References
17
115. Giri R, Shi BF, Engle KM, Maugel N, Yu JQ (2009) Transition metal-catalyzed C–H activation
reactions: diastereoselectivity and enantioselectivity. Chem Soc Rev 38:3242–3272
116. Trost BM, Van Vranken DL (1996) Asymmetric transition metal-catalyzed allylic alkylations.
Chem Rev 96:395–422
117. Lim YG, Kim YH, Kang JB (1994) Rhodium-catalysed regioselective alkylation of the phenyl
ring of 2-phenylpyridines with olefins. J Chem Soc Chem Commun:2267
118. Jun C-H, Hong J-B, Kim Y-H, Chung K-Y (2000) The Catalytic alkylation of aromatic imines
by Wilkinson’s complex: the domino reaction of hydroacylation andortho-Alkylation. Angew
Chem Int Ed 39:3440–3442
119. Lim Y-G, Han J-S, Koo BT, Kang J-B (2004) Regioselective alkylation of aromatic aldimines
and ketimines via C–H bond activation by a rhodium catalyst. J Mol Catal A-Chem 209:41–49
120. Lim Y-G, Lee K-H, Koo BT, Kang J-B (2001) Rhodium(I)-catalyzed ortho- alkenylation of
2-phenylpyridines with alkynes. Tetrahedron Lett 42:7609–7612
121. Lim SG, Lee JH, Moon CW, Hong J-B, Jun CH (2003) Rh(I)-catalyzed direct orthoalkenylation of aromatic ketimines with alkynes and its application to the synthesis of
isoquinoline derivatives. Org Lett 5:2759–2761
122. Oi S, Fukita S, Inoue Y (1998) Rhodium-catalysed direct ortho arylation of 2-arylpyridines
with arylstannanes via C–H activation. Chem Commun:2439–2440
123. Asaumi T, Matsuo T, Fukuyama T, Ie Y, Kakiuchi F, Chatani N (2004) Ruthenium- and
rhodium-catalyzed direct carbonylation of the ortho C-H bond in the benzene ring of Narylpyrazoles. J Org Chem 69:4433–4440
124. Jun C-H, Moon CW, Kim Y-M, Lee H, Lee JH (2002) Chelation-assisted β-alkylation of α,
β-unsaturated ketone using Rh(I) catalyst and dialkyl amine. Tetrahedron Lett 43:4233–4236
125. Aissa C, Furstner A (2007) A rhodium-catalyzed C–H activation/cycloisomerization tandem.
J Am Chem Soc 129:14836–14837
126. Tan KL, Bergman RG, Ellman JA (2001) Annulation of alkenyl-substituted heterocycles
via rhodium-catalyzed intramolecular C–H activated coupling reactions. J Am Chem Soc
123:2685–2686
127. Lewis JC, Wiedemann SH, Bergman RG, Ellman JA (2004) Arylation of heterocycles via
rhodium-catalyzed C–H bond functionalization. Org Lett 6:35–38
128. Ueura K, Satoh T, Miura M (2007) Rhodium- and iridium-catalyzed oxidative coupling of
benzoic acids with alkynes via regioselective C–H bond cleavage. J Org Chem 72:5362–5367
129. Chen W-J, Lin Z (2014) Rhodium(III)-catalyzed hydrazine-directed C–H activation for indole
synthesis: mechanism and role of internal oxidant probed by DFT studies. Organometallics
34:309–318
130. Sperger T, Sanhueza IA, Kalvet I, Schoenebeck F (2015) Computational Studies of synthetically relevant homogeneous organometallic catalysis involving Ni, Pd, Ir, and Rh: an overview
of commonly employed DFT methods and mechanistic insights. Chem Rev 115:9532–9586
131. Lin Z (2010) Interplay between theory and experiment: computational organometallic and
transition metal chemistry. Acc Chem Res 43:602–611
132. Xue L, Lin Z (2010) Theoretical aspects of palladium-catalysed carbon-carbon cross-coupling
reactions. Chem Soc Rev 39:1692–1705
133. Dang Y, Qu S, Tao Y, Deng X, Wang ZX (2015) Mechanistic insight into ketone alphaalkylation with unactivated olefins via C–H activation promoted by metal-organic cooperative
catalysis (MOCC): enriching the MOCC chemistry. J Am Chem Soc 137:6279–6291
134. Guimond N, Gorelsky SI, Fagnou K (2011) Rhodium(III)-catalyzed heterocycle synthesis
using an internal oxidant: improved reactivity and mechanistic studies. J Am Chem Soc
133:6449–6457
135. Li Y, Liu S, Qi Z, Qi X, Li X, Lan Y (2015) The mechanism of N–O bond cleavage in RhodiumCatalyzed C–H bond functionalization of quinoline N-oxides with alkynes: a computational
study. Chem A Eur J 21:10131–10137
136. Neufeldt SR, Jimenez-Oses G, Huckins JR, Thiel OR, Houk KN (2015) Pyridine N-Oxide vs
pyridine substrates for Rh(III)-Catalyzed oxidative C–H Bond Functionalization. J Am Chem
Soc 137:9843–9854
17
115. Giri R, Shi BF, Engle KM, Maugel N, Yu JQ (2009) Transition metal-catalyzed C–H activation
reactions: diastereoselectivity and enantioselectivity. Chem Soc Rev 38:3242–3272
