20
1 Overview of Direct Methane Conversion to Chemicals …
61. Soulivong D, Copéret C, Thivolle-Cazat J, Basset JM (2004) Cross-metathesis of propane and
methane: a catalytic reaction of C-C bond cleavage of a higher alkane by methane. Angew
Chem Int Ed 43:5366–5369
62. Lunsford JH, Qiu P, Rosynek MP, Yu Z (1998) Catalytic conversion methane and ethylene to
propylene. J Phys Chem B 102:167–173
63. Adebajo MO (2007) Green chemistry perspectives of methane conversion via oxidative
methylation of aromatics. Green Chem 9:526–539
64. Kim H, Suh HM, Paik H (1992) Oxidative methylation of toluene with methane over leadlithum-magnesium oxide catalysts. Appl Catal A General 87:115–127
65. Stoukides M (1995) Electrochemical studies of methane activation. J Appl Electrochem
25:899–912
66. Spinner N, Mustain WE (2013) Electrochemical methane activation and conversion to
oxygenates at room temperature. ECS Trans 53:1–20
67. Arnason L, Schmidt PS, Pandey M, Bagger A, Thygesen KS, Steprens IEL, Rossmeisl J (2018)
Fundamental limitation of electrocatalytic methane conversion to methanol. Phys Chem Chem
Phys 20:11152–11159
68. Minea T, vanden Bekerom DCM, Peeters FJJ, Zoethout E, Graswinckel MF, van de Sanden
MCM, Cents T, Lefferts, van Rooij LGJ (2018) Non-oxidative methane coupling to C 2
hydrocarbons in a microwave plasma reactor. Plasma Process Polym 15:e1800087 (1–16)
69. Yang Y (2002) Methane conversion and reforming by nonthermal plasma on pins. Ind Eng
Chem Res 41:5198–5926
70. Ogo S, Sekine Y (2017) Catalytic reaction assisted by plasma or electronic field. Chem Rec
17:726–738
71. Ogo S, Nakatsubo H, Iwasaki K, Sato A, Murakami K, Yabe T, Ishikawa A, Nakai H, Seine Y
(2018) Electron-hopping brings lattice strain and high catalytic activity in the low-temperature
oxidative coupling of methane in an electric filed. J Phys Chem C 122:2089–2096
72. Delikonsntis E, Scapinello M, Stefanidis GD (2018) Low energy cost conversion of methane
to ethylene in a hybrid plasma-catalytic reactor system. Fuel Process Technol 176:33–42
73. Park S, Lee M, Bae J, Hong DY, Park YH, Hwang YK, Jeong MG, Kim YD (2017) Plasmaassisted no-oxidative conversion of methane over Mo/H-ZSM-5 catalyst in DBP reactor. Top
Catal 60:735–742
74. Baltrusaitis J, Jansen I, Christus JDS (2014) Renewable energy based catalytic CH 4 conversion
to fuels. Catal Sci Technol 4:2397–2411
75. Shimura S, Yoshida H (2014) Semiconductor photocatalysts for non-oxidative coupling, dry
reforming, and steam reforming of methane. Catal Surv Asia 18:24–33
76. Handa H, Baba T, Ono Y (1998) H-D exchange between methane and deuteriated potassium
amide supported on alumina. J Chem Soc, Faraday Trans 94:451–454
77. Eller K, Schwarz H (1991) Organometallic chemistry in the gas phase. Chem Rev 91:1121–1177
78. Schwarz H, Shaik S, Li J (2017) Electronic effect on room-temperatures, Gas-phase C-H
bond activation by cluster oxides and metal carbide: the methane challenges. J Am Chem Soc
