12
1 Theoretical View of Rh-Catalyzed C–H Functionalization
and its relationship with the C–H bond activation mode are emphasized to reveal the
mechanistic diversity.
References
1. Arndtsen BA, Bergman RG, Mobley TA, Peterson TH (2002) Selective intermolecular carbonhydrogen bond activation by synthetic metal complexes in homogeneous solution. Acc Chem
Res 28:154–162
2. Cheng D, Ishihara Y, Tan B, Barbas CF (2014) Organocatalytic asymmetric assembly
reactions: synthesis of spirooxindoles via organocascade strategies. ACS Catal 4:743–762
3. Crisenza GEM, Mazzarella D, Melchiorre P (2020) Synthetic methods driven by the
photoactivity of electron donor-acceptor complexes. J Am Chem Soc 142:5461–5476
4. Kendall JL, Canelas DA, Young JL, DeSimone JM (1999) Polymerizations in supercritical
carbon dioxide. Chem Rev 99:543–564
5. Kim J, Kim H, Park SB (2014) Privileged structures: efficient chemical “navigators” toward
unexplored biologically relevant chemical spaces. J Am Chem Soc 136:14629–14638
6. Melchiorre P, Marigo M, Carlone A, Bartoli G (2008) Asymmetric aminocatalysis-gold rush
in organic chemistry. Angew Chem Int Ed 47:6138–6171
7. Nicolaou KC, Hale CRH, Nilewski C, Ioannidou HA (2012) Constructing molecular
complexity and diversity: total synthesis of natural products of biological and medicinal
importance. Chem Soc Rev 41:5185
8. Santaniello E, Ferraboschi P, Grisenti P, Manzocchi A (1992) The biocatalytic approach to
the preparation of enantiomerically pure chiral building blocks. Chem Rev 92:1071–1140
9. Segura JL, Martin N (1999) o-Quinodimethanes: efficient intermediates in organic synthesis.
Chem Rev 99:3199–3246
10. Tortajada A, Julia-Hernandez F, Borjesson M, Moragas T, Martin R (2018) Transition-metalcatalyzed carboxylation reactions with carbon dioxide. Angew Chem Int Ed 57:15948–15982
11. Whitesides GM, Simanek EE, Mathias JP, Seto CT, Chin D, Mammen M, Gordon DM (2002)
Noncovalent synthesis: using physical-organic chemistry to make aggregates. Acc Chem Res
28:37–44
12. Zhan G, Du W, Chen Y-C (2017) Switchable divergent asymmetric synthesis via organocatalysis. Chem Soc Rev 46:1675–1692
13. Zimmer R, Dinesh CU, Nandanan E, Khan FA (2000) Palladium-catalyzed reactions of
allenes. Chem Rev 100:3067–3126
14. Liu S, Lei Y, Li Y, Zhang T, Wang H, Lan Y (2014) Hexahapto-chromium complexes of
graphene: a theoretical study. RSC Adv. 4:28640–28644
15. Yudin AK (2010) Catalyzed carbon-heteroatom bond formation. Wiley-VCH, Weinheim
16. Katritzky A, Rees CW, Scriven EF, Ramsden C, Taylor R (1984) Comprehensive heterocyclic
chemistry. Elsevier Science, Oxford
17. Monnier F, Taillefer M (2009) Catalytic C–C, C–N, and C–O Ullmann-type coupling
reactions. Angew Chem Int Ed 48:6954–6971
18. Nasrollahzadeh M, Issaabadi Z, Tohidi MM, Mohammad Sajadi S (2018) Recent progress in
application of graphene supported metal nanoparticles in C–C and C–X coupling reactions.
Chem Rec 18:165–229
19. Sherry BD, Furstner A (2008) The promise and challenge of iron-catalyzed cross coupling.
Acc Chem Res 41:1500–1511
20. Tang X, Wu W, Zeng W, Jiang H (2018) Copper-catalyzed oxidative carbon-carbon and/or
carbon-heteroatom bond formation with O 2 or internal oxidants. Acc Chem Res 51:1092–1105
21. Valente C, Calimsiz S, Hoi KH, Mallik D, Sayah M, Organ MG (2012) The development of
bulky palladium NHC complexes for the most-challenging cross-coupling reactions. Angew
Chem Int Ed 51:3314–3332
1 Theoretical View of Rh-Catalyzed C–H Functionalization
and its relationship with the C–H bond activation mode are emphasized to reveal the
mechanistic diversity.
