25. Tanaka H, Inoue Y, Mori T (2018) Circularly polarized luminescence and circular dichroisms in
small organic molecules: correlation between excitation and emission dissymmetry factors.
ChemPhotoChem 2:386–402
26. Kitayama Y, Amako T, Suzuki N, Fujiki M, Imai Y (2014) Enhancing circularly polarised
luminescence by extending the π-conjugation of axially chiral compounds. Org Biomol Chem
12:4342–4346
27. Kumar J, Nakashima T, Kawai T (2015) Circularly polarized luminescence in chiral molecules
and supramolecular assemblies. J Phys Chem Lett 6:3445–3452
28. Longhi G, Castiglioni E, Koshoubu J, Mazzeo G, Abbate S (2016) Circularly polarized
luminescence: a review of experimental and theoretical aspects. Chirality 28:696–707
29. Saleh N, Srebro M, Reynaldo T, Vanthuyne N, Toupet L, Chang VI, Muller G, Williams G,
Roussel C, Autschbach J, Crassous J (2015) Enantio-enriched CPL-active helicene–bipyridine–
rhenium complexes. Chem Commun 51:3754–3757
30. Abbate S, Longhi G, Lebon F, Castiglioni E, Superchi S, Pisani L, Fontana F, Torricelli F,
Caronna T, Villani C, Sabia R, Tommasini M, Lucotti A, Mendola D, Mele A, Lightner DA
(2014) Helical sense-responsive and substituent-sensitive features in vibrational and electronic
circular dichroism, in circularly polarized luminescence and in Raman spectra of some simple
optically active hexahelicenes. J Phys Chem C 118:1682–1695
31. Liu Y, Cerezo J, Mazzeo G, Lin N, Zhao X, Longhi G, Abbate S, Santoro F (2016) Vibronic
coupling explains the different aspect of electronic circular dichroism and of circularly polarized
luminescence spectra of hexahelicenes. J Chem Theory Comput 12:2799–2819
32. Sato T, Tajima N, Ueno H, Harada T, Fujiki M, Imai Y (2017) Binaphthyl luminophores with
triphenylsilyl groups: sign inversion of circularly polarized luminescence and circular dichroism. Tetrahedron 72:7032–7038
33. Longhi G, Castiglioni E, Abbate S, Lebon F, Lightner DA (2013) Experimental and calculated
CPL spectra and related spectroscopic data of camphor and other simple chiral bicyclic ketones.
Chirality 25:589–599
34. Schippers PH, van der Ploeg JPM, Dekkers HPJM (1983) Circular polarization in the Fluorescence of β,γ-enones: distortion in the
1
nπà states. J Am Chem Soc 105:84–89
35. Dekkers HPJM, Closs LEJ (1976) The optical activity of low symmetry ketones in absorption
and emission. J Am Chem Soc 98:2210–2219
36. Moscowitz A (1960) Theory and analysis of rotatory dispersion curves. In: Djerassi C
(ed) Optical rotatory dispersion. McGraw-Hill, New York, pp 150–177
37. Lightner DA, Gurst JE (2000) Organic conformational analysis and stereochemistry from
circular dichroism spectroscopy. Wiley, New York, Chapter 4
38. Morcillo SP, Miguel D, Alvarez de Cienfuegos L, Justicia J, Abbate S, Castiglioni E, Bour C,
Ribagorda M, Cardenas DJ, Paredes JM, Crovetto J, Choquesillo-Lazarte D, Mota AJ, Carreño
MC, Longhi G, Cuerva JM (2016) Stapled helical o-OPE foldamers as new circularly polarized
luminescence emitters based on carbophilic interactions with Ag(I)-sensitivity. Chem Sci
7:5663–5670
39. Amako T, Nakabayashi K, Suzuki N, Guo S, Rahim NAA, Harada T, Fujiki M, Imai Y (2015)
Pyrene magic: chiroptical enciphering and deciphering 1,3-dioxolane bearing two wirepullings
to drive two remote pyrenes. Chem Commun 51:8237–8240
40. Hara N, Yanai M, Kaji D, Shizuma M, Tajima N, Fujiki M, Imai Y (2000) A pivotal biaryl
rotamer bearing two floppy pyrenes that exhibits cryptochiral characteristics in the ground state.
ChemistrySelect 3:9970
41. Reiné P, Justicia J, Morcillo SP, Abbate S, Vaz B, Ribagorda M, Orte Á, Álvarez de
Cienfuegos L, Longhi G, Campaña AG, Miguel D, Cuerva JM (2018) Pyrene-containing
ortho-oligo(phenylene)ethynylene foldamer as a ratiometric probe based on circularly polarized
luminescence. J Org Chem 83:4455–4463
42. Domínguez Z, López-Rodríguez R, Álvarez E, Abbate S, Longhi G, Pischel U, Ros A (2018)
Azabora[5]helicene charge-transfer dyes show efficient and spectrally variable circularly polarized luminescence. Chem Eur J 24:12660–12668
10 Structural and Electronic Information Drawn. . .
245
small organic molecules: correlation between excitation and emission dissymmetry factors.
