140
5 Metallic Technetium, Corrosion, Technetium Alloys …
Ozawa M, Shinoda Y, Sano Y (2002) The separationof fission products rare elements toward bridging
the nuclear and soft energy systems. Prog Nucl Energy 40(3–4):527–538
Ozawa M, Ishida M, Sano Y (2003) Strategic separation of technetium and rare metal fissionproducts in spent nuclear fuel e solvent extraction behavior and partitioning by catalytic
electrolytic extraction. Radiochem (Radiokhim) 45(3):225–232
Ozawa M, Suzuki T, Koyama S et al (2005) Separation of rare metal fission products in radiactive
wastes in new direction of their utilization. Prog Nucl Energy 47(1–4):462–471
Ozawa M, Suzuki T, Koyama S (2008) new back-end cycle strategy for enhancing separation,
transmutation and utilization of materials (Adv.-ORIENT cycle). Prog Nucl Energy 50:476–482
Peretrukhin VF, Silin VI, Kareta AV et al (1998) Purification of alkaline solutions and wastes from
actinides and technetium by coprecipitation with some carriers using the method of appearing
reagents: Final Report Final report of Institute of Physical Chemistry of Russian Academy of
Sciences Contract with DOE, PNNL 1998
Perterukhin VF, Moisy F, Maslennikov AG (2008) Physicochemical behavior of uranium and
technetium in some new stages of the nuclear fuel cycle. Russ J Gen Chem 78(5):1031–1046
Pikaev AK, Gogolev AV, Kryutchkov SV et al (1996) Radiolysis of Actinides and Technetium in
Alkaline Media. WHC-EP-0901, Westinghouse Hanford Corporation
Poineau F, Weck PF, Burton-Pye BP et al (2013) Reactivity of HTcO 4 with methanol in sulfuric acid:
Tc-sulfate complexes revealed by XAFS spectroscopy and first principles calculations. Dalton
Trans 42:4348–4352
Poineau F, Gray K, Ebert W (2014) Electrochemical corrosion studies for modeling metallic waste
form release rates. Project No. 12–4026. Final report. Nuclear Energy University Program USA
Poineau F, Koury DJ, Bertoia J et al (2016) Electrochemical studies of technetium-ruthenium alloys
in HNO3: implications for the behavior of technetium waste forms 1 . Radiochemistry 59(1):41–47
Rard JA, Rand MH, Anderegg G et al (1999) Chemical thermodynamics of technetium, vol 3.
Elsevier
Rotmanov KV, Maslennikov AG, Zakharova LV, Goncharenko YuD, Pertetrukhin VF (2015) Anodic
dissolution oof Tc metal in HNO 3 solutions. Radiochemistry 57(1):26–30
Rudenko A, Isakov A, Apisarov A et al (2019) Liquidus temperature and electrical conductivity of
molten eutectic CsCl–NaCl–KCl containing ReCl 4 . J Chem Eng Data 64:567–573
Salakhova E (2014) The electrochemical deposition of rhenium chalcogenides from different
electrolytes. J Chem Eng Chem Res 1(3):185–198
Sekine T, Narushima H, Suzuki et al (2004) Technetium(IV) oxide colloids produced by radiolytic
reactions in aqueous pertechnetate solution. Colloids Surf. A Physicochem Eng Asp 249:105–109
Skriver HL, Rosengaard NM (1992) Surface energy and work function of elemental metals. Phys
Rev 46(11):7157–7168
Sympson RF, Cartledge GH (1956) The mechanism of the inhibition of corrosion by the
pertechnetate ion. IV. Comparison with other XO
n−
4 inhibitors. J Phys Chem 60(8):1037–1043
Szabó S, Bakos I (2000) Electroreduction of rhenium from sulfuric acid solutions of perrhenic acid.
