5 Mechanistic Insight into the Hydrogen Activation by Frustrated Lewis Pairs
203
References
1. Maseras F, Lledós A, Clot E, Eisenstein O (2000) Transition Metal Polyhydrides: From
Qualitative Ideas to Reliable Computational Studies. Chem Rev 100:601–636. https://doi.org/
10.1021/cr980397d (b) Samec JSM, Bäckvall JE, Andersson PG, Brandt P (2006) Mechanistic
Aspects of Transition Metal-Catalyzed Hydrogen Transfer Reactions. Chem Soc Rev 35:237–
248. https://doi.org/10.1039/B515269K (c) Kubas G J (2007) Fundamentals of H 2 Binding
and Reactivity on Transition Metals Underlying Hydrogenase Function and H 2 Production and
Storage. Chem Rev 107:4152–4205. https://doi.org/10.1021/cr050197j (d) Darwish M, Wills
M (2012) Asymmetric Catalysis using Iron Complexes - ‘Ruthenium Lite’? Catal Sci Technol
2:243–255. https://doi.org/10.1039/C1CY00390A (e) Friedfeld MR, Shevlin M, Hoyt JM,
Krska SW, Tudge MT, Chirik PJ (2013) Cobalt Precursors for High-Throughput Discovery of
Base Metal Asymmetric Alkene Hydrogenation Catalysts. Science 342:1076–1080. https://
doi.org/10.1126/science.1243550 (f) Bullock RM (2013) Abundant Metals Give Precious
Hydrogenation Performance. Science 342: 1054–1055. https://doi.org/10.1126/science.124
7240
2. Stephan DW (2016) The Broadening Reach of Frustrated Lewis Pair Chemistry. Science
354:1248–1256. https://doi.org/10.1126/science.aaf7229 (b) Scott DJ, Fuchter MJ, Ashley
AE (2017) Designing Effective ‘Frustrated Lewis Pair’ Hydrogenation Catalysts. Chem Soc
Rev 46:5689–5700. https://doi.org/10.1039/C7CS00154A (c) Liu L, Lukose B, Jaque P, et al
(2019) Reaction Mechanism of Hydrogen Activation by Frustrated Lewis Pairs. Green Energy
Environ 1:20–28. https://doi.org/10.1016/j.gee.2018.06.001 (d) Paradies J (2019) From Structure to Novel Reactivity in Frustrated Lewis Pairs. Coord Chem Rev 380:170–183. https://doi.
org/10.1016/j.ccr.2018.09.014 (e) Jupp AR, Stephan DW (2019) New Directions for Frustrated Lewis Pair Chemistry. Trends Chem 1:35–48. https://doi.org/10.1016/j.trechm.2019.
01.006
3. Frey GD, Lavallo V, Donnadieu B, Schoeller WW, Bertrand G (2007) Facile Splitting of
Hydrogen and Ammonia by Nucleophilic Activation at a Single Carbon Center. Science
316:439–441. https://doi.org/10.1126/science.1141474
4. Berkessel A, Schubert TJS, Müller TN (2002) Hydrogenation Without a Transition-Metal
Catalyst: On the Mechanism of the Base-Catalyzed Hydrogenation of Ketones. J Am Chem
Soc 124:8693–8698. https://doi.org/10.1021/ja016152r
5. Welch GC, San Juan RR, Masuda JD, Stephan DW (2006) Reversible Metal-Free Hydrogen
Activation. Science 314:1124–1126. https://doi.org/10.1126/science.1134230
6. Lewis GN (1923) Valence and the Structure of Atoms and Molecules. Chemical Catalogue
Company
7. Jian Z, Kehr G, Daniliuc CG, Wibbeling B, Wiegand T, Siedow M, Eckert H, Bursch M,
Grimme S, Erker G (2017) CO-Reduction Chemistry: Reaction of a CO-Derived Formylhydridoborate with Carbon Monoxide, with Carbon Dioxide, and with Dihydrogen. J Am Chem
Soc 139:6474–6483. https://doi.org/10.1021/jacs.7b02548
8. Bontemps S (2016) Boron-Mediated Activation of Carbon Dioxide. Coord Chem Rev
308:117–130. https://doi.org/10.1016/j.ccr.2015.06.003
9. Chi JJ, Johnstone TC, Voicu D, Mehlmann P, Dielmann F, Kumacheva E, Stephan DW (2017)
Quantifying the Efficiency of CO 2 Capture by Lewis Pairs. Chem Sci 8:3270–3275. https://
doi.org/10.1039/C6SC05607E
10. Lang XD, He X, Li ZM, He LN (2017) New Routes for CO 2 Activation and Subsequent
Conversion. Curr Opin Green Sustain Chem 7:31–38. https://doi.org/10.1016/j.cogsc.2017.