ChemPhotoChem 2:386–402
26. Kitayama Y, Amako T, Suzuki N, Fujiki M, Imai Y (2014) Enhancing circularly polarised
luminescence by extending the π-conjugation of axially chiral compounds. Org Biomol Chem
12:4342–4346
27. Kumar J, Nakashima T, Kawai T (2015) Circularly polarized luminescence in chiral molecules
and supramolecular assemblies. J Phys Chem Lett 6:3445–3452
28. Longhi G, Castiglioni E, Koshoubu J, Mazzeo G, Abbate S (2016) Circularly polarized
luminescence: a review of experimental and theoretical aspects. Chirality 28:696–707
29. Saleh N, Srebro M, Reynaldo T, Vanthuyne N, Toupet L, Chang VI, Muller G, Williams G,
Roussel C, Autschbach J, Crassous J (2015) Enantio-enriched CPL-active helicene–bipyridine–
rhenium complexes. Chem Commun 51:3754–3757
30. Abbate S, Longhi G, Lebon F, Castiglioni E, Superchi S, Pisani L, Fontana F, Torricelli F,
Caronna T, Villani C, Sabia R, Tommasini M, Lucotti A, Mendola D, Mele A, Lightner DA
(2014) Helical sense-responsive and substituent-sensitive features in vibrational and electronic
circular dichroism, in circularly polarized luminescence and in Raman spectra of some simple
optically active hexahelicenes. J Phys Chem C 118:1682–1695
31. Liu Y, Cerezo J, Mazzeo G, Lin N, Zhao X, Longhi G, Abbate S, Santoro F (2016) Vibronic
coupling explains the different aspect of electronic circular dichroism and of circularly polarized
luminescence spectra of hexahelicenes. J Chem Theory Comput 12:2799–2819
32. Sato T, Tajima N, Ueno H, Harada T, Fujiki M, Imai Y (2017) Binaphthyl luminophores with
triphenylsilyl groups: sign inversion of circularly polarized luminescence and circular dichroism. Tetrahedron 72:7032–7038
33. Longhi G, Castiglioni E, Abbate S, Lebon F, Lightner DA (2013) Experimental and calculated
CPL spectra and related spectroscopic data of camphor and other simple chiral bicyclic ketones.
Chirality 25:589–599
34. Schippers PH, van der Ploeg JPM, Dekkers HPJM (1983) Circular polarization in the Fluorescence of β,γ-enones: distortion in the
1
nπà states. J Am Chem Soc 105:84–89
35. Dekkers HPJM, Closs LEJ (1976) The optical activity of low symmetry ketones in absorption
and emission. J Am Chem Soc 98:2210–2219
36. Moscowitz A (1960) Theory and analysis of rotatory dispersion curves. In: Djerassi C
(ed) Optical rotatory dispersion. McGraw-Hill, New York, pp 150–177
37. Lightner DA, Gurst JE (2000) Organic conformational analysis and stereochemistry from
circular dichroism spectroscopy. Wiley, New York, Chapter 4
38. Morcillo SP, Miguel D, Alvarez de Cienfuegos L, Justicia J, Abbate S, Castiglioni E, Bour C,
Ribagorda M, Cardenas DJ, Paredes JM, Crovetto J, Choquesillo-Lazarte D, Mota AJ, Carreño
MC, Longhi G, Cuerva JM (2016) Stapled helical o-OPE foldamers as new circularly polarized
luminescence emitters based on carbophilic interactions with Ag(I)-sensitivity. Chem Sci
7:5663–5670
39. Amako T, Nakabayashi K, Suzuki N, Guo S, Rahim NAA, Harada T, Fujiki M, Imai Y (2015)
Pyrene magic: chiroptical enciphering and deciphering 1,3-dioxolane bearing two wirepullings
to drive two remote pyrenes. Chem Commun 51:8237–8240
40. Hara N, Yanai M, Kaji D, Shizuma M, Tajima N, Fujiki M, Imai Y (2000) A pivotal biaryl
rotamer bearing two floppy pyrenes that exhibits cryptochiral characteristics in the ground state.
ChemistrySelect 3:9970
41. Reiné P, Justicia J, Morcillo SP, Abbate S, Vaz B, Ribagorda M, Orte Á, Álvarez de
Cienfuegos L, Longhi G, Campaña AG, Miguel D, Cuerva JM (2018) Pyrene-containing
ortho-oligo(phenylene)ethynylene foldamer as a ratiometric probe based on circularly polarized
luminescence. J Org Chem 83:4455–4463
42. Domínguez Z, López-Rodríguez R, Álvarez E, Abbate S, Longhi G, Pischel U, Ros A (2018)
Azabora[5]helicene charge-transfer dyes show efficient and spectrally variable circularly polarized luminescence. Chem Eur J 24:12660–12668
10 Structural and Electronic Information Drawn. . .
245