18
1 Overview of Direct Methane Conversion to Chemicals …
20. Tang P, Zlau Q, Wu Z, Ma D (2014) Methane activation: the past and future. Energy Environ
Sci 7:2580–2591
21. Shtenman AA (2016) Coordinational activation of methane and other alkanes by metal
complexes. Russ Chem Bull Int Ed 65:1930–1944
22. Lotz MD, Remy MS, Lao DB, Ariafard A, Yates BF, Canty AJ, Mayer JM, Sanford MS
(2014) Formation of ethane from mono-methyl palladium (II) complexes. J Am Chem Soc
136:8237–8242
23. Citek C, Herres-Pawlis S, Daniel T, Stack P (2015) Low temperature synthesis and reactivity
of Cu 2 O 2 models. Acc Chem Res 48:2424–2433
24. Perianna RA, Bhalla G, Tenn WT III, Yong KJH, Kiu XY, Mironov O, Jones CJ, Ziatdinov
VR (2004) Perspective on some challenges and approaches for developing the next generation
of selective low temperature, oxidation catalysts for alkane hydroxylation based on the C-H
activation reaction. J Mol Catal A: Chem 220:7–25
25. Cavaliere VN, Mindiola DJ (2012) Methane: a new frontier in organometallic chemistry. Chem
Sci 3:3356–3365
26. Schwarz H (2014) How and why do cluster size, charge state and ligands affect the course of
metal mediated gas-phase activation of methane. Isr J Chem 54:1413–1431
27. Golisz SR, Gunnoe TB, Goddard WA III, Groves JT, Perianna RA (2011) Chemistry in the
center for catalytic hydrocarbon functionalization: an energy frontier research center. Catal
Lett 141:213–221
28. Olah GA, Surya Prakash GK, Sommer J (1985) Superacids. Wiley, Wiley Interscience
Publication
29. Olah GA, Surya Prakash GK, Sommer J (1979) Superacids. Science 206:13–20
30. Olah GA (1973) Carbocations and electrophilic reactions. Angew Chem Inter Ed 12:173–254
31. Jansiewski AJ, Que L (2018) Dioxygen activation by nonheme diiron enzymes: diverse dioxygen adducts, high-valent intermediate, and related model complexes. Chem Rev 118:2554–
2592
32. Zhang S, Karthikeyan R, Fernando SD (2017) Low-temperature biological activation of
methane: structure, function and molecular interactions of soluble and particulate methane
monooxygenases. Rev Environ Sci Biotechnol 16:611–623
33. Wang VCC, Maji S, Chen PPY, Lee HK, Yu SSF, Chan SI (2017) Alkane oxidation: methane
monooxygenases, related enzymes, and their biomimetics. Chem Rev 117:8574–8621
34. Wang W, Liang AD, Lippard SJ (2015) Coupling oxygen consumption with hydrocarbon
oxidation in bacterial multicomponent monooxygenases. Acc Chem Res 48:2632–2639
35. Haynes CA, Gonzalez R (2014) Rethinking biological activation of methane and conversion
to liquid fuels. Nat Chem Biol 10:331–339
36. Sirajuddin S, Rosenzweig AC (2015) Enzymatic oxidation of methane. Biochemistry 54:2283–
2294
37. Bjorck CE, Dobson PD, Pandhal J (2018) Biotechnological conversion of methane to methanol:
evaluation of progress and potential. AIMS Bioeng 5:1–38
38. Xu J, Zheng A, Wang X, Qi G, Su J, Du J, Gan Z, Wu J, Wang W, Deng F (2012) Room
temperature activation of methane over Zn modified H-ZSM-5 zeolites: insight from solid-state
NMR and theoretical calculations. Chem Soc 3:2932–2940
39. Bango A, Saielli G (2011) Relative DFT calculations of the NMR properties and reactivity of
transition metal σ-complexes insight on C-H bond activation. Phys Chem Chem Phys 13:4285–
4291
40. Gabrienko AA, Arzumanov SS, Morzo IB, Toktarev AV, Wang W, Stepanov AG (2013)
Methane activation and transformation on Ag/H-ZSM-5zeolite studied with solid-state NMR.
