References
93
152. Yi W, Li L, Chen H, Ma K, Zhong Y, Chen W, Gao H, Zhou Z (2018) Rh(III)-catalyzed
oxidative [5+2] annulation using two transient assisting groups: stereospecific assembly of
3-alkenylated benzoxepine framework. Org Lett 20:6812–6816
153. Yi W, Chen W, Liu FX, Zhong Y, Wu D, Zhou Z, Gao H (2018) Rh(III)-catalyzed and solventcontrolled chemoselective synthesis of chalcone and benzofuran frameworks via synergistic
dual directing groups enabled regioselective C–H functionalization: a combined experimental
and computational study. ACS Catal 8:9508–9519
154. Quiñones N, Seoane A, García-Fandiño R, Mascareñas JL, Gulías M (2013) Rhodium(III)catalyzed intramolecular annulations involving amide-directed C–H activations: synthetic
scope and mechanistic studies. Chem Sci 4:2874–2879
155. Algarra AG, Cross WB, Davies DL, Khamker Q, Macgregor SA, McMullin CL, Singh K
(2014) Combined experimental and computational investigations of rhodium- and rutheniumcatalyzed C–H functionalization of pyrazoles with alkynes. J Org Chem 79:1954–1970
156. Zheng J, Wang SB, Zheng C, You SL (2015) Asymmetric dearomatization of naphthols via
a Rh-Catalyzed C(sp 2 )-H functionalization/annulation reaction. J Am Chem Soc 137:4880–
4883
157. Zheng C, Zheng J, You S-L (2016) A DFT study on Rh-catalyzed asymmetric dearomatization
of 2-Naphthols Initiated with C–H activation: a refined reaction mechanism and origins of
multiple selectivity. ACS Catal 6:262–271
158. Seo J, Park Y, Jeon I, Ryu T, Park S, Lee PH (2013) Synthesis of phosphaisocoumarins through
rhodium-catalyzed cyclization using alkynes and arylphosphonic acid monoesters. Org Lett
15:3358–3361
159. Liu L, Wu Y, Wang T, Gao X, Zhu J, Zhao Y (2014) Mechanism, reactivity, and selectivity
in Rh(III)-catalyzed phosphoryl-directed oxidative C–H activation/cyclization: a DFT study.
J Org Chem 79:5074–5081
160. Fan Z, Song S, Li W, Geng K, Xu Y, Miao ZH, Zhang A (2015) Rh(III)-catalyzed redox-neutral
C–H activation of pyrazolones: an economical approach for the synthesis of N-substituted
indoles. Org Lett 17:310–313
161. Zhang G, Yang L, Wang Y, Xie Y, Huang H (2013) An efficient Rh/O2 catalytic system for
oxidative C–H activation/annulation: evidence for Rh(I) to Rh(III) oxidation by molecular
oxygen. J Am Chem Soc 135:8850–8853
162. Zhang X, Si W, Bao M, Asao N, Yamamoto Y, Jin T (2014) Rh(III)-catalyzed regioselective
functionalization of C-H bonds of naphthylcarbamates for oxidative annulation with alkynes.
Org Lett 16:4830–4833
163. Pham MV, Cramer N (2014) Rhodium(III)/copper(II)-promoted trans-selective heteroaryl
acyloxylation of alkynes: stereodefined access to trans-enol esters. Angew Chem Int Ed
53:14575–14579
164. Zhou B, Du J, Yang Y, Feng H, Li Y (2014) Rh(III)-catalyzed C–H amidation with Nhydroxycarbamates: a new entry to N-carbamate-protected arylamines. Org Lett 16:592–595
165. Huang X, Huang J, Du C, Zhang X, Song F, You J (2013) N-oxide as a traceless
oxidizing directing group: mild rhodium(III)-catalyzed C–H olefination for the synthesis of
ortho-alkenylated tertiary anilines. Angew Chem Int Ed 52:12970–12974
166. Li Y, Chen H, Qu L-B, Houk KN, Lan Y (2019) Origin of regiochemical control in
Rh(III)/Rh(V)-catalyzed reactions of unsaturated oximes and alkenes to form pyrdines. ACS
Catal 9:7154–7165
167. Liu B, Fan Y, Gao Y, Sun C, Xu C, Zhu J (2013) Rhodium(III)-catalyzed N-nitroso-directed
C-H olefination of arenes. High-yield, versatile coupling under mild conditions. J Am Chem
Soc 135:468–473
168. Liu G, Shen Y, Zhou Z, Lu X (2013) Rhodium(III)-catalyzed redox-neutral coupling of Nphenoxyacetamides and alkynes with tunable selectivity. Angew Chem Int Ed 52:6033–6037
169. Wangweerawong A, Bergman RG, Ellman JA (2014) Asymmetric synthesis of alpha-branched
amines via Rh(III)-catalyzed C-H bond functionalization. J Am Chem Soc 136:8520–8523
170. Xie W, Chen X, Shi J, Li J, Liu R (2019) Synthesis of 1-aminoindole derivatives via Rh(III)catalyzed annulation reactions of hydrazines with sulfoxonium ylides. Org Chem Front
