106
4 Technetium Coordinated by Organic Ligands …
Lever ABP (1991) Electrochemical parametrization of rhenium redox couples. Inorg Chem
30:1980–1985
Libson K, Barnett BL, Deutsch E (1983) Synthesis, characterization, and electrochemical properties
of tertiary diphosphine complexes of technetium: single-crystal structure of the prototype complex
trans-[Tc(DPPE) 2 Br 2 ]BF 4 . Inorg Chem 22(12):1695–1704
Linder KE, Davison A, Dewan JC et al (1986) Nitrosyl complexes of technetium: synthesis and characterization of [Tc I (NO)(CNCMe 3 ) 5 ](PF 6 ) 2 and Tc(NO)Br 2 (CNCMe 3 ) 3 and the crystal structure
of Tc(NO)Br 2 (CNCMe 3 ) 3 . Inorg Chem 25:2085–2089
Linder KE, Dewan JC, Davison A (1989) Technetium bis(μ-oxo) dimers of 1,4,7-triazacvclononaneN, N’, N”-triacetate (TCTA). Synthesis and characterization of [(TCTA)Tc(μ-O) 2 Tc(TCTA)] n- (n
= 2, 3) and the crystal structure of Ba 2 [(TCTA)Tc(μ-O) 2 Tc(TCTA)](ClO 4 )·9H 2 O. Inorg Chem
28:3820–3825
Linder KE, Chan YW, Cyr JE et al (1994) TcO(PnAO-1-(2-nitroimidazole)) [BMS-181321], a new
technetium-containing nitroimidazole complex for imaging hypoxia: synthesis, characterization,
and xanthine oxidase-catalyzed reduction. J Med Chem 37:9–17
Lu J, Yamano A, Clarke MJ (1990) Synthesis and characterization of technetium(III) complexes with
nitrogen heterocycles by O atom transfer from oxotechnetium(V) cores. Crystal structures of mer[Cl 3 (pic) 3 Tc] and mer-[Cl 3 (pic)(PMe 2 Ph) 2 Tc] (pic = 4-Picoline). electrochemical parameters
for the reduction of TcII, TcIII, and TcIV. Inorg Chem 29:3483–3487
Lu J, Hiller CD, Clarke MJ (1993) Synthesis and electrochemistry of (g-Oxo)technetium complexes
with bipyridine and halide ligands. Crystal structures of (μ-O)[X(bpy) 2 Tc] 2 X 2 -bpy (X = Cl, Br)
and (μ-O)[Cl(phen) 2 Tc] 2 Cl 2 . Inorg Chem 32:1417–1423
Luo H (1995) Chelate complexes of rhenium and technetium: toward their potential applications as
radiopharmaceutical. PhD dissertation, The University of British Columbia. Vancouver
Mazzi U, Clemente DA, Bandoli G (1977) Technetium-phosphonite complexes. Synthesis of
hexacoordinate technetium(II) and technetium(III) complexes of diethyl phenylphosphonite and
the crystal structure of dichlorotetrakis(diethyl phenylphosphonite)technetium(II). Inorg Chem
16(5):1042–1048
Mazzi U, Roncari E, Seeber R et al (1980) Voltammetric behaviour of technetium99 complexes with
π-acceptor ligands in aprotic medium. III. Oxidation of technetium(I) complexes with phosphine
and carbon monoxide ligands. Inorg Chim Acta 41:95–98
Mévellec F, Tisato F, Refosco F et al (2002) Synthesis and characterization of the “sulfur-rich”
bis(perthiobenzoato)(dithiobenzoato)technetium(III) heterocomplex. Inorg Chem 41:598–601
Mullen GED, Blower PJ, Price DJ (2000) Trithiacyclononane as a ligand for potential technetium
and rhenium radiopharmaceuticals: synthesis of [M(9S3)(SC 2 H 4 SC 2 H 4 S)][BF 4 ] (M) 99 Tc, Re,
188 Re) via C-S bond cleavage. Inorg Chem 39:4093–4098
Nicholson T, Mahmood A, Morgan G et al (1991) The synthesis and characterization of
[M(C 8 H 5 N 2 N=NH) 3 ](BPh 4 ), where M = Tc or Re. Tris-diazene chelate complexes of technetium(I) and rhenium(I). Inorg Chim Acta 179(1):53–57
Okamoto K-I, Chen B, Kirchhoff JR et al (1993a) Preparation, characterization and electrochemical properties of technetium(II) complexes with 1,2-bis(diethylphosphino)ethane (depe) and
dithiocarbamate ligands. Single-crystal structural analysis of [Tc((CH 3 ) 2 NCS 2 )(DEPE 2 )](PF 6 ).
