51. Yavari K, Delaunay W, De Rycke N, Reynaldo T, Aillard P, Srebro-Hooper M, Chang VY,
Muller G, Tondelier D, Geffroy B, Voituriez A, Marinetti A, Hissler M, Crassous J (2019)
Phosphahelicenes: from chiroptical and photophysical properties to OLED applications.
Chem Eur J 25:5303–5310
52. Nishigaki S, Murayama K, Shibata Y, Tanaka K (2018) Rhodium-mediated enantioselective
synthesis of a benzopicene-based phospha[9]helicene: the structure–property relationship
of triphenylene- and benzopicene-based carbo- and phosphahelicenes. Mater Chem Front
2:585–590
53. Tanaka H, Kato Y, Fujiki M, Inoue Y, Mori T (2018) Combined experimental and theoretical
study on circular dichroism and circularly polarized luminescence of configurationally robust
D 3 -symmetric triple pentahelicene. J Phys Chem A 122:7378–7384
54. He D-Q, Lu H-Y, Li M, Chen C-F (2017) Intense blue circularly polarized luminescence
from helical aromatic esters. Chem Commun 53:6093–6096
55. Fang L, Li M, Lin W-B, Chen C-F (2018) Enantiopure (P)- and (M )-3,14-bis(O-hydroxyaryl)
tetrahydrobenzo[5]helicenediols and their helicene analogues: synthesis, amplified circularly
polarized luminescence and catalytic activity in asymmetric hetero-Diels–Alder reactions.
Tetrahedron 74:7164–7172
56. Dhbaibi K, Favereau L, Srebro-Hooper M, Jean M, Vanthuyne N, Zinna F, Jamoussi B,
Di Bari L, Autschbach J, Crassous J (2018) Exciton coupling in diketopyrrolopyrrole-helicene
derivatives leads to red and near-infrared circularly polarized luminescence. Chem Sci
9:735–742
57. Satoh M, Shibata Y, Tanaka K (2018) Enantioselective synthesis of fully benzenoid single
and double carbohelicenes via gold-catalyzed intramolecular hydroarylation. Chem Eur J
24:5434–5438
58. Fang L, Li M, Lin W-B, Shen Y, Chen C-F (2018) One-pot oxidative aromatization and
dearomatization of tetrahydro[5]helicene diols: synthesis, structure, photophysical and
chiroptical properties of chiral π-extended diones. Asian J OrgChem 12:2518–2526
59. Sawada Y, Furumi S, Takai A, Takeuchi M, Noguchi K, Tanaka K (2012) Rhodium-catalyzed
enantioselective synthesis, crystal structures, and photophysical properties of helically chiral
1,1-bitriphenylenes. J Am Chem Soc 134:4080–4083
60. Oyama H, Akiyama M, Nakano K, Naito M, Nobusawa K, Nozaki K (2016) Synthesis and
properties of [7]helicene-like compounds fused with a fluorene unit. Org Lett 18:3654–3657
61. Sakai H, Shinto S, Kumar J, Araki Y, Sakanoue T, Takenobu T, Wada T, Kawai T, Hasobe T
(2015) Highly fluorescent [7]carbohelicene fused by asymmetric 1,2-dialkyl-substituted
quinoxaline for circularly polarized luminescence and electroluminescence. J Phys Chem C
119:13937–13947
62. Saleh N, Shen C, Crassous J (2014) Helicene-based transition metal complexes: synthesis,
properties and applications. Chem Sci 5:3680–3694
63. Ou-Yang J-K, Crassous J (2018) Chiral multifunctional molecules based on organometallic
helicenes: recent advances. Coord Chem Rev 376:533–547
64. Norel L, Rudolph M, Vanthuyne N, Williams JAG, Lescop C, Roussel C, Autschbach J,
Crassous J, Réau R (2010) Metallahelicenes: easily accessible helicene derivatives with large
and tunable chiroptical properties. Angew Chem Int Ed 49:99–102
65. Shen C, Anger E, Srebro M, Vanthuyne N, Deol KK, Jefferson TD, Muller G, Williams JAG,
Toupet L, Roussel C, Autschbach J, Réau R, Crassous J (2014) Straightforward access to monoand bis- cycloplatinated helicenes displaying circularly polarized phosphorescence by using
crystallization resolution methods. Chem Sci 5:1915–1927
66. Yan Z-P, Luo X-F, Liu W-Q, Wu Z-G, Liang X, Liao K, Wang Y, Zheng Y-X, Zhou L,
Zuo J-L, Pan Y, Zhang H (2019) Configurationally stable platinahelicene enantiomers
for efficient circularly polarized phosphorescent organic light-emitting diodes. Chem Eur J
25:5672–5676
67. Saleh N, Moore B, Srebro M, Vanthuyne N, Toupet L, Williams JAG, Roussel C, Deol KK,
Muller G, Autschbach J, Crassous J (2015) Acid/base-triggered switching of circularly
96
J. Crassous
Muller G, Tondelier D, Geffroy B, Voituriez A, Marinetti A, Hissler M, Crassous J (2019)
Phosphahelicenes: from chiroptical and photophysical properties to OLED applications.
