64
3 Technetium Coordinated by Inorganic Ligands in Aqueous …
Baldas J, Heath GA, Macgregor SA et al (1998) Spectroelectrochemical and computational studies
of tetrachloro and tetrabromo oxo- and nitrido-technetium(V) and their TcVI counterparts. J
Chem Soc Dalton Trans 2303–2314
Bancroft EE, Sidwell JS, Blount HN (1981) Derivative linear sweep and derivative cyclic
voltabsorptometry. Anal Chem 53:1390–1394
Boyd GE (1978) Osmotic and activity coefficients of aqueous HTcO 4 and HReO 4 solutions at 25
°C. Inor Chem 17(7):1808–1810
Chatterjee S, Hall GB, Johnsonet IE et al (2018) Surprising formation of quasi-stable Tc(VI) in
high ionic strength alkaline media. Inorg Chem Front 5:2081–2091
Chotkowski M, Czerwi´ nski A (2012) Electrochemical and spectroelectrochemical studies of
pertechnetate electroreduction in acidic media. Electrochim Acta 76:165–173
Chotkowski M, Czerwi´ nski A (2014a) Thin layer spectroelectrochemical (RVC-OTTLE) studies
of pertechnetate reduction in acidic media. J Radioanal Nucl Chem 300:229–234
Chotkowski M, Czerwi´ nski A (2014b) Thin layer spectroelectrochemical studies of pertechnetate
reduction on the gold electrodes in acidic media. Electrochim Acta 121:44–48
Chotkowski M, Wrzosek B, Grde´ n M (2018a) Intermediate oxidation states of technetium in
concentrated sulfuric acid solutions. J Electroanal Chem 814:83–90
Chotkowski M, Grde´ n M, Wrzosek B (2018b) Intermediate oxidation states of technetium in alkaline
solutions. J Electroanal Chem 829:148–156
Clarke MJ, Fackler PH (1982) The chemistry of technetium toward improved diagnostic agents in:
structure and bonding, vol 50. Topics in Inorganic and Physical Chemistry. Springer, p. 62
Cobble JW, Smith WT, Boyd GE (1953) Thermodynamic properties of technetium and rhenium
compounds. II. Heats of formation of technetium heptoxide and pertechnic acid, potential of the
technetium(IV)-technetium(VII) couple, and a potential diagram for technetium. J Am Chem Soc
75:5777–5782
Colton R, Dalziel J, Griffith WP et al. (1960) Polarographic study of manganese, technetium, and
rhenium. J Chem Soc 71–79
Compton RG, Banks CE (2011) Understanding voltammetry, 2nd edn, Ch. 7. Imperial College Press
Cotton FA, Pedersen E (1975) Magnetic and electrochemical properties of transition metal
complexes with multiple metal-to-metal bonds. I. [Tc 2 Cl 8 ] n− and [Re 2 Cl 8 ] n− with n = 2 and 3.
Inorg Chem 14(2):388–391
Courson O, Le Naour C, David F et al. (1999) Electrochemical behawior of technetium in acetic
buffer. Czechoslov J Phys 49(Suppl S1): 687–694
Deutsch E, Heinemann W, Hurst R et al (1978) Production, detection, and characterization of
transient hexavalent technetium in aqueous alkaline media by pulse radiolysis and very fast scan
cyclic voltammetry. JCS Chem Comm 1038–1040
Duluard S, Ouvrard B, Celik-Cochet A et al (2010) Comparision of PEDOT films obtained via three
different routhes through spectroelectrochemistry and the differential cyclic voltabsorptometry
method (DCVA). J Phys Chem B 114:7445–7451
Founta A, Aikens DA, Clark HM (1987) Mechanism and kinetics of the stepwise voltammetric
reduction of pertechnetates in alkali solutions to Tc(VI), Tc(V) and Tc(IV). J Electroanal Chem
219:221–246
Galus Z (1976) Fundamentals of electrochemical analysis, Chapter 3. Horwood – PWN Warszawa
German K, Kryutchkov SV (2002) Polynuclear technetium halide clusters. Russ J Inorg Chem
47(4):578–583
Gorshkov NI, Miroslavov AE, Lumpov AA et al (2003) Complexation of tricarbonyltechnetium(I)
Ion with halide and thiocyanate ions in aqueous solution: 99Tc NMR study. Radiochem
45(2):127–130
Grambow B, Grenthe I, Gaona X et al (2020) Discussion of new data selected for technetium. In:
Grenthe I, Gaona X, Plyasunov AV (eds) Second update of the chemical thermodynamics of
uranium, neptunium, plutonium, americium and technetium, OECD
Grassi J, Devynck J, Trémilton (1979) Electrochemical studies of technetium at a mercury electrode.