References
1. Arndtsen BA, Bergman RG, Mobley TA, Peterson TH (2002) Selective intermolecular carbonhydrogen bond activation by synthetic metal complexes in homogeneous solution. Acc Chem
Res 28:154–162
2. Cheng D, Ishihara Y, Tan B, Barbas CF (2014) Organocatalytic asymmetric assembly
reactions: synthesis of spirooxindoles via organocascade strategies. ACS Catal 4:743–762
3. Crisenza GEM, Mazzarella D, Melchiorre P (2020) Synthetic methods driven by the
photoactivity of electron donor-acceptor complexes. J Am Chem Soc 142:5461–5476
4. Kendall JL, Canelas DA, Young JL, DeSimone JM (1999) Polymerizations in supercritical
carbon dioxide. Chem Rev 99:543–564
5. Kim J, Kim H, Park SB (2014) Privileged structures: efficient chemical “navigators” toward
unexplored biologically relevant chemical spaces. J Am Chem Soc 136:14629–14638
6. Melchiorre P, Marigo M, Carlone A, Bartoli G (2008) Asymmetric aminocatalysis-gold rush
in organic chemistry. Angew Chem Int Ed 47:6138–6171
7. Nicolaou KC, Hale CRH, Nilewski C, Ioannidou HA (2012) Constructing molecular
complexity and diversity: total synthesis of natural products of biological and medicinal
importance. Chem Soc Rev 41:5185
8. Santaniello E, Ferraboschi P, Grisenti P, Manzocchi A (1992) The biocatalytic approach to
the preparation of enantiomerically pure chiral building blocks. Chem Rev 92:1071–1140
9. Segura JL, Martin N (1999) o-Quinodimethanes: efficient intermediates in organic synthesis.
Chem Rev 99:3199–3246
10. Tortajada A, Julia-Hernandez F, Borjesson M, Moragas T, Martin R (2018) Transition-metalcatalyzed carboxylation reactions with carbon dioxide. Angew Chem Int Ed 57:15948–15982
11. Whitesides GM, Simanek EE, Mathias JP, Seto CT, Chin D, Mammen M, Gordon DM (2002)
Noncovalent synthesis: using physical-organic chemistry to make aggregates. Acc Chem Res
28:37–44
12. Zhan G, Du W, Chen Y-C (2017) Switchable divergent asymmetric synthesis via organocatalysis. Chem Soc Rev 46:1675–1692
13. Zimmer R, Dinesh CU, Nandanan E, Khan FA (2000) Palladium-catalyzed reactions of
allenes. Chem Rev 100:3067–3126
14. Liu S, Lei Y, Li Y, Zhang T, Wang H, Lan Y (2014) Hexahapto-chromium complexes of
graphene: a theoretical study. RSC Adv. 4:28640–28644
15. Yudin AK (2010) Catalyzed carbon-heteroatom bond formation. Wiley-VCH, Weinheim
16. Katritzky A, Rees CW, Scriven EF, Ramsden C, Taylor R (1984) Comprehensive heterocyclic
chemistry. Elsevier Science, Oxford
17. Monnier F, Taillefer M (2009) Catalytic C–C, C–N, and C–O Ullmann-type coupling
reactions. Angew Chem Int Ed 48:6954–6971
18. Nasrollahzadeh M, Issaabadi Z, Tohidi MM, Mohammad Sajadi S (2018) Recent progress in
application of graphene supported metal nanoparticles in C–C and C–X coupling reactions.
Chem Rec 18:165–229
19. Sherry BD, Furstner A (2008) The promise and challenge of iron-catalyzed cross coupling.
Acc Chem Res 41:1500–1511
20. Tang X, Wu W, Zeng W, Jiang H (2018) Copper-catalyzed oxidative carbon-carbon and/or
carbon-heteroatom bond formation with O 2 or internal oxidants. Acc Chem Res 51:1092–1105
21. Valente C, Calimsiz S, Hoi KH, Mallik D, Sayah M, Organ MG (2012) The development of
bulky palladium NHC complexes for the most-challenging cross-coupling reactions. Angew
Chem Int Ed 51:3314–3332