49. Gossauer A, Fehr F, Nydegger F, Stöckli-Evans H (1997) Synthesis and conformational studies
of urobilin difluoroboron complexes. unprecedented solvent-dependent chiroptical properties of
the BF 2 chelate of an urobilinoid analogue. J Am Chem Soc 119:1599–1608
50. Sánchez-Carnerero EM, Moreno F, Maroto BL, Agarrabeitia AR, Ortiz MJ, Vo BG, Muller G,
de la Moya S (2014) Circularly polarized luminescence by visible-light absorption in a chiral OBODIPY dye: unprecedented design of CPL organic molecules from achiral chromophores. J
Am Chem Soc 136:3346–3349
51. Gartzia-Rivero L, Sánchez-Carnerero EM, Jiménez J, Bañuelos J, Moreno F, Maroto BL,
López-Arbeloa I, de la Moya S (2017) Modulation of ICT probability in bi(polyarene)-based
O-BODIPYs: towards the development of low-cost bright arene-BODIPY dyad. Dalton Trans
46:11830–11839
52. Jiménez J, Cerdán L, Moreno F, Maroto BL, García-Moreno I, Lunkley JL, Muller G, de la
Moya S (2017) Chiral organic dyes endowed with circularly polarized laser emission. J Phys
Chem C 121:5287–5292
53. Jiménez J, Moreno F, Maroto BL, Cabreros TA, Huy AS, Muller G, Bañuelos J, de la Moya S
(2019) Modulating ICT emission: a new strategy to manipulate the CPL sign in chiral emitters.
Chem Commun 55:1631–1634
54. Zhang S, Wang Y, Meng F, Dai C, Cheng Y, Zhu C (2015) Circularly polarized luminescence
of AIE-active chiral O-BODIPYs induced via intramolecular energy transfer. Chem Commun
51:9014–9017
55. Alnoman RB, Rihn S, O’Connor DC, Black FA, Costello B, Waddell PG, Clegg W, Peacock
RD, Herrebout W, Knight JG, Hall MJ (2016) Circularly polarized luminescence from helically
chiral N,N,O,O-boron-chelated dipyrromethenes. Chem Eur J 22:93–96
56. Gobo Y, Yamamura M, Nakamura T, Nabeshima T (2016) Synthesis and chiroptical properties
of a ring-fused BODIPY with a skewed chiral π skeleton. Org Lett 18:2719–2721
57. Clarke R, Ho KL, Alsimaree AA, Waddell PG, Bogaerts J, Herrebout W, Knight J, Pal R,
Penfold T, Hall MJ (2017) Circularly polarised luminescence from helically chiral “confused”
N,N,O,C-boron-chelated dipyrromethenes (BODIPYs). ChemPhotoChem 1:513–517
58. Toyoda M, Imai Y, Mori T (2017) Propeller chirality of boron heptaaryldipyrromethene:
unprecedented supramolecular dimerization and chiroptical properties. Phys Chem Lett
8:42–48
59. Bruhn T, Pescitelli G, Jurinovich S, Schaumlöffel A, Witterauf F, Ahrens J, Bröring M,
Bringmann G (2014) Axially chiral BODIPY DYEmers: an apparent exception to the exciton
chirality rule. Angew Chem Int Ed Engl 53:14592–14595
60. Zinna F, Bruhn T, Guido CA, Ahrens J, Bröring M, Di Bari L, Pescitelli G (2016) Circularly
polarized luminescence from axially chiral BODIPY DYEmers: an experimental and computational study. Chem Eur J 22:16089–16098
61. Sanchez-Carnerero EM, Moreno F, Maroto BL, Agarrabeitia AR, Bañuelos J, Arbeloa T,
López-Arbeloa I, Ortiz MJ, de la Moya S (2013) Unprecedented induced axial chirality in a
molecular BODIPY dye: strongly bisignated electronic circular dichroism in the visible region.
