclizations. Angew Chem Int Ed
54:818–822
64. Murakami R, Inagaki F (2019) Recent topics of gold catalyst featuring Z-type ligands.
Tetrahedron Lett 60:151231
66
M. R. Tiddens and M.-E. Moret