26
D. W. Stephan
104. Farrell JM, Heiden ZM, Stephan DW (2011) Metal-Free Transfer Hydrogenation Catalysis
by B(C 6 F 5 ) 3 . Organometallics 30(17):4497–4500. https://doi.org/10.1021/Om2005832
105. Yuan W, Orecchia P, Oestreich M (2017) Cyclohexa-1,3-diene-Based Dihydrogen
and Hydrosilane Surrogates in B(C 6 F 5 ) 3 -Catalysed Transfer Processes. Chem Comm
53(75):10390–10393. https://doi.org/10.1039/c7cc06195a
106. Chen J, Chen EXY (2015) Reactivity of Amine/E(C 6 F 5 ) 3 (E = B, Al) Lewis Pairs Toward
Linear and Cyclic Acrylic Monomers: Hydrogenation versus Polymerization. Molecules
20(6):9575–9590. doi: https://doi.org/10.3390/molecules20069575
107. Khan I, Reed-Berendt BG, Melen RL, Morrill LC (2018) FLP-Catalyzed Transfer Hydrogenation of Silyl Enol Ethers. Angew Chem Int Ed 57(38):12356–12359. https://doi.org/10.
1002/anie.201808800
108. Dunn NL, Ha MJ, Radosevich AT (2012) Main Group Redox Catalysis: Reversible P-III/P-V
Redox Cycling at a Phosphorus Platform. J Am Chem Soc 134(28):11330–11333. https://
doi.org/10.1021/ja302963p
109. Li SL, Li G, Meng W, Du HF (2016) A Frustrated Lewis Pair Catalyzed Asymmetric Transfer
Hydrogenation of Imines Using Ammonia Borane. J Am Chem Soc 138(39):12956–12962.
https://doi.org/10.1021/jacs.6b07245
110. Meng W, Feng X, Du H (2018) Frustrated Lewis Pairs Catalyzed Asymmetric Metal-Free
Hydrogenations and Hydrosilylations. Acc Chem Res 51(1):191–201. https://doi.org/10.
1021/acs.accounts.7b00530
111. Dureen MA, Lough A, Gilbert TM, Stephan DW (2008) B-H Activation by Frustrated Lewis
Pairs: Borenium or Boryl Phosphonium Cation? Chem Commun 36:4303–4305. https://doi.
org/10.1039/B808348g
112. Fan XT, Zheng JH, Li ZH, Wang HD (2015) Organoborane Catalyzed Regioselective 1,4Hydroboration of Pyridines. J Am Chem Soc 137(15):4916–4919. https://doi.org/10.1021/
jacs.5b03147
113. Fleige M, Mobus J, vom Stein T, Glorius F, Stephan DW (2016) Lewis Acid Catalysis: Catalytic Hydroboration of Alkynes Initiated by Piers’ Borane. Chem Commun
52(72):10830–10833. https://doi.org/10.1039/c6cc05360b
114. Yin Q, Kemper S, Klare HF, Oestreich M (2016) Boron Lewis Acid-Catalyzed Hydroboration
of Alkenes with Pinacolborane: B(Ar F ) 3 Does What B(C 6 F 5 ) 3 Cannot Do! Chem Eur J
22(39):13840–13844. https://doi.org/10.1002/chem.201603466
115. Yin Q, Soltani Y, Melen RL, Oestreich M (2017) BAr 3
F -Catalyzed Imine Hydroboration with
Pinacolborane not Requiring the Assistance of an Additional Lewis Base. Organometallics
36(13):2381–2384. https://doi.org/10.1021/acs.organomet.7b00381
116. Lawson JR, Wilkins LC, Melen RL (2017) Tris(2,4,6-trifluorophenyl)borane: An Efficient
Hydroboration Catalyst. Chem Eur J 23(46):10997–11000. https://doi.org/10.1002/chem.201
703109
117. Cade IA, Ingleson MJ (2014) syn-1,2-Carboboration of Alkynes with Borenium Cations.
Chem Eur J 20(40):12874–12880. https://doi.org/10.1002/chem.201403614
118. McGough JS, Butler SM, Cade IA, Ingleson MJ (2016) Highly Selective Catalytic transHydroboration of Alkynes Mediated by Borenium Cations and B(C 6 F 5 ) 3 . Chem Sci 7:3384–
3389. https://doi.org/10.1039/c5sc04798f
119. Eisenberger P, Bailey AM, Crudden CM (2012) Taking the F out of FLP: Simple Lewis AcidBase Pairs for Mild Reductions with Neutral Boranes via Borenium Ion Catalysis. J Am Chem
Soc 134(42):17384–17387. https://doi.org/10.1021/Ja307374j
120. Mahdi T, Stephan DW (2013) Frustrated Lewis Pair Catalyzed Hydroamination of Terminal
Alkynes. Angew Chem Int Ed 52(47):12418–12421. https://doi.org/10.1002/anie.201307254
121. Mahdi T, Stephan DW (2015b) Stoichiometric and Catalytic Inter- and Intramolecular
Hydroamination of Terminal Alkynes by Frustrated Lewis Pairs. Chem Eur J 21(31):11134–
11142. https://doi.org/10.1002/chem.201501535
122. Shang M, Wang XX, Koo SM, Youn J, Chan JZ, Yao WZ, Hastings BT, Wasa M (2017)
Frustrated Lewis Acid/Brønsted Base Catalysts for Direct Enantioselective alpha-Amination
of Carbonyl Compounds. J Am Chem Soc 139(1):95–98. https://doi.org/10.1021/jacs.6b1
1908
D. W. Stephan
104. Farrell JM, Heiden ZM, Stephan DW (2011) Metal-Free Transfer Hydrogenation Catalysis
by B(C 6 F 5 ) 3 . Organometallics 30(17):4497–4500. https://doi.org/10.1021/Om2005832
105. Yuan W, Orecchia P, Oestreich M (2017) Cyclohexa-1,3-diene-Based Dihydrogen
and Hydrosilane Surrogates in B(C 6 F 5 ) 3 -Catalysed Transfer Processes. Chem Comm
53(75):10390–10393. https://doi.org/10.1039/c7cc06195a
106. Chen J, Chen EXY (2015) Reactivity of Amine/E(C 6 F 5 ) 3 (E = B, Al) Lewis Pairs Toward
Linear and Cyclic Acrylic Monomers: Hydrogenation versus Polymerization. Molecules
20(6):9575–9590. doi: https://doi.org/10.3390/molecules20069575
107. Khan I, Reed-Berendt BG, Melen RL, Morrill LC (2018) FLP-Catalyzed Transfer Hydrogenation of Silyl Enol Ethers. Angew Chem Int Ed 57(38):12356–12359. https://doi.org/10.
