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79. Ding B, Huang H, Wang W (2008) Methane activation over Ag-exchanged ZSM-5 zeolites:
a theoretical study. Appl Surf Sci 254:4944–4948
80. Oda A, Torigoe H, Itadani A, Ohkubo T, Yumura T, Kobayashi H, Kuroda Y (2013) Mechanism
of CH 4 activation on a monomeric Zn 2+ -ion exchanged in MFI-type zeolite with a specific
Al arrangement: similarity to the activation site for H 2 . J Phys Chem C 117:19525–19534
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“alkyl” and “carbenium” pathways of methane activation on Ga-modified zeolite BEA: 13 C
solid-state NMR and GC-MS study of methane aromatization in the presence of higher alkane.
J Phys Chem C 114:21555–21561
83. Luzgin MV, Rogov VA, Arzumanov SS, Toktarev AV, Stepanov AG, Parmon VN (2009)
Methane aromatization on Zn-modified zeolite in the presence of a co-reactant higher alkane:
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methane activation on Zn 2+ -modified ZSM-5 zeolite: H/D hydrogen exchange with Brønsted
acid sites versus dissociate adsorption to form Zn-methyl species. Catal Sci Technol 6:6381–
6388
85. Wang X, Xu J, Qi G, Li B, Wang C, Deng F (2013) Alkylation of benzene with methane over
ZnZSM-5 zeolites studied with solid-state NMR spectroscopy. J Phys Chem C 117:4018–4023
86. Xu J, Zheng A, Wang X, Qi G, Su J, Du J, Gan Z, Wu J, Wang W, Deng F (2012) Room
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NMR and theoretical calculations. Chem Sci 3:2932–2940
87. Liu BS, Zhang Y, Liu JF, Tian M, Zhang FM, Au CT, Cheung ASC (2011) Characterization
and mechanism of methane dehydroaromatization over Zn-based/H-ZSM-5 catalyst under
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16962
88. Gabrienko AA, Arzumanov SS, Toktarev AV, Danilova IG, Prosvirin IP, Kriventsov VV,
Zaikovskii VI, Fruede D, Stepanov AG (2017) Different efficiency of Zn 2+ and ZnO species
for methane activation on Zn-modified zeolite. ACS Catal 7:1818–1830
89. Gabrienko AA, Arzumanov SS, Moroz IB, Prosvirin IP, Toktarev AV, Wang W, Stepanov
AG (2014) Methane activation on In-modified ZSM-5: The state of indium in zeolite and
pathways of methane transformation to surface species. J Phys Chem C 118:8034–8043
90. Baba T, Abe Y, Nomoto K, Inazu K, Echizen T, Ishikawa A, Murai K (2005) Catalytic
transformation of methane over In-loaded ZSM-5 zeolite in the presence of ethylene. J Phys
Chem B 109:4263–4268
91. Messe M, Beier H, Zeeh B (1996) Spectroskopiche Methoden in der Organischen Chemie,
Georg Thieme Verlag 1996, Chapter 4
92. Ono Y, Kanae K (1991) Transformation of butanes over ZSM-5 zeolites. Part-1.—Mechanism
of cracking of butanes over H-ZSM-5. J Chem Soc Faraday Trans 87:663–667
93. Ono Y, Kanae K (1991) Transformation of butanes over ZSM-5 zeolites. Part-2—Formation of
aromatic hydrocarbons over Zn-ZSM-5 and Ga-ZSM-5. J Chem Soc Faraday Trans 87:669–
675
94. Shigeishi R, Harris GI, Dyer J (1991) The conversion of butane in HZSM-5. J Catal 130:423–
439
95. Krannila H, Haag WO, Gates BC (1992) Monomolecular and bimolecular mechanisms of
paraffin cracking: n-Butane cracking catalyzed by HZSM-5. J Catal 135:115–124
96. Narbeshuber TF, Vinek H, Lercher JA (1995) Monomolecular conversion of light alkanes
over H-ZSM-5. J Catal 157:388–395
219
78. Baba T, Iwase Y, Inazu K, Masih D, Matsumoto A (2007) Catalytic properties of silverexchanged zeolites for propene production by conversion of methane in the presence of
ethene. Microporous Mesoporous Mater 101:142–147
79. Ding B, Huang H, Wang W (2008) Methane activation over Ag-exchanged ZSM-5 zeolites:
a theoretical study. Appl Surf Sci 254:4944–4948
80. Oda A, Torigoe H, Itadani A, Ohkubo T, Yumura T, Kobayashi H, Kuroda Y (2013) Mechanism
of CH 4 activation on a monomeric Zn 2+ -ion exchanged in MFI-type zeolite with a specific
Al arrangement: similarity to the activation site for H 2 . J Phys Chem C 117:19525–19534
81. Luzgin MV, Rogov VA, Arzumanov SS, Toktarev AV, Stepanov AG, Parmon VN (2008)
Understanding methane aromaticzation on Zn-modified high-silica zeolite. Angew Chem Int
Ed 47:4559–4562
82. Luzgin MV, Gabrienko AA, Rogov VA, Toktarev AV, Parmon VN, Stepanov AG (2010) The
“alkyl” and “carbenium” pathways of methane activation on Ga-modified zeolite BEA: 13 C
solid-state NMR and GC-MS study of methane aromatization in the presence of higher alkane.
