210
7 C–C Bond Formation via Carbocations in the Methane …
Table 7.11
Absolute rates (10 −2
mol h −1
g −1
) of dehydrogenation (hydride abstraction) of lower alkanes over Ag-ZSM-5 and Zn-ZSM-5 (Reprinted from
ref. [97], Copyright 2020, with permission from Elsevier)
>
C
CH
3
H
3 C
H
CH
3
>
C
H
3 C
CH
2 CH
3
H
CH
3
>
CH
3 CH
2 CH
2 CH
2 CH
3
CH3CH2CH2CH3 >
C
CH
3
CH
3
CH
3
H
3 C
Ag-ZSM-5
27
20
7.8
4.3
0
Zn-ZSM-5
36
19
8.9
5.8
0
7 C–C Bond Formation via Carbocations in the Methane …
Table 7.11
Absolute rates (10 −2
mol h −1
g −1
) of dehydrogenation (hydride abstraction) of lower alkanes over Ag-ZSM-5 and Zn-ZSM-5 (Reprinted from
ref. [97], Copyright 2020, with permission from Elsevier)
>
C
CH
3
H
3 C
H
CH
3
>
C
H
3 C
CH
2 CH
3
H
CH
3
>
CH
3 CH
2 CH
2 CH
2 CH
3
CH3CH2CH2CH3 >
C
CH
3
CH
3
CH
3
H
3 C
Ag-ZSM-5
27
20
7.8
4.3
0
Zn-ZSM-5
36
19
8.9
5.8
0