6:2662–2666
93
152. Yi W, Li L, Chen H, Ma K, Zhong Y, Chen W, Gao H, Zhou Z (2018) Rh(III)-catalyzed
oxidative [5+2] annulation using two transient assisting groups: stereospecific assembly of
3-alkenylated benzoxepine framework. Org Lett 20:6812–6816
153. Yi W, Chen W, Liu FX, Zhong Y, Wu D, Zhou Z, Gao H (2018) Rh(III)-catalyzed and solventcontrolled chemoselective synthesis of chalcone and benzofuran frameworks via synergistic
dual directing groups enabled regioselective C–H functionalization: a combined experimental
and computational study. ACS Catal 8:9508–9519
154. Quiñones N, Seoane A, García-Fandiño R, Mascareñas JL, Gulías M (2013) Rhodium(III)catalyzed intramolecular annulations involving amide-directed C–H activations: synthetic
scope and mechanistic studies. Chem Sci 4:2874–2879
155. Algarra AG, Cross WB, Davies DL, Khamker Q, Macgregor SA, McMullin CL, Singh K
(2014) Combined experimental and computational investigations of rhodium- and rutheniumcatalyzed C–H functionalization of pyrazoles with alkynes. J Org Chem 79:1954–1970
156. Zheng J, Wang SB, Zheng C, You SL (2015) Asymmetric dearomatization of naphthols via
a Rh-Catalyzed C(sp 2 )-H functionalization/annulation reaction. J Am Chem Soc 137:4880–
4883
157. Zheng C, Zheng J, You S-L (2016) A DFT study on Rh-catalyzed asymmetric dearomatization
of 2-Naphthols Initiated with C–H activation: a refined reaction mechanism and origins of
multiple selectivity. ACS Catal 6:262–271
158. Seo J, Park Y, Jeon I, Ryu T, Park S, Lee PH (2013) Synthesis of phosphaisocoumarins through
rhodium-catalyzed cyclization using alkynes and arylphosphonic acid monoesters. Org Lett
15:3358–3361
159. Liu L, Wu Y, Wang T, Gao X, Zhu J, Zhao Y (2014) Mechanism, reactivity, and selectivity
in Rh(III)-catalyzed phosphoryl-directed oxidative C–H activation/cyclization: a DFT study.
J Org Chem 79:5074–5081
160. Fan Z, Song S, Li W, Geng K, Xu Y, Miao ZH, Zhang A (2015) Rh(III)-catalyzed redox-neutral
C–H activation of pyrazolones: an economical approach for the synthesis of N-substituted
indoles. Org Lett 17:310–313
161. Zhang G, Yang L, Wang Y, Xie Y, Huang H (2013) An efficient Rh/O2 catalytic system for
oxidative C–H activation/annulation: evidence for Rh(I) to Rh(III) oxidation by molecular
oxygen. J Am Chem Soc 135:8850–8853
162. Zhang X, Si W, Bao M, Asao N, Yamamoto Y, Jin T (2014) Rh(III)-catalyzed regioselective
functionalization of C-H bonds of naphthylcarbamates for oxidative annulation with alkynes.
Org Lett 16:4830–4833
163. Pham MV, Cramer N (2014) Rhodium(III)/copper(II)-promoted trans-selective heteroaryl
acyloxylation of alkynes: stereodefined access to trans-enol esters. Angew Chem Int Ed
53:14575–14579
164. Zhou B, Du J, Yang Y, Feng H, Li Y (2014) Rh(III)-catalyzed C–H amidation with Nhydroxycarbamates: a new entry to N-carbamate-protected arylamines. Org Lett 16:592–595
165. Huang X, Huang J, Du C, Zhang X, Song F, You J (2013) N-oxide as a traceless
oxidizing directing group: mild rhodium(III)-catalyzed C–H olefination for the synthesis of
ortho-alkenylated tertiary anilines. Angew Chem Int Ed 52:12970–12974
166. Li Y, Chen H, Qu L-B, Houk KN, Lan Y (2019) Origin of regiochemical control in
Rh(III)/Rh(V)-catalyzed reactions of unsaturated oximes and alkenes to form pyrdines. ACS
Catal 9:7154–7165
167. Liu B, Fan Y, Gao Y, Sun C, Xu C, Zhu J (2013) Rhodium(III)-catalyzed N-nitroso-directed
C-H olefination of arenes. High-yield, versatile coupling under mild conditions. J Am Chem
Soc 135:468–473
168. Liu G, Shen Y, Zhou Z, Lu X (2013) Rhodium(III)-catalyzed redox-neutral coupling of Nphenoxyacetamides and alkynes with tunable selectivity. Angew Chem Int Ed 52:6033–6037
169. Wangweerawong A, Bergman RG, Ellman JA (2014) Asymmetric synthesis of alpha-branched
amines via Rh(III)-catalyzed C-H bond functionalization. J Am Chem Soc 136:8520–8523
170. Xie W, Chen X, Shi J, Li J, Liu R (2019) Synthesis of 1-aminoindole derivatives via Rh(III)catalyzed annulation reactions of hydrazines with sulfoxonium ylides. Org Chem Front
6:2662–2666