19 Photoinduced Morphological Transformation and Photodriven …
347
UV light and they were able to affect the diffusion direction of other objects. Moreover, the nanofibers proved to be capable of assisting the clustering of PS beads
into a UV-focused point. We expect that the further investigation on various types
of morphological changes and external stimuli will lead to the development of more
sophisticated functionalities.
Acknowledgements This work was supported by a Grant-in-Aid for Scientific Research on Innovative Areas “Photosynergetics” (JSPS KAKENHI Grant No. JP26107008), from MEXT, Japan and
PRESTO, JST (Grant No. JPMJPR12K7). This work was performed under the Research Program of
“Dynamic Alliance for Open Innovation Bridging Human, Environment and Materials” in “Network
Joint Research Center for Materials and Devices” (No. 2014445, 20162025, and 20172024).
References
1. Israelachvili JN (1992) Intermolecular and surface forces, 2nd edn. Academic Press, London
2. Zhang X, Rehm S, Safont-Sempere MM, Würthner F (2009) Vesicular perylene dye
nanocapsules as supramolecular fluorescent pH sensor systems. Nat Chem 1:623–629
3. Kunitake T, Nakashima N, Shimomura M, Okahata Y, Kano K, Ogawa T (1980) Unique properties of chromophore-containing bilayer aggregates: enhanced chirality and photochemically
induced morphological change. J Am Chem Soc 102:6642–6644
4. Faure D, Gravier J, Labrot T, Desbat B, Oda R, Bassani DM (2005) Photoinduced morphism
of gemini surfactant aggregates. Chem Commun 1167–1169
5. Hamada T, Sugimoto R, Vestergaard MC, Nagasaki T, Takagi M (2010) Membrane disk and
sphere: controllable mesoscopic structures for the capture and release of a targeted object. J
Am Chem Soc 132:10528–10532
6. Ikegami T, Kageyama Y, Obara K, Takeda S (2016) Dissipative and autonomous squarewave self-oscillation of a macroscopic hybrid self-assembly under continuous light irradiation.
Angew Chem Int Ed 55:8239–8243
7. Yagai S, Iwai K, Karatsu T, Kitamura A (2012) Photoswitchable exciton coupling in
merocyanine-diarylethene multi-chromophore hydrogen-bonded complexes. Angew Chem Int
Ed 51:9679–9683
8. Irie M, Fukaminato T, Matsuda K, Kobatake S (2014) Photochromism of diarylethene
molecules and crystals: memories, switches, and actuators. Chem Rev 114:12174–12277
9. Wang L, Zou H, Dong Z, Zhou L, Li J, Luo Q, Zhu J, Xu J, Liu J (2014) Temperature-driven
switching of the catalytic activity of artificial glutathione peroxidase by the shape transition
between the nanotubes and vesicle-like structures. Langmuir 30:4013–4018
10. Higashiguchi K, Taira G, Ji Kitai, Hirose T, Matsuda K (2015) Photoinduced macroscopic
morphological transformation of an amphiphilic diarylethene assembly: reversible dynamic
motion. J Am Chem Soc 137:2722–2729
11. Yotsuji H, Higashiguchi K, Sato R, Shigeta Y, Matsuda K (2017) Phototransformative
supramolecular assembly of amphiphilic diarylethenes realized by the combination of
photochromism and lower critical solution temperature behavior. Chem Eur J 23:15059–15066
12. Higashiguchi K, Yotsuji H, Matsuda K (2017) Determination of quantum yield of photoreaction
in solution and in suspension by global fitting of prolonged change of concentration. Chem
Lett 46:1564–1566
13. Sakaguchi A, Higashiguchi K, Matsuda K (2018) Bundle formation of supramolecular fibers
of amphiphilic diarylethene by depletion force. Chem Commun 54:4298–4301
14. Sakaguchi A, Higashiguchi K, Matsuda K (2017) Anisotropic diffusion of microbeads
surrounded by an anisotropically elongated supramolecular diarylethene architecture under
linearly polarized light. ChemPhotoChem 1:488–492
347
UV light and they were able to affect the diffusion direction of other objects. Moreover, the nanofibers proved to be capable of assisting the clustering of PS beads
into a UV-focused point. We expect that the further investigation on various types
of morphological changes and external stimuli will lead to the development of more
sophisticated functionalities.