139:17201–17212
79. Labinger JA, Bercaw JE (2002) Understanding and exploiting C-H bond activation. Nature
417:507–514
80. Armold PL, Mcnullon MW, Rieb Kühn JFE (2015) C-H bond activation by f-block complexes.
Angew Chem Int Ed 54:82–100
81. Cavaliere VN, Wicker BF, Mindiola DJ (2012) Homogeneous organometallic chemistry of
methane. Adv Organomet Chem 60:1–47
82. Schwarz H, Schröder D (2000) Concepts of metal-mediated methane functionalization. An
interaction of experiment and theory. Pure Appl Chem 72:2319–2332
83. Cummins CC, Baxter SM, Wolczanski PT (1988) Methane and benzene activation via transient
( t BuSiNH) 2 Zr = NSi t Bu 3 . J Am Chem Soc 110:8731–8733
84. Sherry AE, Wayland BB (1990) Metalloradical activation of methane. J Am Chem Soc
112:1259–1261
1 Overview of Direct Methane Conversion to Chemicals …
61. Soulivong D, Copéret C, Thivolle-Cazat J, Basset JM (2004) Cross-metathesis of propane and
methane: a catalytic reaction of C-C bond cleavage of a higher alkane by methane. Angew
Chem Int Ed 43:5366–5369
62. Lunsford JH, Qiu P, Rosynek MP, Yu Z (1998) Catalytic conversion methane and ethylene to
propylene. J Phys Chem B 102:167–173
63. Adebajo MO (2007) Green chemistry perspectives of methane conversion via oxidative
methylation of aromatics. Green Chem 9:526–539
64. Kim H, Suh HM, Paik H (1992) Oxidative methylation of toluene with methane over leadlithum-magnesium oxide catalysts. Appl Catal A General 87:115–127
65. Stoukides M (1995) Electrochemical studies of methane activation. J Appl Electrochem
25:899–912
66. Spinner N, Mustain WE (2013) Electrochemical methane activation and conversion to
oxygenates at room temperature. ECS Trans 53:1–20
67. Arnason L, Schmidt PS, Pandey M, Bagger A, Thygesen KS, Steprens IEL, Rossmeisl J (2018)
Fundamental limitation of electrocatalytic methane conversion to methanol. Phys Chem Chem
Phys 20:11152–11159
68. Minea T, vanden Bekerom DCM, Peeters FJJ, Zoethout E, Graswinckel MF, van de Sanden
MCM, Cents T, Lefferts, van Rooij LGJ (2018) Non-oxidative methane coupling to C 2
hydrocarbons in a microwave plasma reactor. Plasma Process Polym 15:e1800087 (1–16)
69. Yang Y (2002) Methane conversion and reforming by nonthermal plasma on pins. Ind Eng
Chem Res 41:5198–5926
70. Ogo S, Sekine Y (2017) Catalytic reaction assisted by plasma or electronic field. Chem Rec
17:726–738
71. Ogo S, Nakatsubo H, Iwasaki K, Sato A, Murakami K, Yabe T, Ishikawa A, Nakai H, Seine Y
(2018) Electron-hopping brings lattice strain and high catalytic activity in the low-temperature
oxidative coupling of methane in an electric filed. J Phys Chem C 122:2089–2096
72. Delikonsntis E, Scapinello M, Stefanidis GD (2018) Low energy cost conversion of methane
to ethylene in a hybrid plasma-catalytic reactor system. Fuel Process Technol 176:33–42
73. Park S, Lee M, Bae J, Hong DY, Park YH, Hwang YK, Jeong MG, Kim YD (2017) Plasmaassisted no-oxidative conversion of methane over Mo/H-ZSM-5 catalyst in DBP reactor. Top
Catal 60:735–742
74. Baltrusaitis J, Jansen I, Christus JDS (2014) Renewable energy based catalytic CH 4 conversion
to fuels. Catal Sci Technol 4:2397–2411
75. Shimura S, Yoshida H (2014) Semiconductor photocatalysts for non-oxidative coupling, dry
reforming, and steam reforming of methane. Catal Surv Asia 18:24–33
76. Handa H, Baba T, Ono Y (1998) H-D exchange between methane and deuteriated potassium
amide supported on alumina. J Chem Soc, Faraday Trans 94:451–454
77. Eller K, Schwarz H (1991) Organometallic chemistry in the gas phase. Chem Rev 91:1121–1177
78. Schwarz H, Shaik S, Li J (2017) Electronic effect on room-temperatures, Gas-phase C-H
bond activation by cluster oxides and metal carbide: the methane challenges. J Am Chem Soc
139:17201–17212
79. Labinger JA, Bercaw JE (2002) Understanding and exploiting C-H bond activation. Nature
417:507–514
80. Armold PL, Mcnullon MW, Rieb Kühn JFE (2015) C-H bond activation by f-block complexes.
Angew Chem Int Ed 54:82–100
81. Cavaliere VN, Wicker BF, Mindiola DJ (2012) Homogeneous organometallic chemistry of
methane. Adv Organomet Chem 60:1–47
82. Schwarz H, Schröder D (2000) Concepts of metal-mediated methane functionalization. An
interaction of experiment and theory. Pure Appl Chem 72:2319–2332
83. Cummins CC, Baxter SM, Wolczanski PT (1988) Methane and benzene activation via transient
( t BuSiNH) 2 Zr = NSi t Bu 3 . J Am Chem Soc 110:8731–8733
84. Sherry AE, Wayland BB (1990) Metalloradical activation of methane. J Am Chem Soc
112:1259–1261