456
M. Sakamoto
49. Sakamoto, M., Utsumi, N., Ando, M., Saeki, M., Mino, T., Fujita, T., Katoh, A., Nishio,
T., Kashima, C.: Breaking the symmetry of axially chiral N-Aryl-2(1H)-pyrimidinones by
spontaneous crystallization. Angew. Chem. Int. Ed. 42, 4360–4363 (2003)
50. Sakamoto, M., Unosawa, A., Kobaru, S., Fujita, K., Mino, T., Fujita, T.: An asymmetric SNAr
reaction using the molecular chirality in a crystal. Chem. Commun. 34, 3586–3588 (2007)
51. Engwerda, A.H.J., van Schayik, P., Jagtenberg, H., Meekes, H., Rutjes, F.P.J.T., Vlieg, E.: Solid
phase deracemization of an atropisomer. Cryst. Growth Des. 17, 5583–5585 (2017)
52. Yagishita, F., Okamoto, K., Kamataki, N., Kanno, S., Mino, T., Kasashima, Y., Sakamoto,
M.: Chiral symmetry breaking of axially chiral nicotinamide by crystallization from the melt.
Chem. Lett. 42, 1508–1511 (2013)
53. Sakamoto, M., Unosawa, A., Kobaru, S., Saito, A., Kasashima, Y., Mino, T., Fujita, T.: Asymmetric photocycloaddition in solution of a chiral crystallized naphthamide. Angew. Chem. Int.
Ed. 44, 5523–5526 (2005)
54. Sakamoto, M., Kato, M., Aida, Y., Fujita, K., Mino, T., Fujita, T.: Photosensitized 2 + 2
cycloaddition reaction using homochirality generated by spontaneous crystallization. J. Am.
Chem. Soc. 130, 1132 (2008)
55. Yagishita, F., Mino, T., Fujita, T., Sakamoto, M.: Two-step asymmetric reaction using the frozen
chirality generated by spontaneous crystallization. Org. Lett. 14, 2638–2641 (2012)
56. Flock, A.M., Reucher, C.M.M., Bolm, C.: Enantioenrichment by iterative retro-aldol/aldol
reaction catalyzed by an achiral or racemic base. Chem. Eur. J. 16, 3918–3921 (2010)
57. Steendam, R.R.E., Verkade, J.M.M., van Benthem, T.J.B., Meekes, H., van Enckevort, W.J.P.,
Raap, J., Rutjes, F.P.J.T., Vlieg, E.: Emergence of single-molecular chirality from achiral
reactants. Nature Commun. 5, 5543–5550 (2014)
58. Kaji, Y., Uemura, N., Kasashima, Y., Ishikawa, H., Yoshida, Y., Mino, T., Sakamoto, M.:
asymmetric synthesis of an amino acid derivative from achiral aroyl acrylamide by reversible
michael addition and preferential crystallization. Chem. Eur. J. 22, 16429–16432 (2016)
59. Uemura, N., Sano, K., Matsumoto, A., Yoshida, Y., Mino, T., Sakamoto, M.: Asymmetric
synthesis of aspartic acid derivative from prochiral maleic acid and pyridine under achiral
conditions. Chem. Asian J. 14, 4150–4153 (2019)
60. Miyagawa, S., Yoshimura, K., Yamazaki, Y., Takamatsu, N., Kuraishi, T., Tetsuya, A., Tokunaga, S., Yuji, K., Kawasaki, T.: Asymmetric strecker reaction arising from the molecular
orientation of an achiral imine at the single-crystal face: enantioenriched l- and d-amino acids.
Angew. Chem. Int. Ed. 56, 1055–1058 (2017)
61. Kawasaki, T., Takamatsu, N., Aiba, S., Tokunaga, Y.: Spontaneous formation and amplification
of an enantioenriched α-amino nitrile: a chiral precursor for Strecker amino acid synthesis.
Chem. Commun. 51, 14377–14380 (2015)
62. Baglai, I., Leeman, M., Wurst, K., Kaptein, B., Kellogg, R.M., Noorduin, W.L.: The strecker
reaction coupled to Viedma ripening: a simple route to highly hindered enantiomerically pure
amino acids. Chem. Commun. 54, 10832–10834 (2018)
63. Ishikawa, H., Uemura, N., Yagishita, F., Baba, N., Yoshida, Y., Mino, T., Kasashima, Y.,
Sakamoto, M.: Asymmetric synthesis involving reversible photodimerization of a prochiral
flavonoid followed by crystallization. Eur. J. Org. Chem. 2017, 6878–6881 (2017)
64. Uemura, N., Toyoda, S., Ishikawa, H., Yoshida, Y., Mino, T., Kasashima, Y., Sakamoto, M.:
Asymmetric Diels–Alder reaction involving dynamic enantioselective crystallization. J. Org.