Acknowledgements This work was supported by a Grant-in-Aid for Scientific Research on Innovative Areas “Photosynergetics” (JSPS KAKENHI Grant No. JP26107008), from MEXT, Japan and
PRESTO, JST (Grant No. JPMJPR12K7). This work was performed under the Research Program of
“Dynamic Alliance for Open Innovation Bridging Human, Environment and Materials” in “Network
Joint Research Center for Materials and Devices” (No. 2014445, 20162025, and 20172024).
References
1. Israelachvili JN (1992) Intermolecular and surface forces, 2nd edn. Academic Press, London
2. Zhang X, Rehm S, Safont-Sempere MM, Würthner F (2009) Vesicular perylene dye
nanocapsules as supramolecular fluorescent pH sensor systems. Nat Chem 1:623–629
3. Kunitake T, Nakashima N, Shimomura M, Okahata Y, Kano K, Ogawa T (1980) Unique properties of chromophore-containing bilayer aggregates: enhanced chirality and photochemically
induced morphological change. J Am Chem Soc 102:6642–6644
4. Faure D, Gravier J, Labrot T, Desbat B, Oda R, Bassani DM (2005) Photoinduced morphism
of gemini surfactant aggregates. Chem Commun 1167–1169
5. Hamada T, Sugimoto R, Vestergaard MC, Nagasaki T, Takagi M (2010) Membrane disk and
sphere: controllable mesoscopic structures for the capture and release of a targeted object. J
Am Chem Soc 132:10528–10532
6. Ikegami T, Kageyama Y, Obara K, Takeda S (2016) Dissipative and autonomous squarewave self-oscillation of a macroscopic hybrid self-assembly under continuous light irradiation.
Angew Chem Int Ed 55:8239–8243
7. Yagai S, Iwai K, Karatsu T, Kitamura A (2012) Photoswitchable exciton coupling in
merocyanine-diarylethene multi-chromophore hydrogen-bonded complexes. Angew Chem Int
Ed 51:9679–9683
8. Irie M, Fukaminato T, Matsuda K, Kobatake S (2014) Photochromism of diarylethene
molecules and crystals: memories, switches, and actuators. Chem Rev 114:12174–12277
9. Wang L, Zou H, Dong Z, Zhou L, Li J, Luo Q, Zhu J, Xu J, Liu J (2014) Temperature-driven
switching of the catalytic activity of artificial glutathione peroxidase by the shape transition
between the nanotubes and vesicle-like structures. Langmuir 30:4013–4018
10. Higashiguchi K, Taira G, Ji Kitai, Hirose T, Matsuda K (2015) Photoinduced macroscopic
morphological transformation of an amphiphilic diarylethene assembly: reversible dynamic
motion. J Am Chem Soc 137:2722–2729
11. Yotsuji H, Higashiguchi K, Sato R, Shigeta Y, Matsuda K (2017) Phototransformative
supramolecular assembly of amphiphilic diarylethenes realized by the combination of
photochromism and lower critical solution temperature behavior. Chem Eur J 23:15059–15066
12. Higashiguchi K, Yotsuji H, Matsuda K (2017) Determination of quantum yield of photoreaction
in solution and in suspension by global fitting of prolonged change of concentration. Chem
Lett 46:1564–1566
13. Sakaguchi A, Higashiguchi K, Matsuda K (2018) Bundle formation of supramolecular fibers
of amphiphilic diarylethene by depletion force. Chem Commun 54:4298–4301
14. Sakaguchi A, Higashiguchi K, Matsuda K (2017) Anisotropic diffusion of microbeads
surrounded by an anisotropically elongated supramolecular diarylethene architecture under
linearly polarized light. ChemPhotoChem 1:488–492