J Phys Chem C 114:21555–21561
83. Luzgin MV, Rogov VA, Arzumanov SS, Toktarev AV, Stepanov AG, Parmon VN (2009)
Methane aromatization on Zn-modified zeolite in the presence of a co-reactant higher alkane:
how does it occur? Catal Today 144:265–272
84. Arzumanov SS, Gabrienko AA, Freude D, Stepanov AG (2016) Competitive pathways of
methane activation on Zn 2+ -modified ZSM-5 zeolite: H/D hydrogen exchange with Brønsted
acid sites versus dissociate adsorption to form Zn-methyl species. Catal Sci Technol 6:6381–
6388
85. Wang X, Xu J, Qi G, Li B, Wang C, Deng F (2013) Alkylation of benzene with methane over
ZnZSM-5 zeolites studied with solid-state NMR spectroscopy. J Phys Chem C 117:4018–4023
86. Xu J, Zheng A, Wang X, Qi G, Su J, Du J, Gan Z, Wu J, Wang W, Deng F (2012) Room
temperature activation of methane over Zn modified H-ZSM-5 zeolite: insight from solid-state
NMR and theoretical calculations. Chem Sci 3:2932–2940
87. Liu BS, Zhang Y, Liu JF, Tian M, Zhang FM, Au CT, Cheung ASC (2011) Characterization
and mechanism of methane dehydroaromatization over Zn-based/H-ZSM-5 catalyst under
conditions of atmospheric pressure and supersonic jet expansion. J Phys Chem C 115:16954–
16962
88. Gabrienko AA, Arzumanov SS, Toktarev AV, Danilova IG, Prosvirin IP, Kriventsov VV,
Zaikovskii VI, Fruede D, Stepanov AG (2017) Different efficiency of Zn 2+ and ZnO species
for methane activation on Zn-modified zeolite. ACS Catal 7:1818–1830
89. Gabrienko AA, Arzumanov SS, Moroz IB, Prosvirin IP, Toktarev AV, Wang W, Stepanov
AG (2014) Methane activation on In-modified ZSM-5: The state of indium in zeolite and
pathways of methane transformation to surface species. J Phys Chem C 118:8034–8043
90. Baba T, Abe Y, Nomoto K, Inazu K, Echizen T, Ishikawa A, Murai K (2005) Catalytic
transformation of methane over In-loaded ZSM-5 zeolite in the presence of ethylene. J Phys
Chem B 109:4263–4268
91. Messe M, Beier H, Zeeh B (1996) Spectroskopiche Methoden in der Organischen Chemie,
Georg Thieme Verlag 1996, Chapter 4
92. Ono Y, Kanae K (1991) Transformation of butanes over ZSM-5 zeolites. Part-1.—Mechanism
of cracking of butanes over H-ZSM-5. J Chem Soc Faraday Trans 87:663–667
93. Ono Y, Kanae K (1991) Transformation of butanes over ZSM-5 zeolites. Part-2—Formation of
aromatic hydrocarbons over Zn-ZSM-5 and Ga-ZSM-5. J Chem Soc Faraday Trans 87:669–
675
94. Shigeishi R, Harris GI, Dyer J (1991) The conversion of butane in HZSM-5. J Catal 130:423–
439
95. Krannila H, Haag WO, Gates BC (1992) Monomolecular and bimolecular mechanisms of
paraffin cracking: n-Butane cracking catalyzed by HZSM-5. J Catal 135:115–124
96. Narbeshuber TF, Vinek H, Lercher JA (1995) Monomolecular conversion of light alkanes
over H-ZSM-5. J Catal 157:388–395