184
V. Schünemann
Fig. 4.7 Simplified scheme for the analysis of paramagnetic Mössbauer spectra with the help of
the spin Hamiltonian formalism. The upper, blue area visualizes the calculation of the electronic
problem. In the lower part, highlighted in red, the energy eigenvalues of the nuclear Hamiltonian
operator are calculated which are used to obtain nuclear transition energies and probabilities. Note
that for a powder sample this has to be done for every orientation of the molecule with respect to
the external field direction which serves as the quantization axis
V. Schünemann
Fig. 4.7 Simplified scheme for the analysis of paramagnetic Mössbauer spectra with the help of
the spin Hamiltonian formalism. The upper, blue area visualizes the calculation of the electronic
problem. In the lower part, highlighted in red, the energy eigenvalues of the nuclear Hamiltonian
operator are calculated which are used to obtain nuclear transition energies and probabilities. Note
that for a powder sample this has to be done for every orientation of the molecule with respect to
the external field direction which serves as the quantization axis