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16. Yang, J., Dewal, M.B., Profeta, S., Smith Jr., M.D., Li, Y., Shimizu, L.S.: Origins of selectivity
for the [2 + 2] cycloaddition of α, β-unsaturated ketones within a porous self-assembled organic
Framework. J. Am. Chem. Soc. 130, 612–621 (2008)
17. Comotti, A., Bracco, S., Distefano, G., Sozzani, P.: Methane, carbon dioxide and hydrogen
storage in nanoporous dipeptide-based materials. Chem. Commun. 284–286 (2009)
18. Yang, W., Greenaway, A., Lin, X., Matsuda, R., Blake, A.J., Wilson, C., Lewis, W., Hubberstey,
P., Kitagawa, S., Champness, N.R., Schröder, M.: Exceptional thermal stability in a supramolecular organic framework: porosity and gas storage. J. Am. Chem. Soc. 132, 14457–14469
(2010)
19. Mastalerz, M., Oppel, I.: Rational construction of an extrinsic porous molecular crystal with
an extraordinary high specific surface area. Angew. Chem. Int. Ed. 51, 5252–5255 (2012)
20. Luo, X.-Z., Jia, X.-J., Deng, J.-H., Zhong, J.-L., Liu, H.-J., Wang, K.-J., Zhong, D.-C.: A
microporous hydrogen-bonded organic framework: exceptional stability and highly selective
adsorption of gas and liquid. J. Am. Chem. Soc. 135, 11684–11687 (2013)
21. Lü, J., Perez-Krap, C., Suyetin, M., Alsmail, N.H., Yan, Y., Yang, S., Lewis, W., Bichoutskaia,
E., Tang, C.C., Blake, A.J., Cao, R., Schröder, M.: A robust binary supramolecular organic
framework (SOF) with high CO 2 adsorption and selectivity. J. Am. Chem. Soc. 136, 12828–
12831 (2014)
22. Comotti, A., Bracco, S., Yamamoto, A., Beretta, M., Hirukawa, T., Tohnai, N., Miyata, M.,
Sozzani, P.: Engineering switchable rotors in molecular crystals with open porosity. J. Am.
Chem. Soc. 136, 618–621 (2014)
23. Chen, T.-H., Popov, I., Kaveevivitchai, W., Chuang, Y.-C., Chen, Y.-S., Daugulis, O., Jacobson,
A.J., Miljani´ c, O.Š.: Thermally robust and porous noncovalent organic framework with high
affinity for fluorocarbons and CFCs. Nat. Commun. 5, 5131 (2014)
24. Tian, J., Zhou, T.-Y., Zhang, S.-C., Aloni, S., Altoe, M.V., Xie, S.-H., Wang, H., Zhang, D.-W.,
Zhao, X., Liu, Y., Li, Z.-T.: Three-dimensional periodic supramolecular organic framework
ion sponge in water and microcrystals. Nat. Commun. 5, 5574 (2014)
25. Li, P., He, Y., Zhao, Y., Weng, L., Wang, H., Krishna, R., Wu, H., Zhou, W., O’Keeffe, M.,
Han, Y., Chen, B.: A rod-packing microporous hydrogen-bonded organic framework for highly
selective separation of C 2 H 2 /CO 2 at room temperature. Angew. Chem. Int. Ed. 54, 574–577
(2015)
26. Wang, H., Li, B., Wu, H., Hu, T.-L., Yao, Z., Zhou, W., Xiang, S., Chen, B.: A flexible microporous hydrogen-bonded organic framework for gas sorption and separation. J. Am. Chem.
Soc. 137, 9963–9970 (2015)
27. Yadav, V.N., Comotti, A., Sozzani, P., Bracco, S., Bonge-Hansen, T., Hennum, M., Görbitz,
C.H.: Microporous molecular materials from dipeptides containing non-proteinogenic sesidues.
Angew. Chem. Int. Ed. 54, 15684–15688 (2015)
28. Zentner, C.A., Lai, H.W.H., Greenfield, J.T., Wiscons, R.A., Zeller, M., Campana, C.F., Talu,
O., FitzGerald, S.A., Rowsell, J.L.C.: High surface area and Z in a thermally stable 8-fold
polycatenated hydrogen-bonded framework. Chem. Commun. 51, 11642–11645 (2015)
29. Nandi, S., Chakraborty, D., Vaidhyanathan, R.: A permanently porous single molecule Hbonded organic framework for selective CO 2 capture. Chem. Commun. 52, 7249–7252 (2016)
30. Yang, W., Wang, J., Wang, H., Bao, Z., Zhao, J.C.-G., Chen, B.: Highly interpenetrated robust
microporous hydrogen-bonded organic framework for gas separation. Cryst. Growth Des. 17,
6132–6137 (2017)
31. Hu, F., Liu, C., Wu, M., Pang, J., Jiang, F., Yuan, D., Hong, M.: An ultrastable and easily
regenerated hydrogen-bonded organic molecular framework with permanent porosity. Angew.
Chem. Int. Ed. 56, 2101–2104 (2017)
32. Hisaki, I., Ikenaka, N., Gomez, E., Cohen, B., Tohnai, N., Douhal, A.: Hexaazatriphenylenebased hydrogen-bonded organic framework with permanent porosity and single-crystallinity.
