24
D. W. Stephan
69. Korte LA, Blomeyer S, Heidemeyer S, Mix A, Neumann B, Mitzel NW (2016) Intramolecular
Cooperativity in Frustrated Lewis Pairs. Chem Commun 52(64):9949–9952. https://doi.org/
10.1039/C6CC05228B
70. Özgün T, Ye KY, Daniliuc CG, Wibbeling B, Liu L, Grimme S, Kehr G, Erker
G (2016) Why Does the Intramolecular Trimethylene-Bridged Frustrated Lewis Pair
Mes 2 PCH 2 CH 2 CH 2 B(C 6 F 5 ) 2 Not Activate Dihydrogen? Chem Eur J 22(17):5988–5995.
https://doi.org/10.1002/chem.201505200
71. Xu MT, Possart J, Waked AE, Roy J, Uhl W, Stephan DW (2017) Halogenated Triphenylgallium and -Indium in Frustrated Lewis Pair Activations and Hydrogenation Catalysis. Phil
Trans a 375:2101. https://doi.org/10.1098/rsta.2017.0014
72. Farrell JM, Hatnean JA, Stephan DW (2012) Activation of Hydrogen and Hydrogenation
Catalysis by a Borenium Cation. J Am Chem Soc 134(38):15728–15731. https://doi.org/10.
1021/Ja307995f
73. Farrell JM, Posaratnanathan RT, Stephan DW (2015) A Family of N-Heterocyclic CarbeneStabilized Borenium Ions for Metal-Free Imine Hydrogenation Catalysis. Chem Sci
6(3):2010–2015. https://doi.org/10.1039/c4sc03675a
74. Eisenberger P, Bestvater BP, Keske EC, Crudden CM (2015) Hydrogenations at Room Temperature and Atmospheric Pressure with Mesoionic Carbene-Stabilized Borenium Catalysts.
Angew Chem Int Ed 54(8):2467–2471. https://doi.org/10.1002/anie.201409250
75. Caputo CB, Hounjet LJ, Dobrovetsky R, Stephan DW (2013) Lewis Acidity of
Organofluorophosphonium Salts: Hydrodefluorination by a Saturated Acceptor. Science
341(6152):1374–1377. https://doi.org/10.1126/science.1241764
76. vom Stein T, Pérez M, Dobrovetsky R, Winkelhaus D, Caputo CB, Stephan DW (2015)
Electrophilic Fluorophosphonium Cations in Frustrated Lewis Pair Hydrogen Activation and
Catalytic Hydrogenation of Olefins. Angew Chem Int Ed 54(35):10178–10182. https://doi.
org/10.1002/anie.201504109
77. Clark ER, Ingleson MJ (2014) N-Methylacridinium Salts: Carbon Lewis Acids in Frustrated Lewis Pairs for Sigma-Bond Activation and Catalytic Reductions. Angew Chem Int Ed
53(42):11306–11309. https://doi.org/10.1002/anie.201406122
78. Boone MP, Stephan DW (2013) A Ru-eta(6)-Arene Complex as a C-Based Lewis Acid in the
Activation of Hydrogen and Hydrogenation Catalysis. J Am Chem Soc 135(23):8508–8511.
https://doi.org/10.1021/Ja403912n
79. Flynn SR, Wass DF (2013) Transition Metal Frustrated Lewis Pairs. ACS Catalysis
3(11):2574–2581. https://doi.org/10.1021/cs400754w
80. Harman WH, Peters JC (2012) Reversible H 2 Addition Across a Nickel-Borane Unit as a
Promising Strategy for Catalysis. J Am Chem Soc 134(11):5080–5082. https://doi.org/10.
1021/ja211419t
81. Xu MT, Jupp AR, Qu ZW, Stephan DW (2018) Alkali Metal Species in the Reversible Activation of H 2 . Angew Chem Int Ed 57(34):11050–11054. https://doi.org/10.1002/ange.201
806849
82. Lu G, Zhang P, Sun D, Wang L, Zhou K, Wang Z-X, Guo G-C (2014) Gold Catalyzed
Hydrogenations of Small Imines and Nitriles: Enhanced Reactivity of Au Surface Toward H 2
via Collaboration with a Lewis Base. Chem Sci 5:1082–1090. https://doi.org/10.1039/C3S
C52851K
83. Niu Z, Bhagya-Gunatilleke WDC, Sun Q, Lan PC, Perman J, Ma J-G, Cheng Y, Aguila B,
Ma S (2018) Metal-Organic Framework Anchored with a Lewis Pair as a New Paradigm for
Catalysis. Chem 2587–2599. https://doi.org/10.1016/j.chempr.2018.08.018
84. Stephan DW (2018) Frustrated Lewis Pair Chemistry Meets Metal-Organic Frameworks.
Chem 4(11):2483–2485. https://doi.org/10.1016/j.chempr.2018.09.008
85. Niu Z, Zhang W, Lan PC, Aguila B, Ma S (2019) Promoting Frustrated Lewis Pairs for
Heterogeneous Chemoselective Hydrogenation via the Tailored Pore Environment Within
Metal-Organic Frameworks. Angew Chem Int Ed 58(22):7420–7424. https://doi.org/10.1002/
anie.201903763
D. W. Stephan
69. Korte LA, Blomeyer S, Heidemeyer S, Mix A, Neumann B, Mitzel NW (2016) Intramolecular
Cooperativity in Frustrated Lewis Pairs. Chem Commun 52(64):9949–9952. https://doi.org/
10.1039/C6CC05228B
70. Özgün T, Ye KY, Daniliuc CG, Wibbeling B, Liu L, Grimme S, Kehr G, Erker
G (2016) Why Does the Intramolecular Trimethylene-Bridged Frustrated Lewis Pair
Mes 2 PCH 2 CH 2 CH 2 B(C 6 F 5 ) 2 Not Activate Dihydrogen? Chem Eur J 22(17):5988–5995.
