15 Creation of Molecularly Integrated Multi-responsive …
271
Thus, “molecularly integrated multi-responsive photochromic systems” could
be synthesized through several pathways. We hope these findings can be considered milestones to advance research and lead to useful applications in the field of
photochromism.
Acknowledgements The author is deeply grateful to Professors H. Miyasaka (Osaka University),
T. Kawai (NAIST), J. Abe (Aoyama Gakuin University) and K. Matsuda (Kyoto University) for the
kind assistance and guidance during the research period. Thanks are extended to Drs. T. Ubukata,
I. Kawamura and T. Nakagawa of Yokohama National University for their great help to conduct the
research, and to the students and postdocs of our laboratory who have carried out the experiments
with great efforts. The work shown in this chapter was supported by JSPS KAKENHI Grant Number
26107009 in Scientific Research on Innovative Areas “Photosynergetics,” and MEXT KAKENHI
Grant Number JP19050004 in Grant-in-Aid for Scientific Research in Priority Areas “New Frontiers
in Photochromism (No. 471).”
References
1. Dürr H, Bouas-Laurent H (eds) (2003) Photochromism: Molecules and systems. Elsevier,
Amsterdam (Revised Ed.)
2. Crano JC, Guglielmetti RJ (eds) (1999) Organic photochromic and thermochromic compounds,
vol 1 and 2. Plenum Press, New York
3. Irie M, Yokoyama Y, Seki T (eds) (2013) New frontiers in photochromism. Springer, Tokyo
4. Tian H, Zhang J (eds) (2016) Photochromic materials: preparation, properties and applications.
Wiley-VCH, Weinheim
5. Yokoyama Y, Nakatani K (eds) (2017) Photon-working switches. Springer, Tokyo
6. Irie M (2000) Diarylethenes for memories and switches. Chem Rev 100:1685–1716
7. Tian H, Yang S (2004) Recent progresses on diarylethene based photochromic switches. Chem
Soc Rev 33:85–97
8. Irie M, Fukaminato T, Matsuda K, Kobatake S (2014) Photochromism of diarylethene
molecules and crystals: memories, switches, and actuators. Chem Rev 114:12174–12277
9. Kusumoto S, Nakagawa T, Yokoyama Y (2016) All-optical fine-tuning of absorption band of
diarylethene with photochromic acid-generating spiropyran. Adv Opt Mater 4:1350–1353
10. Shi Z, Peng P, Strohecker D, Liao Y (2011) Long-lived photoacid based upon a photochromic
reaction. J Am Chem Soc 133:14699–14703
11. Hoefnage AJ, Hoefnagel MA, Wepster BM (1976) Substituent effects 5. Resonance saturation
effects in anilines having a π-donor group in para position. J Am Chem Soc 98:6194–6197
12. Fickling MM, Fischer A, Mann BR, Packer J, Vaughan J (1959) Hammett substituent
constants for electron-withdrawing substituents: Dissociation of phenols, anilinium ions and
dimethylanilinium ions. J Am Chem Soc 81:4226–4230
13. Uehara S, Hiromoto Y, Minkovska S, Suzuki K, Ubukata T, Yokoyama Y (2012) Photochromic
behavior of a bisthienylethene bearing Cu(I)-1,10-phenanthroline complexes. Dyes Pigm
92:861–867
14. Yokoyama Y, Hiromoto Y, Takagi K, Ishii K, Delbaere S, Watanobe Y, Ubukata T (2015)
Solubility control of organic acid-base salts by photochromism. Dyes Pigm 114:1–7
15. Dean JA (ed) (1985) Lange’s handbook of chemistry, vol 5–53, 13th edn. McGraw-Hill, New
York
16. Mahvidi S, Takeuchi S, Kusumoto S, Sato H, Nakagawa T, Yokoyama Y (2016) Gated
photochromic system of diarylethene with a photon-working key. Org Lett 18:5042–5045
17. Irie M, Sayo K (1992) Solvent effects on the photochromic reactions of diarylethene derivatives.
J Phys Chem 96:7671–7674
271
Thus, “molecularly integrated multi-responsive photochromic systems” could
be synthesized through several pathways. We hope these findings can be considered milestones to advance research and lead to useful applications in the field of
photochromism.
