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23. Lewis JC, Berman AM, Bergman RG, Ellman JA (2008) Rh(I)-catalyzed arylation of heterocycles via C–H bond activation: expanded scope through mechanistic insight. J Am Chem
Soc 130:2493–2500
24. Wang X, Lane BS, Sames D (2005) Direct C-arylation of free (NH)-indoles and pyrroles
catalyzed by Ar-Rh(III) complexes assembled in situ. J Am Chem Soc 127:4996–4997
25. Santoro S, Himo F (2018) Mechanism and selectivity of rhodium-catalyzed C–H bond
arylation of indoles. Int J Quantum Chem 118:e25526
26. Oi S, Fukita S, Inoue Y (1998) Rhodium-catalysed direct ortho arylation of 2-arylpyridines
with arylstannanes via C–H activation. Chem Comm:2439–2440
27. Ueura K, Satoh T, Miura M (2005) Rhodium-catalyzed arylation using arylboron compounds:
efficient coupling with aryl halides and unexpected multiple arylation of benzonitrile. Org Lett
7:2229–2231
28. Miyamura S, Tsurugi H, Satoh T, Miura M (2008) Rhodium-catalyzed regioselective arylation
of phenylazoles and related compounds with arylboron reagents via C–H bond cleavage. J
Organomet Chem 693:2438–2442
29. Vogler T, Studer A (2008) Oxidative coupling of arylboronic acids with arenes via
Rh-catalyzed direct C–H arylation. Org Lett 10:129–131
30. Karthikeyan J, Haridharan R, Cheng CH (2012) Rhodium(III)-catalyzed oxidative C–H
coupling of N-methoxybenzamides with aryl boronic acids: one-pot synthesis of phenanthridinones. Angew Chem Int Ed 51:12343–12347
31. Zheng J, Zhang Y, Cui S (2014) Rh(III)-catalyzed selective coupling of N-methoxy-1Hindole-1-carboxamides and aryl boronic acids. Org Lett 16:3560–3563
32. Wencel-Delord J, Nimphius C, Patureau FW, Glorius F (2012) [Rh(III)Cp*]-catalyzed
dehydrogenative aryl-aryl bond formation. Angew Chem Int Ed 51:2247–2251
33. Zhao D, Li X, Han K, Li X, Wang Y (2015) Theoretical investigations on Rh(III)-catalyzed
cross-dehydrogenative aryl-aryl coupling via C–H bond activation. J Phys Chem A 119:2989–
2997
34. Colby DA, Tsai AS, Bergman RG, Ellman JA (2012) Rhodium catalyzed chelation-assisted
C–H bond functionalization reactions. Acc Chem Res 45:814–825
35. He Q, Yamaguchi T, Chatani N (2017) Rh(I)-Catalyzed Alkylation of ortho-C–H Bonds in
Aromatic Amides with Maleimides. Org Lett 19:4544–4547
36. Song G, Wang F, Li X (2012) C–C, C–O and C–N bond formation via rhodium(III)-catalyzed
oxidative C–H activation. Chem Soc Rev 41:3651–3678
37. Tran G, Hesp KD, Mascitti V, Ellman JA (2017) Base-controlled completely selective linear
or branched Rhodium(I)-Catalyzed C–H ortho-alkylation of azines without preactivation.
Angew Chem Int Ed 56:5899–5903
38. Deng H, Li H, Wang L (2015) A unique alkylation of azobenzenes with allyl acetates by
Rh(III)-catalyzed C–H functionalization. Org Lett 17:2450–2453
39. Huang L, Wang Q, Qi J, Wu X, Huang K, Jiang H (2013) Rh(III)-catalyzed ortho-oxidative
alkylation of unactivated arenes with allylic alcohols. Chem Sci 4:2665
40. Lewis JC, Bergman RG, Ellman JA (2007) Rh(I)-catalyzed alkylation of quinolines and
pyridines via C–H bond activation. J Am Chem Soc 129:5332–5333
41. Shibata K, Chatani N (2014) Rhodium-catalyzed alkylation of C-H bonds in aromatic amides
with alpha, beta-unsaturated esters. Org Lett 16:5148–5151
42. Sharma U, Park Y, Chang S (2014) Rh(III)-catalyzed traceless coupling of quinoline N-oxides
with internal diarylalkynes. J Org Chem 79:9899–9906
43. Zhang X, Qi Z, Li X (2014) Rhodium(III)-catalyzed C–C and C–O coupling of quinoline
N-oxides with alkynes: combination of C–H activation with O-atom transfer. Angew Chem
Int Ed 53:10794–10798
44. Chen X, Zheng G, Li Y, Song G, Li X (2017) Rhodium-catalyzed site-selective coupling of
indoles with diazo esters: C4-alkylation versus C2-annulation. Org Lett 19:6184–6187
45. Wu Y, Chen Z, Yang Y, Zhu W, Zhou B (2018) Rh(III)-catalyzed redox-neutral unsymmetrical
C–H alkylation and amidation reactions of N-phenoxyacetamides. J Am Chem Soc 140:42–45