https://doi.org/10.1002/chem.201505200
71. Xu MT, Possart J, Waked AE, Roy J, Uhl W, Stephan DW (2017) Halogenated Triphenylgallium and -Indium in Frustrated Lewis Pair Activations and Hydrogenation Catalysis. Phil
Trans a 375:2101. https://doi.org/10.1098/rsta.2017.0014
72. Farrell JM, Hatnean JA, Stephan DW (2012) Activation of Hydrogen and Hydrogenation
Catalysis by a Borenium Cation. J Am Chem Soc 134(38):15728–15731. https://doi.org/10.
1021/Ja307995f
73. Farrell JM, Posaratnanathan RT, Stephan DW (2015) A Family of N-Heterocyclic CarbeneStabilized Borenium Ions for Metal-Free Imine Hydrogenation Catalysis. Chem Sci
6(3):2010–2015. https://doi.org/10.1039/c4sc03675a
74. Eisenberger P, Bestvater BP, Keske EC, Crudden CM (2015) Hydrogenations at Room Temperature and Atmospheric Pressure with Mesoionic Carbene-Stabilized Borenium Catalysts.
Angew Chem Int Ed 54(8):2467–2471. https://doi.org/10.1002/anie.201409250
75. Caputo CB, Hounjet LJ, Dobrovetsky R, Stephan DW (2013) Lewis Acidity of
Organofluorophosphonium Salts: Hydrodefluorination by a Saturated Acceptor. Science
341(6152):1374–1377. https://doi.org/10.1126/science.1241764
76. vom Stein T, Pérez M, Dobrovetsky R, Winkelhaus D, Caputo CB, Stephan DW (2015)
Electrophilic Fluorophosphonium Cations in Frustrated Lewis Pair Hydrogen Activation and
Catalytic Hydrogenation of Olefins. Angew Chem Int Ed 54(35):10178–10182. https://doi.
org/10.1002/anie.201504109
77. Clark ER, Ingleson MJ (2014) N-Methylacridinium Salts: Carbon Lewis Acids in Frustrated Lewis Pairs for Sigma-Bond Activation and Catalytic Reductions. Angew Chem Int Ed
53(42):11306–11309. https://doi.org/10.1002/anie.201406122
78. Boone MP, Stephan DW (2013) A Ru-eta(6)-Arene Complex as a C-Based Lewis Acid in the
Activation of Hydrogen and Hydrogenation Catalysis. J Am Chem Soc 135(23):8508–8511.
https://doi.org/10.1021/Ja403912n
79. Flynn SR, Wass DF (2013) Transition Metal Frustrated Lewis Pairs. ACS Catalysis
3(11):2574–2581. https://doi.org/10.1021/cs400754w
80. Harman WH, Peters JC (2012) Reversible H 2 Addition Across a Nickel-Borane Unit as a
Promising Strategy for Catalysis. J Am Chem Soc 134(11):5080–5082. https://doi.org/10.
1021/ja211419t
81. Xu MT, Jupp AR, Qu ZW, Stephan DW (2018) Alkali Metal Species in the Reversible Activation of H 2 . Angew Chem Int Ed 57(34):11050–11054. https://doi.org/10.1002/ange.201
806849
82. Lu G, Zhang P, Sun D, Wang L, Zhou K, Wang Z-X, Guo G-C (2014) Gold Catalyzed
Hydrogenations of Small Imines and Nitriles: Enhanced Reactivity of Au Surface Toward H 2
via Collaboration with a Lewis Base. Chem Sci 5:1082–1090. https://doi.org/10.1039/C3S
C52851K
83. Niu Z, Bhagya-Gunatilleke WDC, Sun Q, Lan PC, Perman J, Ma J-G, Cheng Y, Aguila B,
Ma S (2018) Metal-Organic Framework Anchored with a Lewis Pair as a New Paradigm for
Catalysis. Chem 2587–2599. https://doi.org/10.1016/j.chempr.2018.08.018
84. Stephan DW (2018) Frustrated Lewis Pair Chemistry Meets Metal-Organic Frameworks.
Chem 4(11):2483–2485. https://doi.org/10.1016/j.chempr.2018.09.008
85. Niu Z, Zhang W, Lan PC, Aguila B, Ma S (2019) Promoting Frustrated Lewis Pairs for
Heterogeneous Chemoselective Hydrogenation via the Tailored Pore Environment Within
Metal-Organic Frameworks. Angew Chem Int Ed 58(22):7420–7424. https://doi.org/10.1002/
anie.201903763