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104. Lu W, Li C, Wu X, Xie X, Zhang Z (2020) [Rh(COD)Cl] 2 /PPh 3 -Catalyzed dehydrogenative
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108. Murai M, Takeuchi Y, Yamauchi K, Kuninobu Y, Takai K (2016) Rhodium-catalyzed synthesis
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110. Li W, Huang X, You J (2016) Ruthenium-catalyzed intermolecular direct silylation of
unreactive C(sp 3 )-H bonds. Org Lett 18:666–668
111. Liu YJ, Liu YH, Zhang ZZ, Yan SY, Chen K, Shi BF (2016) Divergent and stereoselective synthesis of beta-silyl-alpha-amino acids through palladium-catalyzed intermolecular silylation of unactivated primary and secondary C–H bonds. Angew Chem Int Ed
55:13859–13862
112. Murai M, Takami K, Takai K (2015) Iridium-catalyzed intermolecular dehydrogenative silylation of polycyclic aromatic compounds without directing groups. Chem Eur J
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113. Lin Q, Lin Z, Pan M, Zheng Q, Li H, Chen X, Darcel C, Dixneuf PH, Li B (2020) Alkenes as
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of amides and anilides. Org Chem Front. https://doi.org/10.1039/D0QO01031F
114. Ureshino T, Yoshida T, Kuninobu Y, Takai K (2010) Rhodium-catalyzed synthesis of silafluorene derivatives via cleavage of silicon-hydrogen and carbon-hydrogen bonds. J Am Chem
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123
93. Su B, Lee T, Hartwig JF (2018) Iridium-catalyzed, β-selective C(sp3)-H silylation of aliphatic
amines to form silapyrrolidines and 1,2-amino alcohols. J Am Chem Soc 140:18032–18038
94. Toutov AA, Liu W-B, Betz KN, Fedorov A, Stoltz BM, Grubbs RH (2015) Silylation of C–H
bonds in aromatic heterocycles by an Earth-abundant metal catalyst. Nature 518:80–84
95. Wang D, Zhao Y, Yuan C, Wen J, Zhao Y, Shi Z (2019) Rhodium(II)-catalyzed dehydrogenative silylation of biaryl-type monophosphines with hydrosilanes. Angew Chem Int Ed
58:12529–12533
96. Wen J, Dong B, Zhu J, Zhao Y, Shi Z (2020) Revealing silylation of C(sp(2))/C(sp(3))-H
bonds in arylphosphines by ruthenium catalysis. Angew Chem Int Ed 59:10909–10912
97. Wu Y-J, Yao Q-J, Chen H-M, Liao G, Shi BF (2020) Palladium-catalyzed ortho-C–H silylation
of biaryl aldehydes using a transient directing group. Sci China Chem 63:875–880
98. Yang Y, Wang C (2015) Direct silylation reactions of inert C–H bonds via transition metal
catalysis. Sci. China Chem 58:1266–1279
99. Karmel C, Li B, Hartwig JF (2018) Rhodium-catalyzed regioselective silylation of alkyl C–H
bonds for the synthesis of 1,4-Diols. J Am Chem Soc 140:1460–1470
100. Lee T, Hartwig JF (2016) Rhodium-catalyzed enantioselective silylation of cyclopropyl C–H
bonds. Angew Chem Int Ed 55:8723–8727
101. Zheng S, Zhang T, Maekawa H (2020) Reductive 3-silylation of benzofuran derivatives via
coupling reaction with chlorotrialkylsilane. J Org Chem 85:13965–13972
102. Hua Y, Asgari P, Avullala T, Jeon J (2016) Catalytic reductive ortho-C–H silylation of phenols
with traceless, versatile acetal directing groups and synthetic applications of dioxasilines. J
Am Chem Soc 138:7982–7991
103. Itagaki S, Kamata K, Yamaguchi K, Mizuno N (2012) Rhodium acetate/base-catalyzed Nsilylation of indole derivatives with hydrosilanes. Chem Commun 48:9269–9271
104. Lu W, Li C, Wu X, Xie X, Zhang Z (2020) [Rh(COD)Cl] 2 /PPh 3 -Catalyzed dehydrogenative
silylation of styrene derivatives with NBE as a hydrogen acceptor. Organometallics 39:3780–
3788
105. Mita T, Michigami K, Sato Y (2013) Iridium- and rhodium-catalyzed dehydrogenative silylations of C(sp 3 ) H bonds adjacent to a nitrogen atom using hydrosilanes. Chem-Asian J
8:2970–2973
106. Murai M, Matsumoto K, Takeuchi Y, Takai K (2015) Rhodium-catalyzed synthesis of
benzosilolometallocenes via the dehydrogenative silylation of C(sp 2 )–H bonds. Org Lett
17:3102–3105
107. Murai M, Okada R, Nishiyama A, Takai K (2016) Synthesis and properties of sila[n]helicenes
via dehydrogenative silylation of C–H Bonds under rhodium catalysis. Org Lett 18:4380–4383
108. Murai M, Takeuchi Y, Yamauchi K, Kuninobu Y, Takai K (2016) Rhodium-catalyzed synthesis
of chiral spiro-9-silabifluorenes by dehydrogenative silylation: mechanistic insights into the
construction of tetraorganosilicon stereocenters. Chem Eur J 22:6048–6058
109. Thiot C, Wagner A, Mioskowski C (2006) Rh Soaked in Polyionic Gel: An Effective catalyst
for dehydrogenative silylation of ketones. Org Lett 8:5939–5942
110. Li W, Huang X, You J (2016) Ruthenium-catalyzed intermolecular direct silylation of
unreactive C(sp 3 )-H bonds. Org Lett 18:666–668
111. Liu YJ, Liu YH, Zhang ZZ, Yan SY, Chen K, Shi BF (2016) Divergent and stereoselective synthesis of beta-silyl-alpha-amino acids through palladium-catalyzed intermolecular silylation of unactivated primary and secondary C–H bonds. Angew Chem Int Ed
55:13859–13862
112. Murai M, Takami K, Takai K (2015) Iridium-catalyzed intermolecular dehydrogenative silylation of polycyclic aromatic compounds without directing groups. Chem Eur J
21:4566–4570
113. Lin Q, Lin Z, Pan M, Zheng Q, Li H, Chen X, Darcel C, Dixneuf PH, Li B (2020) Alkenes as
hydrogen trappers to control the regio-selective ruthenium(ii) catalyzed ortho C–H silylation
of amides and anilides. Org Chem Front. https://doi.org/10.1039/D0QO01031F
114. Ureshino T, Yoshida T, Kuninobu Y, Takai K (2010) Rhodium-catalyzed synthesis of silafluorene derivatives via cleavage of silicon-hydrogen and carbon-hydrogen bonds. J Am Chem
Soc 132:14324–14326