Chem. Eur. J. 23, 11611–11619 (2017)
33. Hisaki, I., Suzuki, Y., Gomez, E., Cohen, B., Tohnai, N., Douhal, A.: Docking strategy to
construct thermostable, single-crystalline, hydrogen-bonded organic framework with high
surface area. Angew. Chem. Int. Ed. 57, 12650–12655 (2018)
I. Hisaki et al.
16. Yang, J., Dewal, M.B., Profeta, S., Smith Jr., M.D., Li, Y., Shimizu, L.S.: Origins of selectivity
for the [2 + 2] cycloaddition of α, β-unsaturated ketones within a porous self-assembled organic
Framework. J. Am. Chem. Soc. 130, 612–621 (2008)
17. Comotti, A., Bracco, S., Distefano, G., Sozzani, P.: Methane, carbon dioxide and hydrogen
storage in nanoporous dipeptide-based materials. Chem. Commun. 284–286 (2009)
18. Yang, W., Greenaway, A., Lin, X., Matsuda, R., Blake, A.J., Wilson, C., Lewis, W., Hubberstey,
P., Kitagawa, S., Champness, N.R., Schröder, M.: Exceptional thermal stability in a supramolecular organic framework: porosity and gas storage. J. Am. Chem. Soc. 132, 14457–14469
(2010)
19. Mastalerz, M., Oppel, I.: Rational construction of an extrinsic porous molecular crystal with
an extraordinary high specific surface area. Angew. Chem. Int. Ed. 51, 5252–5255 (2012)
20. Luo, X.-Z., Jia, X.-J., Deng, J.-H., Zhong, J.-L., Liu, H.-J., Wang, K.-J., Zhong, D.-C.: A
microporous hydrogen-bonded organic framework: exceptional stability and highly selective
adsorption of gas and liquid. J. Am. Chem. Soc. 135, 11684–11687 (2013)
21. Lü, J., Perez-Krap, C., Suyetin, M., Alsmail, N.H., Yan, Y., Yang, S., Lewis, W., Bichoutskaia,
E., Tang, C.C., Blake, A.J., Cao, R., Schröder, M.: A robust binary supramolecular organic
framework (SOF) with high CO 2 adsorption and selectivity. J. Am. Chem. Soc. 136, 12828–
12831 (2014)
22. Comotti, A., Bracco, S., Yamamoto, A., Beretta, M., Hirukawa, T., Tohnai, N., Miyata, M.,
Sozzani, P.: Engineering switchable rotors in molecular crystals with open porosity. J. Am.
Chem. Soc. 136, 618–621 (2014)
23. Chen, T.-H., Popov, I., Kaveevivitchai, W., Chuang, Y.-C., Chen, Y.-S., Daugulis, O., Jacobson,
A.J., Miljani´ c, O.Š.: Thermally robust and porous noncovalent organic framework with high
affinity for fluorocarbons and CFCs. Nat. Commun. 5, 5131 (2014)
24. Tian, J., Zhou, T.-Y., Zhang, S.-C., Aloni, S., Altoe, M.V., Xie, S.-H., Wang, H., Zhang, D.-W.,
Zhao, X., Liu, Y., Li, Z.-T.: Three-dimensional periodic supramolecular organic framework
ion sponge in water and microcrystals. Nat. Commun. 5, 5574 (2014)
25. Li, P., He, Y., Zhao, Y., Weng, L., Wang, H., Krishna, R., Wu, H., Zhou, W., O’Keeffe, M.,
Han, Y., Chen, B.: A rod-packing microporous hydrogen-bonded organic framework for highly
selective separation of C 2 H 2 /CO 2 at room temperature. Angew. Chem. Int. Ed. 54, 574–577
(2015)
26. Wang, H., Li, B., Wu, H., Hu, T.-L., Yao, Z., Zhou, W., Xiang, S., Chen, B.: A flexible microporous hydrogen-bonded organic framework for gas sorption and separation. J. Am. Chem.
Soc. 137, 9963–9970 (2015)
27. Yadav, V.N., Comotti, A., Sozzani, P., Bracco, S., Bonge-Hansen, T., Hennum, M., Görbitz,
C.H.: Microporous molecular materials from dipeptides containing non-proteinogenic sesidues.
Angew. Chem. Int. Ed. 54, 15684–15688 (2015)
28. Zentner, C.A., Lai, H.W.H., Greenfield, J.T., Wiscons, R.A., Zeller, M., Campana, C.F., Talu,
O., FitzGerald, S.A., Rowsell, J.L.C.: High surface area and Z in a thermally stable 8-fold
polycatenated hydrogen-bonded framework. Chem. Commun. 51, 11642–11645 (2015)
29. Nandi, S., Chakraborty, D., Vaidhyanathan, R.: A permanently porous single molecule Hbonded organic framework for selective CO 2 capture. Chem. Commun. 52, 7249–7252 (2016)
30. Yang, W., Wang, J., Wang, H., Bao, Z., Zhao, J.C.-G., Chen, B.: Highly interpenetrated robust
microporous hydrogen-bonded organic framework for gas separation. Cryst. Growth Des. 17,
6132–6137 (2017)
31. Hu, F., Liu, C., Wu, M., Pang, J., Jiang, F., Yuan, D., Hong, M.: An ultrastable and easily
regenerated hydrogen-bonded organic molecular framework with permanent porosity. Angew.
Chem. Int. Ed. 56, 2101–2104 (2017)
32. Hisaki, I., Ikenaka, N., Gomez, E., Cohen, B., Tohnai, N., Douhal, A.: Hexaazatriphenylenebased hydrogen-bonded organic framework with permanent porosity and single-crystallinity.
Chem. Eur. J. 23, 11611–11619 (2017)
33. Hisaki, I., Suzuki, Y., Gomez, E., Cohen, B., Tohnai, N., Douhal, A.: Docking strategy to
construct thermostable, single-crystalline, hydrogen-bonded organic framework with high
surface area. Angew. Chem. Int. Ed. 57, 12650–12655 (2018)