J Electroanal Chem 492(2):103–111
Taylor CD (2011) Surface segregation and adsorption effects of iron–technetium alloys from firstprinciples. J Nucl Mater 408:183–187
Trasatti S (1972a) Discussion of the electrochemical behavior of technetium and iron containing
technetium. Cartledge GH (pp 1752–1758, vol 118, no 11)] Discussion Section. J Electrochem
Soc 119(12):1696–1697
Trasatti S (1972b) Work function, electronegativity, and electrochemical behavior of metals. III
Electrolytic hydrogen evolution in acid soultions. J Electroanal Chem Interfacial Electrochem
39:163–184
Trasatti S, Petri OA (1991) Real surface area measurements in electrochemistry. Pure Appl Chem
63(5):711–734
Volkovich VA, Vasin BD, Griffiths TR (2010) Electrochemical and spectroscopic properties of
technetium in fused alkali metal chlorides. ECS Trans 33(7):381–390
5 Metallic Technetium, Corrosion, Technetium Alloys …
Ozawa M, Shinoda Y, Sano Y (2002) The separationof fission products rare elements toward bridging
the nuclear and soft energy systems. Prog Nucl Energy 40(3–4):527–538
Ozawa M, Ishida M, Sano Y (2003) Strategic separation of technetium and rare metal fissionproducts in spent nuclear fuel e solvent extraction behavior and partitioning by catalytic
electrolytic extraction. Radiochem (Radiokhim) 45(3):225–232
Ozawa M, Suzuki T, Koyama S et al (2005) Separation of rare metal fission products in radiactive
wastes in new direction of their utilization. Prog Nucl Energy 47(1–4):462–471
Ozawa M, Suzuki T, Koyama S (2008) new back-end cycle strategy for enhancing separation,
transmutation and utilization of materials (Adv.-ORIENT cycle). Prog Nucl Energy 50:476–482
Peretrukhin VF, Silin VI, Kareta AV et al (1998) Purification of alkaline solutions and wastes from
actinides and technetium by coprecipitation with some carriers using the method of appearing
reagents: Final Report Final report of Institute of Physical Chemistry of Russian Academy of
Sciences Contract with DOE, PNNL 1998
Perterukhin VF, Moisy F, Maslennikov AG (2008) Physicochemical behavior of uranium and
technetium in some new stages of the nuclear fuel cycle. Russ J Gen Chem 78(5):1031–1046
Pikaev AK, Gogolev AV, Kryutchkov SV et al (1996) Radiolysis of Actinides and Technetium in
Alkaline Media. WHC-EP-0901, Westinghouse Hanford Corporation
Poineau F, Weck PF, Burton-Pye BP et al (2013) Reactivity of HTcO 4 with methanol in sulfuric acid:
Tc-sulfate complexes revealed by XAFS spectroscopy and first principles calculations. Dalton
Trans 42:4348–4352
Poineau F, Gray K, Ebert W (2014) Electrochemical corrosion studies for modeling metallic waste
form release rates. Project No. 12–4026. Final report. Nuclear Energy University Program USA
Poineau F, Koury DJ, Bertoia J et al (2016) Electrochemical studies of technetium-ruthenium alloys
in HNO3: implications for the behavior of technetium waste forms 1 . Radiochemistry 59(1):41–47
Rard JA, Rand MH, Anderegg G et al (1999) Chemical thermodynamics of technetium, vol 3.
Elsevier
Rotmanov KV, Maslennikov AG, Zakharova LV, Goncharenko YuD, Pertetrukhin VF (2015) Anodic
dissolution oof Tc metal in HNO 3 solutions. Radiochemistry 57(1):26–30
Rudenko A, Isakov A, Apisarov A et al (2019) Liquidus temperature and electrical conductivity of
molten eutectic CsCl–NaCl–KCl containing ReCl 4 . J Chem Eng Data 64:567–573
Salakhova E (2014) The electrochemical deposition of rhenium chalcogenides from different
electrolytes. J Chem Eng Chem Res 1(3):185–198
Sekine T, Narushima H, Suzuki et al (2004) Technetium(IV) oxide colloids produced by radiolytic
reactions in aqueous pertechnetate solution. Colloids Surf. A Physicochem Eng Asp 249:105–109
Skriver HL, Rosengaard NM (1992) Surface energy and work function of elemental metals. Phys
Rev 46(11):7157–7168
Sympson RF, Cartledge GH (1956) The mechanism of the inhibition of corrosion by the
pertechnetate ion. IV. Comparison with other XO
n−
4 inhibitors. J Phys Chem 60(8):1037–1043
Szabó S, Bakos I (2000) Electroreduction of rhenium from sulfuric acid solutions of perrhenic acid.
J Electroanal Chem 492(2):103–111
Taylor CD (2011) Surface segregation and adsorption effects of iron–technetium alloys from firstprinciples. J Nucl Mater 408:183–187
Trasatti S (1972a) Discussion of the electrochemical behavior of technetium and iron containing
technetium. Cartledge GH (pp 1752–1758, vol 118, no 11)] Discussion Section. J Electrochem
Soc 119(12):1696–1697
Trasatti S (1972b) Work function, electronegativity, and electrochemical behavior of metals. III
Electrolytic hydrogen evolution in acid soultions. J Electroanal Chem Interfacial Electrochem
39:163–184
Trasatti S, Petri OA (1991) Real surface area measurements in electrochemistry. Pure Appl Chem
63(5):711–734
Volkovich VA, Vasin BD, Griffiths TR (2010) Electrochemical and spectroscopic properties of
technetium in fused alkali metal chlorides. ECS Trans 33(7):381–390