444
S. Kobatake and D. Kitagawa
(a)
(b)
(c)
Fig. 25.19 UV light-induced photosalient effect of a hollow crystal of 15, mimicking Impatiens: a
deformation of the hollow crystal upon UV irradiation, b a hollow crystal packed with fluorescent
polystyrene beads with 1-mm diameter, c UV-induced scattering of fluorescent beads. Scale bars
= 20 µm. Adapted with permission from Ref. [52]. Copyright 2017 Wiley-VCH Verlag GmbH &
Co. KGaA, Weinheim
Acknowledgements We deeply appreciate Professors M. Irie, C. J. Bardeen, Drs. H. Nishi,
R. Tanaka, Mrs. T. Okuyama, H. Tsujioka, K. Kawasaki, A. Hirano for their collaboration. The
present work was supported by JSPS KAKENHI Grant Number JP26107013, Grant-in-Aid for
Scientific Research on Innovative Areas “Photosynergetics”.
References
1. Irie M (2000) Diarylethenes for memories and switches. Chem Rev 100:1685–1716
2. Irie M, Fukaminato T, Matsuda K, Kobatake S (2014) Photochromism of diarylethene
molecules and crystals: memories, switches, and actuators. Chem Rev 114:12174–12277
3. Abakumov GA, Nevodchikov VI (1982) Thermomechanical and photomechanical effects
observed on crystals of a free-radical complex. Dokl Akad Nauk SSSR 266:1407–1410
4. Irie M, Kobatake S, Horichi M (2001) Reversible surface morphology changes of a
photochromic diarylethene single crystal by photoirradiation. Science 291:1769–1772
5. Al-Kaysi RO, Mueller AM, Bardeen CJ (2006) Photochemically driven shape changes of
crystalline organic nanorods. J Am Chem Soc 128:15938–15939
S. Kobatake and D. Kitagawa
(a)
(b)
(c)
Fig. 25.19 UV light-induced photosalient effect of a hollow crystal of 15, mimicking Impatiens: a
deformation of the hollow crystal upon UV irradiation, b a hollow crystal packed with fluorescent
polystyrene beads with 1-mm diameter, c UV-induced scattering of fluorescent beads. Scale bars
= 20 µm. Adapted with permission from Ref. [52]. Copyright 2017 Wiley-VCH Verlag GmbH &
Co. KGaA, Weinheim
Acknowledgements We deeply appreciate Professors M. Irie, C. J. Bardeen, Drs. H. Nishi,
R. Tanaka, Mrs. T. Okuyama, H. Tsujioka, K. Kawasaki, A. Hirano for their collaboration. The
present work was supported by JSPS KAKENHI Grant Number JP26107013, Grant-in-Aid for
Scientific Research on Innovative Areas “Photosynergetics”.
References
1. Irie M (2000) Diarylethenes for memories and switches. Chem Rev 100:1685–1716
2. Irie M, Fukaminato T, Matsuda K, Kobatake S (2014) Photochromism of diarylethene
molecules and crystals: memories, switches, and actuators. Chem Rev 114:12174–12277
3. Abakumov GA, Nevodchikov VI (1982) Thermomechanical and photomechanical effects
observed on crystals of a free-radical complex. Dokl Akad Nauk SSSR 266:1407–1410
4. Irie M, Kobatake S, Horichi M (2001) Reversible surface morphology changes of a
photochromic diarylethene single crystal by photoirradiation. Science 291:1769–1772
5. Al-Kaysi RO, Mueller AM, Bardeen CJ (2006) Photochemically driven shape changes of
crystalline organic nanorods. J Am Chem Soc 128:15938–15939