Chem Commun 49:11641–11643
62. Ray C, Sanchez-Carnerero EM, Moreno F, Maroto BL, Agarrabeitia AR, Ortiz MJ, LópezArbeloa I, Bañuelos J, Cohovi KD, Lunkley JL, Muller G, de la Moya S (2016) Bis
(haloBODIPYs) with labile helicity: valuable simple organic molecules that enable circularly
polarized luminescence. Chem Eur J 22:8805–8808
63. Niu S, Ulrich G, Retailleau P, Ziessel R (2011) BODIPY-bridged push–pull chromophores:
optical and electrochemical properties. Tetrahedron Lett 52:4848–4853
64. Boens N, Leen V, Dehaen W (2012) Fluorescent indicators based on BODIPY. Chem Soc Rev
41:1130–1172
65. Bonnier C, Machin DD, Abdi O, Koivisto BD (2013) Manipulating non-innocent π-spacers: the
challenges of using 2,6-disubstituted BODIPY cores within donor-acceptor light-harvesting
motifs. Org Biomol Chem 11:3756–3760
148
M. J. Hall and S. de la Moya
of urobilin difluoroboron complexes. unprecedented solvent-dependent chiroptical properties of
the BF 2 chelate of an urobilinoid analogue. J Am Chem Soc 119:1599–1608
50. Sánchez-Carnerero EM, Moreno F, Maroto BL, Agarrabeitia AR, Ortiz MJ, Vo BG, Muller G,
de la Moya S (2014) Circularly polarized luminescence by visible-light absorption in a chiral OBODIPY dye: unprecedented design of CPL organic molecules from achiral chromophores. J
Am Chem Soc 136:3346–3349
51. Gartzia-Rivero L, Sánchez-Carnerero EM, Jiménez J, Bañuelos J, Moreno F, Maroto BL,
López-Arbeloa I, de la Moya S (2017) Modulation of ICT probability in bi(polyarene)-based
O-BODIPYs: towards the development of low-cost bright arene-BODIPY dyad. Dalton Trans
46:11830–11839
52. Jiménez J, Cerdán L, Moreno F, Maroto BL, García-Moreno I, Lunkley JL, Muller G, de la
Moya S (2017) Chiral organic dyes endowed with circularly polarized laser emission. J Phys
Chem C 121:5287–5292
53. Jiménez J, Moreno F, Maroto BL, Cabreros TA, Huy AS, Muller G, Bañuelos J, de la Moya S
(2019) Modulating ICT emission: a new strategy to manipulate the CPL sign in chiral emitters.
Chem Commun 55:1631–1634
54. Zhang S, Wang Y, Meng F, Dai C, Cheng Y, Zhu C (2015) Circularly polarized luminescence
of AIE-active chiral O-BODIPYs induced via intramolecular energy transfer. Chem Commun
51:9014–9017
55. Alnoman RB, Rihn S, O’Connor DC, Black FA, Costello B, Waddell PG, Clegg W, Peacock
RD, Herrebout W, Knight JG, Hall MJ (2016) Circularly polarized luminescence from helically
chiral N,N,O,O-boron-chelated dipyrromethenes. Chem Eur J 22:93–96
56. Gobo Y, Yamamura M, Nakamura T, Nabeshima T (2016) Synthesis and chiroptical properties
of a ring-fused BODIPY with a skewed chiral π skeleton. Org Lett 18:2719–2721
57. Clarke R, Ho KL, Alsimaree AA, Waddell PG, Bogaerts J, Herrebout W, Knight J, Pal R,
Penfold T, Hall MJ (2017) Circularly polarised luminescence from helically chiral “confused”
N,N,O,C-boron-chelated dipyrromethenes (BODIPYs). ChemPhotoChem 1:513–517
58. Toyoda M, Imai Y, Mori T (2017) Propeller chirality of boron heptaaryldipyrromethene:
unprecedented supramolecular dimerization and chiroptical properties. Phys Chem Lett
8:42–48
59. Bruhn T, Pescitelli G, Jurinovich S, Schaumlöffel A, Witterauf F, Ahrens J, Bröring M,
Bringmann G (2014) Axially chiral BODIPY DYEmers: an apparent exception to the exciton
chirality rule. Angew Chem Int Ed Engl 53:14592–14595
60. Zinna F, Bruhn T, Guido CA, Ahrens J, Bröring M, Di Bari L, Pescitelli G (2016) Circularly
polarized luminescence from axially chiral BODIPY DYEmers: an experimental and computational study. Chem Eur J 22:16089–16098
61. Sanchez-Carnerero EM, Moreno F, Maroto BL, Agarrabeitia AR, Bañuelos J, Arbeloa T,
López-Arbeloa I, Ortiz MJ, de la Moya S (2013) Unprecedented induced axial chirality in a
molecular BODIPY dye: strongly bisignated electronic circular dichroism in the visible region.
Chem Commun 49:11641–11643
62. Ray C, Sanchez-Carnerero EM, Moreno F, Maroto BL, Agarrabeitia AR, Ortiz MJ, LópezArbeloa I, Bañuelos J, Cohovi KD, Lunkley JL, Muller G, de la Moya S (2016) Bis
(haloBODIPYs) with labile helicity: valuable simple organic molecules that enable circularly
polarized luminescence. Chem Eur J 22:8805–8808
63. Niu S, Ulrich G, Retailleau P, Ziessel R (2011) BODIPY-bridged push–pull chromophores:
optical and electrochemical properties. Tetrahedron Lett 52:4848–4853
64. Boens N, Leen V, Dehaen W (2012) Fluorescent indicators based on BODIPY. Chem Soc Rev
41:1130–1172
65. Bonnier C, Machin DD, Abdi O, Koivisto BD (2013) Manipulating non-innocent π-spacers: the
challenges of using 2,6-disubstituted BODIPY cores within donor-acceptor light-harvesting
motifs. Org Biomol Chem 11:3756–3760
148
M. J. Hall and S. de la Moya