87
23. Lewis JC, Berman AM, Bergman RG, Ellman JA (2008) Rh(I)-catalyzed arylation of heterocycles via C–H bond activation: expanded scope through mechanistic insight. J Am Chem
Soc 130:2493–2500
24. Wang X, Lane BS, Sames D (2005) Direct C-arylation of free (NH)-indoles and pyrroles
catalyzed by Ar-Rh(III) complexes assembled in situ. J Am Chem Soc 127:4996–4997
25. Santoro S, Himo F (2018) Mechanism and selectivity of rhodium-catalyzed C–H bond
arylation of indoles. Int J Quantum Chem 118:e25526
26. Oi S, Fukita S, Inoue Y (1998) Rhodium-catalysed direct ortho arylation of 2-arylpyridines
with arylstannanes via C–H activation. Chem Comm:2439–2440
27. Ueura K, Satoh T, Miura M (2005) Rhodium-catalyzed arylation using arylboron compounds:
efficient coupling with aryl halides and unexpected multiple arylation of benzonitrile. Org Lett
7:2229–2231
28. Miyamura S, Tsurugi H, Satoh T, Miura M (2008) Rhodium-catalyzed regioselective arylation
of phenylazoles and related compounds with arylboron reagents via C–H bond cleavage. J
Organomet Chem 693:2438–2442
29. Vogler T, Studer A (2008) Oxidative coupling of arylboronic acids with arenes via
Rh-catalyzed direct C–H arylation. Org Lett 10:129–131
30. Karthikeyan J, Haridharan R, Cheng CH (2012) Rhodium(III)-catalyzed oxidative C–H
coupling of N-methoxybenzamides with aryl boronic acids: one-pot synthesis of phenanthridinones. Angew Chem Int Ed 51:12343–12347
31. Zheng J, Zhang Y, Cui S (2014) Rh(III)-catalyzed selective coupling of N-methoxy-1Hindole-1-carboxamides and aryl boronic acids. Org Lett 16:3560–3563
32. Wencel-Delord J, Nimphius C, Patureau FW, Glorius F (2012) [Rh(III)Cp*]-catalyzed
dehydrogenative aryl-aryl bond formation. Angew Chem Int Ed 51:2247–2251
33. Zhao D, Li X, Han K, Li X, Wang Y (2015) Theoretical investigations on Rh(III)-catalyzed
cross-dehydrogenative aryl-aryl coupling via C–H bond activation. J Phys Chem A 119:2989–
2997
34. Colby DA, Tsai AS, Bergman RG, Ellman JA (2012) Rhodium catalyzed chelation-assisted
C–H bond functionalization reactions. Acc Chem Res 45:814–825
35. He Q, Yamaguchi T, Chatani N (2017) Rh(I)-Catalyzed Alkylation of ortho-C–H Bonds in
Aromatic Amides with Maleimides. Org Lett 19:4544–4547
36. Song G, Wang F, Li X (2012) C–C, C–O and C–N bond formation via rhodium(III)-catalyzed
oxidative C–H activation. Chem Soc Rev 41:3651–3678
37. Tran G, Hesp KD, Mascitti V, Ellman JA (2017) Base-controlled completely selective linear
or branched Rhodium(I)-Catalyzed C–H ortho-alkylation of azines without preactivation.
Angew Chem Int Ed 56:5899–5903
38. Deng H, Li H, Wang L (2015) A unique alkylation of azobenzenes with allyl acetates by
Rh(III)-catalyzed C–H functionalization. Org Lett 17:2450–2453
39. Huang L, Wang Q, Qi J, Wu X, Huang K, Jiang H (2013) Rh(III)-catalyzed ortho-oxidative
alkylation of unactivated arenes with allylic alcohols. Chem Sci 4:2665
40. Lewis JC, Bergman RG, Ellman JA (2007) Rh(I)-catalyzed alkylation of quinolines and
pyridines via C–H bond activation. J Am Chem Soc 129:5332–5333
41. Shibata K, Chatani N (2014) Rhodium-catalyzed alkylation of C-H bonds in aromatic amides
with alpha, beta-unsaturated esters. Org Lett 16:5148–5151
42. Sharma U, Park Y, Chang S (2014) Rh(III)-catalyzed traceless coupling of quinoline N-oxides
with internal diarylalkynes. J Org Chem 79:9899–9906
43. Zhang X, Qi Z, Li X (2014) Rhodium(III)-catalyzed C–C and C–O coupling of quinoline
N-oxides with alkynes: combination of C–H activation with O-atom transfer. Angew Chem
Int Ed 53:10794–10798
44. Chen X, Zheng G, Li Y, Song G, Li X (2017) Rhodium-catalyzed site-selective coupling of
indoles with diazo esters: C4-alkylation versus C2-annulation. Org Lett 19:6184–6187
45. Wu Y, Chen Z, Yang Y, Zhu W, Zhou B (2018) Rh(III)-catalyzed redox-neutral unsymmetrical
C–H alkylation and amidation reactions of N-phenoxyacetamides. J Am Chem Soc 140:42–45