1002/anie.201808800
108. Dunn NL, Ha MJ, Radosevich AT (2012) Main Group Redox Catalysis: Reversible P-III/P-V
Redox Cycling at a Phosphorus Platform. J Am Chem Soc 134(28):11330–11333. https://
doi.org/10.1021/ja302963p
109. Li SL, Li G, Meng W, Du HF (2016) A Frustrated Lewis Pair Catalyzed Asymmetric Transfer
Hydrogenation of Imines Using Ammonia Borane. J Am Chem Soc 138(39):12956–12962.
https://doi.org/10.1021/jacs.6b07245
110. Meng W, Feng X, Du H (2018) Frustrated Lewis Pairs Catalyzed Asymmetric Metal-Free
Hydrogenations and Hydrosilylations. Acc Chem Res 51(1):191–201. https://doi.org/10.
1021/acs.accounts.7b00530
111. Dureen MA, Lough A, Gilbert TM, Stephan DW (2008) B-H Activation by Frustrated Lewis
Pairs: Borenium or Boryl Phosphonium Cation? Chem Commun 36:4303–4305. https://doi.
org/10.1039/B808348g
112. Fan XT, Zheng JH, Li ZH, Wang HD (2015) Organoborane Catalyzed Regioselective 1,4Hydroboration of Pyridines. J Am Chem Soc 137(15):4916–4919. https://doi.org/10.1021/
jacs.5b03147
113. Fleige M, Mobus J, vom Stein T, Glorius F, Stephan DW (2016) Lewis Acid Catalysis: Catalytic Hydroboration of Alkynes Initiated by Piers’ Borane. Chem Commun
52(72):10830–10833. https://doi.org/10.1039/c6cc05360b
114. Yin Q, Kemper S, Klare HF, Oestreich M (2016) Boron Lewis Acid-Catalyzed Hydroboration
of Alkenes with Pinacolborane: B(Ar F ) 3 Does What B(C 6 F 5 ) 3 Cannot Do! Chem Eur J
22(39):13840–13844. https://doi.org/10.1002/chem.201603466
115. Yin Q, Soltani Y, Melen RL, Oestreich M (2017) BAr 3
F -Catalyzed Imine Hydroboration with
Pinacolborane not Requiring the Assistance of an Additional Lewis Base. Organometallics
36(13):2381–2384. https://doi.org/10.1021/acs.organomet.7b00381
116. Lawson JR, Wilkins LC, Melen RL (2017) Tris(2,4,6-trifluorophenyl)borane: An Efficient
Hydroboration Catalyst. Chem Eur J 23(46):10997–11000. https://doi.org/10.1002/chem.201
703109
117. Cade IA, Ingleson MJ (2014) syn-1,2-Carboboration of Alkynes with Borenium Cations.
Chem Eur J 20(40):12874–12880. https://doi.org/10.1002/chem.201403614
118. McGough JS, Butler SM, Cade IA, Ingleson MJ (2016) Highly Selective Catalytic transHydroboration of Alkynes Mediated by Borenium Cations and B(C 6 F 5 ) 3 . Chem Sci 7:3384–
3389. https://doi.org/10.1039/c5sc04798f
119. Eisenberger P, Bailey AM, Crudden CM (2012) Taking the F out of FLP: Simple Lewis AcidBase Pairs for Mild Reductions with Neutral Boranes via Borenium Ion Catalysis. J Am Chem
Soc 134(42):17384–17387. https://doi.org/10.1021/Ja307374j
120. Mahdi T, Stephan DW (2013) Frustrated Lewis Pair Catalyzed Hydroamination of Terminal
Alkynes. Angew Chem Int Ed 52(47):12418–12421. https://doi.org/10.1002/anie.201307254
121. Mahdi T, Stephan DW (2015b) Stoichiometric and Catalytic Inter- and Intramolecular
Hydroamination of Terminal Alkynes by Frustrated Lewis Pairs. Chem Eur J 21(31):11134–
11142. https://doi.org/10.1002/chem.201501535
122. Shang M, Wang XX, Koo SM, Youn J, Chan JZ, Yao WZ, Hastings BT, Wasa M (2017)
Frustrated Lewis Acid/Brønsted Base Catalysts for Direct Enantioselective alpha-Amination
of Carbonyl Compounds. J Am Chem Soc 139(1):95–98. https://doi.org/10.1021/jacs.6b1
1908