Anal Chim Acta 107:47–58
3 Technetium Coordinated by Inorganic Ligands in Aqueous …
Baldas J, Heath GA, Macgregor SA et al (1998) Spectroelectrochemical and computational studies
of tetrachloro and tetrabromo oxo- and nitrido-technetium(V) and their TcVI counterparts. J
Chem Soc Dalton Trans 2303–2314
Bancroft EE, Sidwell JS, Blount HN (1981) Derivative linear sweep and derivative cyclic
voltabsorptometry. Anal Chem 53:1390–1394
Boyd GE (1978) Osmotic and activity coefficients of aqueous HTcO 4 and HReO 4 solutions at 25
°C. Inor Chem 17(7):1808–1810
Chatterjee S, Hall GB, Johnsonet IE et al (2018) Surprising formation of quasi-stable Tc(VI) in
high ionic strength alkaline media. Inorg Chem Front 5:2081–2091
Chotkowski M, Czerwi´ nski A (2012) Electrochemical and spectroelectrochemical studies of
pertechnetate electroreduction in acidic media. Electrochim Acta 76:165–173
Chotkowski M, Czerwi´ nski A (2014a) Thin layer spectroelectrochemical (RVC-OTTLE) studies
of pertechnetate reduction in acidic media. J Radioanal Nucl Chem 300:229–234
Chotkowski M, Czerwi´ nski A (2014b) Thin layer spectroelectrochemical studies of pertechnetate
reduction on the gold electrodes in acidic media. Electrochim Acta 121:44–48
Chotkowski M, Wrzosek B, Grde´ n M (2018a) Intermediate oxidation states of technetium in
concentrated sulfuric acid solutions. J Electroanal Chem 814:83–90
Chotkowski M, Grde´ n M, Wrzosek B (2018b) Intermediate oxidation states of technetium in alkaline
solutions. J Electroanal Chem 829:148–156
Clarke MJ, Fackler PH (1982) The chemistry of technetium toward improved diagnostic agents in:
structure and bonding, vol 50. Topics in Inorganic and Physical Chemistry. Springer, p. 62
Cobble JW, Smith WT, Boyd GE (1953) Thermodynamic properties of technetium and rhenium
compounds. II. Heats of formation of technetium heptoxide and pertechnic acid, potential of the
technetium(IV)-technetium(VII) couple, and a potential diagram for technetium. J Am Chem Soc
75:5777–5782
Colton R, Dalziel J, Griffith WP et al. (1960) Polarographic study of manganese, technetium, and
rhenium. J Chem Soc 71–79
Compton RG, Banks CE (2011) Understanding voltammetry, 2nd edn, Ch. 7. Imperial College Press
Cotton FA, Pedersen E (1975) Magnetic and electrochemical properties of transition metal
complexes with multiple metal-to-metal bonds. I. [Tc 2 Cl 8 ] n− and [Re 2 Cl 8 ] n− with n = 2 and 3.
Inorg Chem 14(2):388–391
Courson O, Le Naour C, David F et al. (1999) Electrochemical behawior of technetium in acetic
buffer. Czechoslov J Phys 49(Suppl S1): 687–694
Deutsch E, Heinemann W, Hurst R et al (1978) Production, detection, and characterization of
transient hexavalent technetium in aqueous alkaline media by pulse radiolysis and very fast scan
cyclic voltammetry. JCS Chem Comm 1038–1040
Duluard S, Ouvrard B, Celik-Cochet A et al (2010) Comparision of PEDOT films obtained via three
different routhes through spectroelectrochemistry and the differential cyclic voltabsorptometry
method (DCVA). J Phys Chem B 114:7445–7451
Founta A, Aikens DA, Clark HM (1987) Mechanism and kinetics of the stepwise voltammetric
reduction of pertechnetates in alkali solutions to Tc(VI), Tc(V) and Tc(IV). J Electroanal Chem
219:221–246
Galus Z (1976) Fundamentals of electrochemical analysis, Chapter 3. Horwood – PWN Warszawa
German K, Kryutchkov SV (2002) Polynuclear technetium halide clusters. Russ J Inorg Chem
47(4):578–583
Gorshkov NI, Miroslavov AE, Lumpov AA et al (2003) Complexation of tricarbonyltechnetium(I)
Ion with halide and thiocyanate ions in aqueous solution: 99Tc NMR study. Radiochem
45(2):127–130
Grambow B, Grenthe I, Gaona X et al (2020) Discussion of new data selected for technetium. In:
Grenthe I, Gaona X, Plyasunov AV (eds) Second update of the chemical thermodynamics of
uranium, neptunium, plutonium, americium and technetium, OECD
Grassi J, Devynck J, Trémilton (1979) Electrochemical studies of technetium at a mercury electrode.
Anal Chim Acta 107:47–58