Gibbs energy profile
Proposed reaction mechanism
Fig. 1 DFT computed (B3LYP-D3/BS2 in CH 2 Cl 2 ) Gibbs energy profile and proposed mechanism
for the asymmetric hydrogenation of N-methyl imines to amines [3]. The numbers are relative
Gibbs energies in kcal mol
À1
4
O. Eisenstein et al.
Proposed reaction mechanism
Fig. 1 DFT computed (B3LYP-D3/BS2 in CH 2 Cl 2 ) Gibbs energy profile and proposed mechanism
for the asymmetric hydrogenation of N-methyl imines to amines [3]. The numbers are relative
Gibbs energies in kcal mol
À1
4
O. Eisenstein et al.