Polyhedron 12(12):1559–1568
Okamoto K-I, Kirchhoff JR Heineman WR et al (1993b) Preparation, characterization, electrochemical properties and single-crystal structural analysis of [Tc(SCP) 2 (DMPE) 2 ](PF 6 ) 3 ,
where SCP is the Zwitter-ionic ligand − SCH 2 P + (CH 3 ) 2 (CH 2 ) 2 P(S)(CH 3 ) 2 and DMPE is
1,2-bis(dimethylphosphino)ethane. Polyhedron 12(7):749–757
Pasqualini R, Duatti A (1992) Synthesis and characterization of the new neutral myocardial imaging
agent [ 99m TcN(noet) 2 ](noet = N-Ethyl-N-ethoxydithiocarbamato). J Chem Soc Chem Commun
1354–1355
Patterson GS, Davison A, Jones AG et al (1986) Synthesis and characterization of tris(βdiketonato)technetium(III) and -(IV) complexes. Inorg Chim Acta 114:141–144
4 Technetium Coordinated by Organic Ligands …
Lever ABP (1991) Electrochemical parametrization of rhenium redox couples. Inorg Chem
30:1980–1985
Libson K, Barnett BL, Deutsch E (1983) Synthesis, characterization, and electrochemical properties
of tertiary diphosphine complexes of technetium: single-crystal structure of the prototype complex
trans-[Tc(DPPE) 2 Br 2 ]BF 4 . Inorg Chem 22(12):1695–1704
Linder KE, Davison A, Dewan JC et al (1986) Nitrosyl complexes of technetium: synthesis and characterization of [Tc I (NO)(CNCMe 3 ) 5 ](PF 6 ) 2 and Tc(NO)Br 2 (CNCMe 3 ) 3 and the crystal structure
of Tc(NO)Br 2 (CNCMe 3 ) 3 . Inorg Chem 25:2085–2089
Linder KE, Dewan JC, Davison A (1989) Technetium bis(μ-oxo) dimers of 1,4,7-triazacvclononaneN, N’, N”-triacetate (TCTA). Synthesis and characterization of [(TCTA)Tc(μ-O) 2 Tc(TCTA)] n- (n
= 2, 3) and the crystal structure of Ba 2 [(TCTA)Tc(μ-O) 2 Tc(TCTA)](ClO 4 )·9H 2 O. Inorg Chem
28:3820–3825
Linder KE, Chan YW, Cyr JE et al (1994) TcO(PnAO-1-(2-nitroimidazole)) [BMS-181321], a new
technetium-containing nitroimidazole complex for imaging hypoxia: synthesis, characterization,
and xanthine oxidase-catalyzed reduction. J Med Chem 37:9–17
Lu J, Yamano A, Clarke MJ (1990) Synthesis and characterization of technetium(III) complexes with
nitrogen heterocycles by O atom transfer from oxotechnetium(V) cores. Crystal structures of mer[Cl 3 (pic) 3 Tc] and mer-[Cl 3 (pic)(PMe 2 Ph) 2 Tc] (pic = 4-Picoline). electrochemical parameters
for the reduction of TcII, TcIII, and TcIV. Inorg Chem 29:3483–3487
Lu J, Hiller CD, Clarke MJ (1993) Synthesis and electrochemistry of (g-Oxo)technetium complexes
with bipyridine and halide ligands. Crystal structures of (μ-O)[X(bpy) 2 Tc] 2 X 2 -bpy (X = Cl, Br)
and (μ-O)[Cl(phen) 2 Tc] 2 Cl 2 . Inorg Chem 32:1417–1423
Luo H (1995) Chelate complexes of rhenium and technetium: toward their potential applications as
radiopharmaceutical. PhD dissertation, The University of British Columbia. Vancouver
Mazzi U, Clemente DA, Bandoli G (1977) Technetium-phosphonite complexes. Synthesis of
hexacoordinate technetium(II) and technetium(III) complexes of diethyl phenylphosphonite and
the crystal structure of dichlorotetrakis(diethyl phenylphosphonite)technetium(II). Inorg Chem
16(5):1042–1048
Mazzi U, Roncari E, Seeber R et al (1980) Voltammetric behaviour of technetium99 complexes with
π-acceptor ligands in aprotic medium. III. Oxidation of technetium(I) complexes with phosphine
and carbon monoxide ligands. Inorg Chim Acta 41:95–98
Mévellec F, Tisato F, Refosco F et al (2002) Synthesis and characterization of the “sulfur-rich”
bis(perthiobenzoato)(dithiobenzoato)technetium(III) heterocomplex. Inorg Chem 41:598–601
Mullen GED, Blower PJ, Price DJ (2000) Trithiacyclononane as a ligand for potential technetium
and rhenium radiopharmaceuticals: synthesis of [M(9S3)(SC 2 H 4 SC 2 H 4 S)][BF 4 ] (M) 99 Tc, Re,
188 Re) via C-S bond cleavage. Inorg Chem 39:4093–4098
Nicholson T, Mahmood A, Morgan G et al (1991) The synthesis and characterization of
[M(C 8 H 5 N 2 N=NH) 3 ](BPh 4 ), where M = Tc or Re. Tris-diazene chelate complexes of technetium(I) and rhenium(I). Inorg Chim Acta 179(1):53–57
Okamoto K-I, Chen B, Kirchhoff JR et al (1993a) Preparation, characterization and electrochemical properties of technetium(II) complexes with 1,2-bis(diethylphosphino)ethane (depe) and
dithiocarbamate ligands. Single-crystal structural analysis of [Tc((CH 3 ) 2 NCS 2 )(DEPE 2 )](PF 6 ).
Polyhedron 12(12):1559–1568
Okamoto K-I, Kirchhoff JR Heineman WR et al (1993b) Preparation, characterization, electrochemical properties and single-crystal structural analysis of [Tc(SCP) 2 (DMPE) 2 ](PF 6 ) 3 ,
where SCP is the Zwitter-ionic ligand − SCH 2 P + (CH 3 ) 2 (CH 2 ) 2 P(S)(CH 3 ) 2 and DMPE is
1,2-bis(dimethylphosphino)ethane. Polyhedron 12(7):749–757
Pasqualini R, Duatti A (1992) Synthesis and characterization of the new neutral myocardial imaging
agent [ 99m TcN(noet) 2 ](noet = N-Ethyl-N-ethoxydithiocarbamato). J Chem Soc Chem Commun
1354–1355
Patterson GS, Davison A, Jones AG et al (1986) Synthesis and characterization of tris(βdiketonato)technetium(III) and -(IV) complexes. Inorg Chim Acta 114:141–144