Chem. 83, 9300–9304 (2018)
M. Sakamoto
49. Sakamoto, M., Utsumi, N., Ando, M., Saeki, M., Mino, T., Fujita, T., Katoh, A., Nishio,
T., Kashima, C.: Breaking the symmetry of axially chiral N-Aryl-2(1H)-pyrimidinones by
spontaneous crystallization. Angew. Chem. Int. Ed. 42, 4360–4363 (2003)
50. Sakamoto, M., Unosawa, A., Kobaru, S., Fujita, K., Mino, T., Fujita, T.: An asymmetric SNAr
reaction using the molecular chirality in a crystal. Chem. Commun. 34, 3586–3588 (2007)
51. Engwerda, A.H.J., van Schayik, P., Jagtenberg, H., Meekes, H., Rutjes, F.P.J.T., Vlieg, E.: Solid
phase deracemization of an atropisomer. Cryst. Growth Des. 17, 5583–5585 (2017)
52. Yagishita, F., Okamoto, K., Kamataki, N., Kanno, S., Mino, T., Kasashima, Y., Sakamoto,
M.: Chiral symmetry breaking of axially chiral nicotinamide by crystallization from the melt.
Chem. Lett. 42, 1508–1511 (2013)
53. Sakamoto, M., Unosawa, A., Kobaru, S., Saito, A., Kasashima, Y., Mino, T., Fujita, T.: Asymmetric photocycloaddition in solution of a chiral crystallized naphthamide. Angew. Chem. Int.
Ed. 44, 5523–5526 (2005)
54. Sakamoto, M., Kato, M., Aida, Y., Fujita, K., Mino, T., Fujita, T.: Photosensitized 2 + 2
cycloaddition reaction using homochirality generated by spontaneous crystallization. J. Am.
Chem. Soc. 130, 1132 (2008)
55. Yagishita, F., Mino, T., Fujita, T., Sakamoto, M.: Two-step asymmetric reaction using the frozen
chirality generated by spontaneous crystallization. Org. Lett. 14, 2638–2641 (2012)
56. Flock, A.M., Reucher, C.M.M., Bolm, C.: Enantioenrichment by iterative retro-aldol/aldol
reaction catalyzed by an achiral or racemic base. Chem. Eur. J. 16, 3918–3921 (2010)
57. Steendam, R.R.E., Verkade, J.M.M., van Benthem, T.J.B., Meekes, H., van Enckevort, W.J.P.,
Raap, J., Rutjes, F.P.J.T., Vlieg, E.: Emergence of single-molecular chirality from achiral
reactants. Nature Commun. 5, 5543–5550 (2014)
58. Kaji, Y., Uemura, N., Kasashima, Y., Ishikawa, H., Yoshida, Y., Mino, T., Sakamoto, M.:
asymmetric synthesis of an amino acid derivative from achiral aroyl acrylamide by reversible
michael addition and preferential crystallization. Chem. Eur. J. 22, 16429–16432 (2016)
59. Uemura, N., Sano, K., Matsumoto, A., Yoshida, Y., Mino, T., Sakamoto, M.: Asymmetric
synthesis of aspartic acid derivative from prochiral maleic acid and pyridine under achiral
conditions. Chem. Asian J. 14, 4150–4153 (2019)
60. Miyagawa, S., Yoshimura, K., Yamazaki, Y., Takamatsu, N., Kuraishi, T., Tetsuya, A., Tokunaga, S., Yuji, K., Kawasaki, T.: Asymmetric strecker reaction arising from the molecular
orientation of an achiral imine at the single-crystal face: enantioenriched l- and d-amino acids.
Angew. Chem. Int. Ed. 56, 1055–1058 (2017)
61. Kawasaki, T., Takamatsu, N., Aiba, S., Tokunaga, Y.: Spontaneous formation and amplification
of an enantioenriched α-amino nitrile: a chiral precursor for Strecker amino acid synthesis.
Chem. Commun. 51, 14377–14380 (2015)
62. Baglai, I., Leeman, M., Wurst, K., Kaptein, B., Kellogg, R.M., Noorduin, W.L.: The strecker
reaction coupled to Viedma ripening: a simple route to highly hindered enantiomerically pure
amino acids. Chem. Commun. 54, 10832–10834 (2018)
63. Ishikawa, H., Uemura, N., Yagishita, F., Baba, N., Yoshida, Y., Mino, T., Kasashima, Y.,
Sakamoto, M.: Asymmetric synthesis involving reversible photodimerization of a prochiral
flavonoid followed by crystallization. Eur. J. Org. Chem. 2017, 6878–6881 (2017)
64. Uemura, N., Toyoda, S., Ishikawa, H., Yoshida, Y., Mino, T., Kasashima, Y., Sakamoto, M.:
Asymmetric Diels–Alder reaction involving dynamic enantioselective crystallization. J. Org.
Chem. 83, 9300–9304 (2018)