246
H. Ohtsu et al.
In this sense, the careful design of desired interactive sites is a key step toward
building materials that mimic biological functions, particularly the ability to catalyze
reactions under mild conditions. This task will be accomplished by the judicious
development of multifunctional ligands, the selection of appropriate metal connectors, and tuning the reaction parameters. However, there are still many challenges
that need to be addressed before the kinetically assembled coordination networks
could come close to reaching such a formidable goal.
References
1. Dichtel, W.R., Miljani´ c, O.Š., Zhang, W., Spruell, J.M., Patel, K., Aprahamian, I., Heath, J.R.,
Stoddart, J.F.: Kinetic and thermodynamic approaches for the efficient formation of mechanical
bonds. Acc. Chem. Res. 41, 1750–1761 (2008)
2. Dickson, A., Brooks III, C.L.: Native states of fast-folding proteins are kinetic traps. J. Am.
Chem. Soc. 135, 4729–4734 (2013)
3. Hua, Q.X., Gozani, S.N., Chance, R.E., Hoffmann, J.A., Frank, B.H., Weiss, M.A.: Structure
of a protein in a kinetic trap. Nat. Struct. Biol. 2, 129–138 (1995)
4. Cheetham, A.K., Rao, C.N., Feller, R.F.: Structural diversity and chemical trends in hybrid
inorganic–organic framework materials. Chem. Commun. 46, 4780–4795 (2006)
5. Zhu, Y., Hua, Z., Zhou, J., Wang, L., Zhao, J., Gong, Y., Wu, W., Ruan, M., Shi, J.: Hierarchical
mesoporous zeolites: direct self-assembly synthesis in a conventional surfactant solution by
kinetic control over the zeolite seed formation. Chem. Eur. J. 17, 14618–14627 (2011)
6. Wang, Y., Gao, X., Xiao, Y., Zhao, Q., Yang, J., Yan, Y., Huang, J.: Temperature dependent
coordinating self-assembly. Soft Matter 11, 2806–2811 (2015)
7. Zhong, Q.Z., Li, S., Chen, J., Xie, K., Pan, S., Richardson, J.J., Caruso, F.: Oxidation-mediated
kinetic strategies for engineering metal-phenolic networks. Angew. Chem. Int. Ed. 58, 12563–
12568 (2019)
8. Michele, L.D., Varrato, F., Kotar, J., Nathan, S.H., Foffi, G., Eiser, E.: Multistep kinetic selfassembly of DNA-coated colloids. Nat. Commun. 4, 2007 (2013)
9. Batten, S.R., Robson, R.: Interpenetrating nets: ordered, periodic entanglement. Angew. Chem.
Int. Ed. 37, 1460–1494 (1998)
10. Eddaoudi, M., Moler, D.B., Li, H., Chen, B., Reineke, T.M., O’Keefe, M., Yaghi, O.M.: Modular
chemistry: secondary building units as a basis for the design of highly porous and robust
metal–organic carboxylate frameworks. Acc. Chem. Res. 34, 319–330 (2001)
11. Kitagawa, S., Kitaura, R., Noro, S.: Functional porous coordination polymers. Angew. Chem.
Int. Ed. 43, 2334–2375 (2004)
12. Kitagawa, S., Uemura, K.: Dynamic porous properties of coordination polymers inspired by
hydrogen bonds. Chem. Soc. Rev. 34, 109–119 (2005)
13. Bradshaw, D., Claridge, J.B., Cussen, E.J., Prior, T.J., Rosseinsky, M.J.: Design, chirality, and
flexibility in nanoporous molecule-based materials. Acc. Chem. Res. 38, 273–282 (2005)
14. Kawano, M., Fujita, M.: Direct observation of crystalline-state guest exchange in coordination
networks. Coord. Chem. Rev. 251, 2592–2605 (2007)
15. Férey, G.: Hybrid porous solids: past, present, future. Chem. Rev. 37, 191–214 (2008)
16. Furukawa, H., Cordova, K.E., O’Keefe, M., Yaghi, O.M.: The chemistry and applications of
metal-organic frameworks. Science 341, 1230444 (2013)
17. Cook, T.R., Zheng, Y.R., Stang, P.J.: Metal-organic frameworks and self-assembled
supramolecular coordination complexes: comparing and contrasting the design, synthesis, and
functionality of metal-organic materials. Chem. Rev. 113, 734–777 (2013)
18. Hoskins, B.F., Robson, R.: Infinite polymeric frameworks consisting of three dimensionally
linked rod-like segments. J. Am. Chem. Soc. 111, 5962–5964 (1989)
H. Ohtsu et al.
In this sense, the careful design of desired interactive sites is a key step toward
building materials that mimic biological functions, particularly the ability to catalyze
reactions under mild conditions. This task will be accomplished by the judicious
development of multifunctional ligands, the selection of appropriate metal connectors, and tuning the reaction parameters. However, there are still many challenges
that need to be addressed before the kinetically assembled coordination networks
could come close to reaching such a formidable goal.