J Phys Chem C 117:7690–7702
1 Overview of Direct Methane Conversion to Chemicals …
20. Tang P, Zlau Q, Wu Z, Ma D (2014) Methane activation: the past and future. Energy Environ
Sci 7:2580–2591
21. Shtenman AA (2016) Coordinational activation of methane and other alkanes by metal
complexes. Russ Chem Bull Int Ed 65:1930–1944
22. Lotz MD, Remy MS, Lao DB, Ariafard A, Yates BF, Canty AJ, Mayer JM, Sanford MS
(2014) Formation of ethane from mono-methyl palladium (II) complexes. J Am Chem Soc
136:8237–8242
23. Citek C, Herres-Pawlis S, Daniel T, Stack P (2015) Low temperature synthesis and reactivity
of Cu 2 O 2 models. Acc Chem Res 48:2424–2433
24. Perianna RA, Bhalla G, Tenn WT III, Yong KJH, Kiu XY, Mironov O, Jones CJ, Ziatdinov
VR (2004) Perspective on some challenges and approaches for developing the next generation
of selective low temperature, oxidation catalysts for alkane hydroxylation based on the C-H
activation reaction. J Mol Catal A: Chem 220:7–25
25. Cavaliere VN, Mindiola DJ (2012) Methane: a new frontier in organometallic chemistry. Chem
Sci 3:3356–3365
26. Schwarz H (2014) How and why do cluster size, charge state and ligands affect the course of
metal mediated gas-phase activation of methane. Isr J Chem 54:1413–1431
27. Golisz SR, Gunnoe TB, Goddard WA III, Groves JT, Perianna RA (2011) Chemistry in the
center for catalytic hydrocarbon functionalization: an energy frontier research center. Catal
Lett 141:213–221
28. Olah GA, Surya Prakash GK, Sommer J (1985) Superacids. Wiley, Wiley Interscience
Publication
29. Olah GA, Surya Prakash GK, Sommer J (1979) Superacids. Science 206:13–20
30. Olah GA (1973) Carbocations and electrophilic reactions. Angew Chem Inter Ed 12:173–254
31. Jansiewski AJ, Que L (2018) Dioxygen activation by nonheme diiron enzymes: diverse dioxygen adducts, high-valent intermediate, and related model complexes. Chem Rev 118:2554–
2592
32. Zhang S, Karthikeyan R, Fernando SD (2017) Low-temperature biological activation of
methane: structure, function and molecular interactions of soluble and particulate methane
monooxygenases. Rev Environ Sci Biotechnol 16:611–623
33. Wang VCC, Maji S, Chen PPY, Lee HK, Yu SSF, Chan SI (2017) Alkane oxidation: methane
monooxygenases, related enzymes, and their biomimetics. Chem Rev 117:8574–8621
34. Wang W, Liang AD, Lippard SJ (2015) Coupling oxygen consumption with hydrocarbon
oxidation in bacterial multicomponent monooxygenases. Acc Chem Res 48:2632–2639
35. Haynes CA, Gonzalez R (2014) Rethinking biological activation of methane and conversion
to liquid fuels. Nat Chem Biol 10:331–339
36. Sirajuddin S, Rosenzweig AC (2015) Enzymatic oxidation of methane. Biochemistry 54:2283–
2294
37. Bjorck CE, Dobson PD, Pandhal J (2018) Biotechnological conversion of methane to methanol:
evaluation of progress and potential. AIMS Bioeng 5:1–38
38. Xu J, Zheng A, Wang X, Qi G, Su J, Du J, Gan Z, Wu J, Wang W, Deng F (2012) Room
temperature activation of methane over Zn modified H-ZSM-5 zeolites: insight from solid-state
NMR and theoretical calculations. Chem Soc 3:2932–2940
39. Bango A, Saielli G (2011) Relative DFT calculations of the NMR properties and reactivity of
transition metal σ-complexes insight on C-H bond activation. Phys Chem Chem Phys 13:4285–
4291
40. Gabrienko AA, Arzumanov SS, Morzo IB, Toktarev AV, Wang W, Stepanov AG (2013)
Methane activation and transformation on Ag/H-ZSM-5zeolite studied with solid-state NMR.
J Phys Chem C 117:7690–7702