multiple bonds. Further research in order to introduce different concepts, e.g., innersphere reaction pathways, would broaden the applicability of manganese-based
systems. The inspiring discoveries within the last few years led to remarkable
findings in manganese-catalyzed (de)hydrogenation reactions. Regarding the large
growing number of research articles within this flowering field, manganese catalysis
is just at its beginning, and many breakthroughs may be expected in the near future.
References
1. Bullock RM (2013) Science 342:1054–1055
2. Christianson DW (1997) Prog Biophys Mol Biol 67:217
3. Wieghardt K (1989) Angew Chem Int Ed 28:1153
4. Carney JR, Dillon BR, Thomas SP (2016) Eur J Org Chem:3912–3929
5. Garbe M, Junge K, Beller M (2017) Eur J Org Chem:4344–4362
6. Maji B, Barman M (2017) Synthesis 49:3377–3393
7. Filoenko GA, van Putten R, Hensen EJM, Pidko EA (2018) Chem Soc Rev 47:1484–1515
8. Gorgas N, Kirchner K (2018) Acc Chem Res 51:1558–1569
9. Zell T, Langer R (2018) Chem Catal Chem 10:1930–1940
10. Mukherjee A, Milstein D (2018) ACS Catal 8:11435–11469
11. Guanathan C, Milstein D (2013) Science 341:1229712
12. de Vries JG (2006) The handbook of homogeneous hydrogenation. Wiley-VCH Verlag GmbH,
Weinheim
13. Khusnutdinova JR, Milstein D (2015) Angew Chem Int Ed 54:12236–12273
14. Elangovan S, Topf C, Fischer S, Jiao H, Spannenberg A, Baumann W, Ludwig R, Junge K,
Beller M (2016) J Am Chem Soc 138:8809–8814
15. Kallmeier F, Irrgang T, Dietel T, Kempe R (2016) Angew Chem Int Ed 55:11806–11809
16. Bruneau-Voisine A, Wang D, Roisnel T, Darcel C, Sortais J-B (2017) Catal Commun 92:1–4
17. Glatz M, Stöger B, Himmelbauer D, Veiros LF, Kirchner K (2018) ACS Catal 8:4009–4016
18. Wie D, Bruneau-Voisine A, Chauvin T, Dorcet V, Roisnel T, Valyaev DA, Lugan N, Sortais
J-B (2018) Adv Syn Catal 360:676–681
19. Buhaibeh R, Filippov OA, Bruneau-Voisine A, Willot J, Duhayon C, Valyaev DA, Lugan N,
Canac Y, Sortais J-B (2019) Angew Chem Int Ed 58:6727–6731
20. Widegren MB, Harkness GJ, Slawin AMZ, Cordes DB, Clarke ML (2017) Angew Chem Int Ed
56:5825–5828
21. Garbe M, Junge K, Walker S, Wei Z, Jiao H, Spennenberg A, Bachmann S, Scalone M, Beller
M (2017) Angew Chem Int Ed 56:11237–11241
22. Zhang L, Tang Y, Han Z, Ding K (2019) Angew Chem Int Ed 58:4973–4977
23. Elangovan S, Garbe M, Jiao H, Spannenberg A, Junge K, Beller M (2016) Angew Chem Int Ed
55:15364–15368
24. Widegren MB, Clarke ML (2018) Org Lett 20:2654–2658
25. Espinosa-Jalapa NA, Nerush A, Shimon LJW, Leitus G, Avram L, Ben-David Y, Milstein D
(2017) Chem Eur J 23:5934–5938
26. van Putten R, Uslamin EA, Garbe M, Liu C, Gonzalez-de-Castro A, Lutz M, Junge K, Hensen
EJM, Beller M, Lefort L, Pidko EA (2017) Angew Chem Int Ed 56:7531–7534
27. Papa V, Cabrero-Antonino JR, Alberico E, Spannenberg A, Junge K, Junge H, Beller M (2017)
Chem Sci 8:3576–3585
28. Zou Y-Q, Chakraborty S, Nerusch A, Oren D, Diskin-Posner Y, Ben-David Y, Milstein D
(2018) ACS Catal 8:8014–8019
The Role of Metal-Ligand Cooperation in Manganese(I)-Catalyzed. . .