References
1. Dichtel, W.R., Miljani´ c, O.Š., Zhang, W., Spruell, J.M., Patel, K., Aprahamian, I., Heath, J.R.,
Stoddart, J.F.: Kinetic and thermodynamic approaches for the efficient formation of mechanical
bonds. Acc. Chem. Res. 41, 1750–1761 (2008)
2. Dickson, A., Brooks III, C.L.: Native states of fast-folding proteins are kinetic traps. J. Am.
Chem. Soc. 135, 4729–4734 (2013)
3. Hua, Q.X., Gozani, S.N., Chance, R.E., Hoffmann, J.A., Frank, B.H., Weiss, M.A.: Structure
of a protein in a kinetic trap. Nat. Struct. Biol. 2, 129–138 (1995)
4. Cheetham, A.K., Rao, C.N., Feller, R.F.: Structural diversity and chemical trends in hybrid
inorganic–organic framework materials. Chem. Commun. 46, 4780–4795 (2006)
5. Zhu, Y., Hua, Z., Zhou, J., Wang, L., Zhao, J., Gong, Y., Wu, W., Ruan, M., Shi, J.: Hierarchical
mesoporous zeolites: direct self-assembly synthesis in a conventional surfactant solution by
kinetic control over the zeolite seed formation. Chem. Eur. J. 17, 14618–14627 (2011)
6. Wang, Y., Gao, X., Xiao, Y., Zhao, Q., Yang, J., Yan, Y., Huang, J.: Temperature dependent
coordinating self-assembly. Soft Matter 11, 2806–2811 (2015)
7. Zhong, Q.Z., Li, S., Chen, J., Xie, K., Pan, S., Richardson, J.J., Caruso, F.: Oxidation-mediated
kinetic strategies for engineering metal-phenolic networks. Angew. Chem. Int. Ed. 58, 12563–
12568 (2019)
8. Michele, L.D., Varrato, F., Kotar, J., Nathan, S.H., Foffi, G., Eiser, E.: Multistep kinetic selfassembly of DNA-coated colloids. Nat. Commun. 4, 2007 (2013)
9. Batten, S.R., Robson, R.: Interpenetrating nets: ordered, periodic entanglement. Angew. Chem.
Int. Ed. 37, 1460–1494 (1998)
10. Eddaoudi, M., Moler, D.B., Li, H., Chen, B., Reineke, T.M., O’Keefe, M., Yaghi, O.M.: Modular
chemistry: secondary building units as a basis for the design of highly porous and robust
metal–organic carboxylate frameworks. Acc. Chem. Res. 34, 319–330 (2001)
11. Kitagawa, S., Kitaura, R., Noro, S.: Functional porous coordination polymers. Angew. Chem.
Int. Ed. 43, 2334–2375 (2004)
12. Kitagawa, S., Uemura, K.: Dynamic porous properties of coordination polymers inspired by
hydrogen bonds. Chem. Soc. Rev. 34, 109–119 (2005)
13. Bradshaw, D., Claridge, J.B., Cussen, E.J., Prior, T.J., Rosseinsky, M.J.: Design, chirality, and
flexibility in nanoporous molecule-based materials. Acc. Chem. Res. 38, 273–282 (2005)
14. Kawano, M., Fujita, M.: Direct observation of crystalline-state guest exchange in coordination
networks. Coord. Chem. Rev. 251, 2592–2605 (2007)
15. Férey, G.: Hybrid porous solids: past, present, future. Chem. Rev. 37, 191–214 (2008)
16. Furukawa, H., Cordova, K.E., O’Keefe, M., Yaghi, O.M.: The chemistry and applications of
metal-organic frameworks. Science 341, 1230444 (2013)
17. Cook, T.R., Zheng, Y.R., Stang, P.J.: Metal-organic frameworks and self-assembled
supramolecular coordination complexes: comparing and contrasting the design, synthesis, and
functionality of metal-organic materials. Chem. Rev. 113, 734–777 (2013)
18. Hoskins, B.F., Robson, R.: Infinite polymeric frameworks consisting of three dimensionally
linked rod-like segments. J. Am. Chem. Soc. 111, 5962–5964 (1989)