Acknowledgements The author is deeply grateful to Professors H. Miyasaka (Osaka University),
T. Kawai (NAIST), J. Abe (Aoyama Gakuin University) and K. Matsuda (Kyoto University) for the
kind assistance and guidance during the research period. Thanks are extended to Drs. T. Ubukata,
I. Kawamura and T. Nakagawa of Yokohama National University for their great help to conduct the
research, and to the students and postdocs of our laboratory who have carried out the experiments
with great efforts. The work shown in this chapter was supported by JSPS KAKENHI Grant Number
26107009 in Scientific Research on Innovative Areas “Photosynergetics,” and MEXT KAKENHI
Grant Number JP19050004 in Grant-in-Aid for Scientific Research in Priority Areas “New Frontiers
in Photochromism (No. 471).”
References
1. Dürr H, Bouas-Laurent H (eds) (2003) Photochromism: Molecules and systems. Elsevier,
Amsterdam (Revised Ed.)
2. Crano JC, Guglielmetti RJ (eds) (1999) Organic photochromic and thermochromic compounds,
vol 1 and 2. Plenum Press, New York
3. Irie M, Yokoyama Y, Seki T (eds) (2013) New frontiers in photochromism. Springer, Tokyo
4. Tian H, Zhang J (eds) (2016) Photochromic materials: preparation, properties and applications.
Wiley-VCH, Weinheim
5. Yokoyama Y, Nakatani K (eds) (2017) Photon-working switches. Springer, Tokyo
6. Irie M (2000) Diarylethenes for memories and switches. Chem Rev 100:1685–1716
7. Tian H, Yang S (2004) Recent progresses on diarylethene based photochromic switches. Chem
Soc Rev 33:85–97
8. Irie M, Fukaminato T, Matsuda K, Kobatake S (2014) Photochromism of diarylethene
molecules and crystals: memories, switches, and actuators. Chem Rev 114:12174–12277
9. Kusumoto S, Nakagawa T, Yokoyama Y (2016) All-optical fine-tuning of absorption band of
diarylethene with photochromic acid-generating spiropyran. Adv Opt Mater 4:1350–1353
10. Shi Z, Peng P, Strohecker D, Liao Y (2011) Long-lived photoacid based upon a photochromic
reaction. J Am Chem Soc 133:14699–14703
11. Hoefnage AJ, Hoefnagel MA, Wepster BM (1976) Substituent effects 5. Resonance saturation
effects in anilines having a π-donor group in para position. J Am Chem Soc 98:6194–6197
12. Fickling MM, Fischer A, Mann BR, Packer J, Vaughan J (1959) Hammett substituent
constants for electron-withdrawing substituents: Dissociation of phenols, anilinium ions and
dimethylanilinium ions. J Am Chem Soc 81:4226–4230
13. Uehara S, Hiromoto Y, Minkovska S, Suzuki K, Ubukata T, Yokoyama Y (2012) Photochromic
behavior of a bisthienylethene bearing Cu(I)-1,10-phenanthroline complexes. Dyes Pigm
92:861–867
14. Yokoyama Y, Hiromoto Y, Takagi K, Ishii K, Delbaere S, Watanobe Y, Ubukata T (2015)
Solubility control of organic acid-base salts by photochromism. Dyes Pigm 114:1–7
15. Dean JA (ed) (1985) Lange’s handbook of chemistry, vol 5–53, 13th edn. McGraw-Hill, New
York
16. Mahvidi S, Takeuchi S, Kusumoto S, Sato H, Nakagawa T, Yokoyama Y (2016) Gated
photochromic system of diarylethene with a photon-working key. Org Lett 18:5042–5045
17. Irie M, Sayo K (1992) Solvent effects on the photochromic reactions of diarylethene derivatives.
J Phys Chem 96:7671–7674