07.001
11. Ghara M, Chattaraj PK (2018) Fixation of Nitrous Oxide (N 2 O) by 1,4,2,5-Diazadiborinine:
A DFT Study. Int J Quantum Chem 118:e25593. https://doi.org/10.1002/qua.25593
12. Stephan DW, Erker G (2014) Frustrated Lewis Pair Chemistry of Carbon, Nitrogen and Sulfur
Oxides. Chem Sci 5:2625–2641. https://doi.org/10.1039/C4SC00395K
13. Kehr G, Schwendemann S, Erker G (2013) Intramolecular Frustrated Lewis Pairs: Formation
and Chemical Features. In: Erker G., Stephan D. (eds) Frustrated Lewis Pairs I. Top Curr
Chem 332:45–84. https://doi.org/10.1007/128_2012_373
203
References
1. Maseras F, Lledós A, Clot E, Eisenstein O (2000) Transition Metal Polyhydrides: From
Qualitative Ideas to Reliable Computational Studies. Chem Rev 100:601–636. https://doi.org/
10.1021/cr980397d (b) Samec JSM, Bäckvall JE, Andersson PG, Brandt P (2006) Mechanistic
Aspects of Transition Metal-Catalyzed Hydrogen Transfer Reactions. Chem Soc Rev 35:237–
248. https://doi.org/10.1039/B515269K (c) Kubas G J (2007) Fundamentals of H 2 Binding
and Reactivity on Transition Metals Underlying Hydrogenase Function and H 2 Production and
Storage. Chem Rev 107:4152–4205. https://doi.org/10.1021/cr050197j (d) Darwish M, Wills
M (2012) Asymmetric Catalysis using Iron Complexes - ‘Ruthenium Lite’? Catal Sci Technol
2:243–255. https://doi.org/10.1039/C1CY00390A (e) Friedfeld MR, Shevlin M, Hoyt JM,
Krska SW, Tudge MT, Chirik PJ (2013) Cobalt Precursors for High-Throughput Discovery of
Base Metal Asymmetric Alkene Hydrogenation Catalysts. Science 342:1076–1080. https://
doi.org/10.1126/science.1243550 (f) Bullock RM (2013) Abundant Metals Give Precious
Hydrogenation Performance. Science 342: 1054–1055. https://doi.org/10.1126/science.124
7240
2. Stephan DW (2016) The Broadening Reach of Frustrated Lewis Pair Chemistry. Science
354:1248–1256. https://doi.org/10.1126/science.aaf7229 (b) Scott DJ, Fuchter MJ, Ashley
AE (2017) Designing Effective ‘Frustrated Lewis Pair’ Hydrogenation Catalysts. Chem Soc
Rev 46:5689–5700. https://doi.org/10.1039/C7CS00154A (c) Liu L, Lukose B, Jaque P, et al
(2019) Reaction Mechanism of Hydrogen Activation by Frustrated Lewis Pairs. Green Energy
Environ 1:20–28. https://doi.org/10.1016/j.gee.2018.06.001 (d) Paradies J (2019) From Structure to Novel Reactivity in Frustrated Lewis Pairs. Coord Chem Rev 380:170–183. https://doi.
org/10.1016/j.ccr.2018.09.014 (e) Jupp AR, Stephan DW (2019) New Directions for Frustrated Lewis Pair Chemistry. Trends Chem 1:35–48. https://doi.org/10.1016/j.trechm.2019.
01.006
3. Frey GD, Lavallo V, Donnadieu B, Schoeller WW, Bertrand G (2007) Facile Splitting of
Hydrogen and Ammonia by Nucleophilic Activation at a Single Carbon Center. Science
316:439–441. https://doi.org/10.1126/science.1141474
4. Berkessel A, Schubert TJS, Müller TN (2002) Hydrogenation Without a Transition-Metal
Catalyst: On the Mechanism of the Base-Catalyzed Hydrogenation of Ketones. J Am Chem
Soc 124:8693–8698. https://doi.org/10.1021/ja016152r
5. Welch GC, San Juan RR, Masuda JD, Stephan DW (2006) Reversible Metal-Free Hydrogen
Activation. Science 314:1124–1126. https://doi.org/10.1126/science.1134230
6. Lewis GN (1923) Valence and the Structure of Atoms and Molecules. Chemical Catalogue
Company
7. Jian Z, Kehr G, Daniliuc CG, Wibbeling B, Wiegand T, Siedow M, Eckert H, Bursch M,
Grimme S, Erker G (2017) CO-Reduction Chemistry: Reaction of a CO-Derived Formylhydridoborate with Carbon Monoxide, with Carbon Dioxide, and with Dihydrogen. J Am Chem
Soc 139:6474–6483. https://doi.org/10.1021/jacs.7b02548
8. Bontemps S (2016) Boron-Mediated Activation of Carbon Dioxide. Coord Chem Rev
308:117–130. https://doi.org/10.1016/j.ccr.2015.06.003
9. Chi JJ, Johnstone TC, Voicu D, Mehlmann P, Dielmann F, Kumacheva E, Stephan DW (2017)
Quantifying the Efficiency of CO 2 Capture by Lewis Pairs. Chem Sci 8:3270–3275. https://
doi.org/10.1039/C6SC05607E
10. Lang XD, He X, Li ZM, He LN (2017) New Routes for CO 2 Activation and Subsequent
Conversion. Curr Opin Green Sustain Chem 7:31–38. https://doi.org/10.1016/j.cogsc.2017.
07.001
11. Ghara M, Chattaraj PK (2018) Fixation of Nitrous Oxide (N 2 O) by 1,4,2,5-Diazadiborinine:
A DFT Study. Int J Quantum Chem 118:e25593. https://doi.org/10.1002/qua.25593
12. Stephan DW, Erker G (2014) Frustrated Lewis Pair Chemistry of Carbon, Nitrogen and Sulfur
Oxides. Chem Sci 5:2625–2641. https://doi.org/10.1039/C4SC00395K
13. Kehr G, Schwendemann S, Erker G (2013) Intramolecular Frustrated Lewis Pairs: Formation
and Chemical Features. In: Erker G., Stephan D. (eds) Frustrated Lewis Pairs I. Top Curr
Chem 332:45–84. https://doi.org/10.1007/128_2012_373