116. Trost BM, Van Vranken DL (1996) Asymmetric transition metal-catalyzed allylic alkylations.
Chem Rev 96:395–422
117. Lim YG, Kim YH, Kang JB (1994) Rhodium-catalysed regioselective alkylation of the phenyl
ring of 2-phenylpyridines with olefins. J Chem Soc Chem Commun:2267
118. Jun C-H, Hong J-B, Kim Y-H, Chung K-Y (2000) The Catalytic alkylation of aromatic imines
by Wilkinson’s complex: the domino reaction of hydroacylation andortho-Alkylation. Angew
Chem Int Ed 39:3440–3442
119. Lim Y-G, Han J-S, Koo BT, Kang J-B (2004) Regioselective alkylation of aromatic aldimines
and ketimines via C–H bond activation by a rhodium catalyst. J Mol Catal A-Chem 209:41–49
120. Lim Y-G, Lee K-H, Koo BT, Kang J-B (2001) Rhodium(I)-catalyzed ortho- alkenylation of
2-phenylpyridines with alkynes. Tetrahedron Lett 42:7609–7612
121. Lim SG, Lee JH, Moon CW, Hong J-B, Jun CH (2003) Rh(I)-catalyzed direct orthoalkenylation of aromatic ketimines with alkynes and its application to the synthesis of
isoquinoline derivatives. Org Lett 5:2759–2761
122. Oi S, Fukita S, Inoue Y (1998) Rhodium-catalysed direct ortho arylation of 2-arylpyridines
with arylstannanes via C–H activation. Chem Commun:2439–2440
123. Asaumi T, Matsuo T, Fukuyama T, Ie Y, Kakiuchi F, Chatani N (2004) Ruthenium- and
rhodium-catalyzed direct carbonylation of the ortho C-H bond in the benzene ring of Narylpyrazoles. J Org Chem 69:4433–4440
124. Jun C-H, Moon CW, Kim Y-M, Lee H, Lee JH (2002) Chelation-assisted β-alkylation of α,
β-unsaturated ketone using Rh(I) catalyst and dialkyl amine. Tetrahedron Lett 43:4233–4236
125. Aissa C, Furstner A (2007) A rhodium-catalyzed C–H activation/cycloisomerization tandem.
J Am Chem Soc 129:14836–14837
126. Tan KL, Bergman RG, Ellman JA (2001) Annulation of alkenyl-substituted heterocycles
via rhodium-catalyzed intramolecular C–H activated coupling reactions. J Am Chem Soc
123:2685–2686
127. Lewis JC, Wiedemann SH, Bergman RG, Ellman JA (2004) Arylation of heterocycles via
rhodium-catalyzed C–H bond functionalization. Org Lett 6:35–38
128. Ueura K, Satoh T, Miura M (2007) Rhodium- and iridium-catalyzed oxidative coupling of
benzoic acids with alkynes via regioselective C–H bond cleavage. J Org Chem 72:5362–5367
129. Chen W-J, Lin Z (2014) Rhodium(III)-catalyzed hydrazine-directed C–H activation for indole
synthesis: mechanism and role of internal oxidant probed by DFT studies. Organometallics
34:309–318
130. Sperger T, Sanhueza IA, Kalvet I, Schoenebeck F (2015) Computational Studies of synthetically relevant homogeneous organometallic catalysis involving Ni, Pd, Ir, and Rh: an overview
of commonly employed DFT methods and mechanistic insights. Chem Rev 115:9532–9586
131. Lin Z (2010) Interplay between theory and experiment: computational organometallic and
transition metal chemistry. Acc Chem Res 43:602–611
132. Xue L, Lin Z (2010) Theoretical aspects of palladium-catalysed carbon-carbon cross-coupling
reactions. Chem Soc Rev 39:1692–1705
133. Dang Y, Qu S, Tao Y, Deng X, Wang ZX (2015) Mechanistic insight into ketone alphaalkylation with unactivated olefins via C–H activation promoted by metal-organic cooperative
catalysis (MOCC): enriching the MOCC chemistry. J Am Chem Soc 137:6279–6291
134. Guimond N, Gorelsky SI, Fagnou K (2011) Rhodium(III)-catalyzed heterocycle synthesis
using an internal oxidant: improved reactivity and mechanistic studies. J Am Chem Soc
133:6449–6457
135. Li Y, Liu S, Qi Z, Qi X, Li X, Lan Y (2015) The mechanism of N–O bond cleavage in RhodiumCatalyzed C–H bond functionalization of quinoline N-oxides with alkynes: a computational
study. Chem A Eur J 21:10131–10137
136. Neufeldt SR, Jimenez-Oses G, Huckins JR, Thiel OR, Houk KN (2015) Pyridine N-Oxide vs
pyridine substrates for Rh(III)-Catalyzed oxidative C–H Bond Functionalization. J Am Chem
Soc 137:9843–9854