Chem Eur J 25:5303–5310
52. Nishigaki S, Murayama K, Shibata Y, Tanaka K (2018) Rhodium-mediated enantioselective
synthesis of a benzopicene-based phospha[9]helicene: the structure–property relationship
of triphenylene- and benzopicene-based carbo- and phosphahelicenes. Mater Chem Front
2:585–590
53. Tanaka H, Kato Y, Fujiki M, Inoue Y, Mori T (2018) Combined experimental and theoretical
study on circular dichroism and circularly polarized luminescence of configurationally robust
D 3 -symmetric triple pentahelicene. J Phys Chem A 122:7378–7384
54. He D-Q, Lu H-Y, Li M, Chen C-F (2017) Intense blue circularly polarized luminescence
from helical aromatic esters. Chem Commun 53:6093–6096
55. Fang L, Li M, Lin W-B, Chen C-F (2018) Enantiopure (P)- and (M )-3,14-bis(O-hydroxyaryl)
tetrahydrobenzo[5]helicenediols and their helicene analogues: synthesis, amplified circularly
polarized luminescence and catalytic activity in asymmetric hetero-Diels–Alder reactions.
Tetrahedron 74:7164–7172
56. Dhbaibi K, Favereau L, Srebro-Hooper M, Jean M, Vanthuyne N, Zinna F, Jamoussi B,
Di Bari L, Autschbach J, Crassous J (2018) Exciton coupling in diketopyrrolopyrrole-helicene
derivatives leads to red and near-infrared circularly polarized luminescence. Chem Sci
9:735–742
57. Satoh M, Shibata Y, Tanaka K (2018) Enantioselective synthesis of fully benzenoid single
and double carbohelicenes via gold-catalyzed intramolecular hydroarylation. Chem Eur J
24:5434–5438
58. Fang L, Li M, Lin W-B, Shen Y, Chen C-F (2018) One-pot oxidative aromatization and
dearomatization of tetrahydro[5]helicene diols: synthesis, structure, photophysical and
chiroptical properties of chiral π-extended diones. Asian J OrgChem 12:2518–2526
59. Sawada Y, Furumi S, Takai A, Takeuchi M, Noguchi K, Tanaka K (2012) Rhodium-catalyzed
enantioselective synthesis, crystal structures, and photophysical properties of helically chiral
1,1-bitriphenylenes. J Am Chem Soc 134:4080–4083
60. Oyama H, Akiyama M, Nakano K, Naito M, Nobusawa K, Nozaki K (2016) Synthesis and
properties of [7]helicene-like compounds fused with a fluorene unit. Org Lett 18:3654–3657
61. Sakai H, Shinto S, Kumar J, Araki Y, Sakanoue T, Takenobu T, Wada T, Kawai T, Hasobe T
(2015) Highly fluorescent [7]carbohelicene fused by asymmetric 1,2-dialkyl-substituted
quinoxaline for circularly polarized luminescence and electroluminescence. J Phys Chem C
119:13937–13947
62. Saleh N, Shen C, Crassous J (2014) Helicene-based transition metal complexes: synthesis,
properties and applications. Chem Sci 5:3680–3694
63. Ou-Yang J-K, Crassous J (2018) Chiral multifunctional molecules based on organometallic
helicenes: recent advances. Coord Chem Rev 376:533–547
64. Norel L, Rudolph M, Vanthuyne N, Williams JAG, Lescop C, Roussel C, Autschbach J,
Crassous J, Réau R (2010) Metallahelicenes: easily accessible helicene derivatives with large
and tunable chiroptical properties. Angew Chem Int Ed 49:99–102
65. Shen C, Anger E, Srebro M, Vanthuyne N, Deol KK, Jefferson TD, Muller G, Williams JAG,
Toupet L, Roussel C, Autschbach J, Réau R, Crassous J (2014) Straightforward access to monoand bis- cycloplatinated helicenes displaying circularly polarized phosphorescence by using
crystallization resolution methods. Chem Sci 5:1915–1927
66. Yan Z-P, Luo X-F, Liu W-Q, Wu Z-G, Liang X, Liao K, Wang Y, Zheng Y-X, Zhou L,
Zuo J-L, Pan Y, Zhang H (2019) Configurationally stable platinahelicene enantiomers
for efficient circularly polarized phosphorescent organic light-emitting diodes. Chem Eur J
25:5672–5676
67. Saleh N, Moore B, Srebro M, Vanthuyne N, Toupet L, Williams JAG, Roussel C, Deol KK,
Muller G, Autschbach J, Crassous J (2015) Acid/base-triggered switching of circularly
96
J. Crassous