259
systems. The inspiring discoveries within the last few years led to remarkable
findings in manganese-catalyzed (de)hydrogenation reactions. Regarding the large
growing number of research articles within this flowering field, manganese catalysis
is just at its beginning, and many breakthroughs may be expected in the near future.
References
1. Bullock RM (2013) Science 342:1054–1055
2. Christianson DW (1997) Prog Biophys Mol Biol 67:217
3. Wieghardt K (1989) Angew Chem Int Ed 28:1153
4. Carney JR, Dillon BR, Thomas SP (2016) Eur J Org Chem:3912–3929
5. Garbe M, Junge K, Beller M (2017) Eur J Org Chem:4344–4362
6. Maji B, Barman M (2017) Synthesis 49:3377–3393
7. Filoenko GA, van Putten R, Hensen EJM, Pidko EA (2018) Chem Soc Rev 47:1484–1515
8. Gorgas N, Kirchner K (2018) Acc Chem Res 51:1558–1569
9. Zell T, Langer R (2018) Chem Catal Chem 10:1930–1940
10. Mukherjee A, Milstein D (2018) ACS Catal 8:11435–11469
11. Guanathan C, Milstein D (2013) Science 341:1229712
12. de Vries JG (2006) The handbook of homogeneous hydrogenation. Wiley-VCH Verlag GmbH,
Weinheim
13. Khusnutdinova JR, Milstein D (2015) Angew Chem Int Ed 54:12236–12273
14. Elangovan S, Topf C, Fischer S, Jiao H, Spannenberg A, Baumann W, Ludwig R, Junge K,
Beller M (2016) J Am Chem Soc 138:8809–8814
15. Kallmeier F, Irrgang T, Dietel T, Kempe R (2016) Angew Chem Int Ed 55:11806–11809
16. Bruneau-Voisine A, Wang D, Roisnel T, Darcel C, Sortais J-B (2017) Catal Commun 92:1–4
17. Glatz M, Stöger B, Himmelbauer D, Veiros LF, Kirchner K (2018) ACS Catal 8:4009–4016
18. Wie D, Bruneau-Voisine A, Chauvin T, Dorcet V, Roisnel T, Valyaev DA, Lugan N, Sortais
J-B (2018) Adv Syn Catal 360:676–681
19. Buhaibeh R, Filippov OA, Bruneau-Voisine A, Willot J, Duhayon C, Valyaev DA, Lugan N,
Canac Y, Sortais J-B (2019) Angew Chem Int Ed 58:6727–6731
20. Widegren MB, Harkness GJ, Slawin AMZ, Cordes DB, Clarke ML (2017) Angew Chem Int Ed
56:5825–5828
21. Garbe M, Junge K, Walker S, Wei Z, Jiao H, Spennenberg A, Bachmann S, Scalone M, Beller
M (2017) Angew Chem Int Ed 56:11237–11241
22. Zhang L, Tang Y, Han Z, Ding K (2019) Angew Chem Int Ed 58:4973–4977
23. Elangovan S, Garbe M, Jiao H, Spannenberg A, Junge K, Beller M (2016) Angew Chem Int Ed
55:15364–15368
24. Widegren MB, Clarke ML (2018) Org Lett 20:2654–2658
25. Espinosa-Jalapa NA, Nerush A, Shimon LJW, Leitus G, Avram L, Ben-David Y, Milstein D
(2017) Chem Eur J 23:5934–5938
26. van Putten R, Uslamin EA, Garbe M, Liu C, Gonzalez-de-Castro A, Lutz M, Junge K, Hensen
EJM, Beller M, Lefort L, Pidko EA (2017) Angew Chem Int Ed 56:7531–7534
27. Papa V, Cabrero-Antonino JR, Alberico E, Spannenberg A, Junge K, Junge H, Beller M (2017)
Chem Sci 8:3576–3585
28. Zou Y-Q, Chakraborty S, Nerusch A, Oren D, Diskin-Posner Y, Ben-David Y, Milstein D
(2018) ACS Catal 8:8014–8019
The Role of Metal-Ligand Cooperation in Manganese(I)-Catalyzed. . .
259