Table 10.3
(continued)
References
Target compound/initial
concentration
Water
matrix
Process conditions
parameters
Scale
Measure of degradability
Summary results
MirallesCuevas et al.
(2014a)
CBZ and IBP at
15–150
μg/L
Natural
ground
water
NF (5.2 m
2
; 50 L/h) combined with solar photoFenton, photo-Fenton like Fe
(III)u
EDDS and O
3
[O
3 ]
¼ 8.82 g O
3
h
À1
Gas
flow: 0.2 Nm
3
h
À1
[Fe
+2
]
¼ 0.1 mM
[H
2 O
2 ]
¼ 25 mg/L
Fe
2 (SO
4 )
3 :EDDS 1:2 M
Pilot
plant
Organic compounds,
DOC, TIC, ions concentrations and toxicity test
by Vibrio
fischeri
Combined process
NF/AOP over direct
treatment reduced in the
total volume to be
treated; consequently, a
lower AOP treatment
time and more efficient
reagent consumption
were observed
MirallesCuevas et al.
(2014b)
CBZ and IBP at 15
μg/L Real
municipal
wastewater
NF (5.2 m
2
; 50 L/h) combined with mild solar photoFenton and complexing
agents (EDDS and citrate)
H
2 O
2 was added 1.5 mM
Fe: Complexing agents
(1:0.5 to 1:5 M)
Pilot
plant
Organic compounds,
DOC, TIC and ions
concentrations
Pharmaceuticals were
efficiently removed
(>90%), requiring low
accumulated solar energy
(2 kJ
uv L
À1
), and low iron
and H
2 O
2 concentrations
Giannakis
et al. (2015)
CBZ and DCF at range
6–18 ng/L
Real
wastewater
Secondary treatments
coupled at UV, UV/H
2 O
2 ,
solar irradiation, Fenton,
solar photo-Fenton
Secondary treatment: Activated sludge
Moving bed bioreactor
coagulation-flocculation
Bench
Target compounds
Municipal wastewater
subjected to biological
treatment followed by
UV/H
2 O
2 resulted in the
highest elimination levels
330
E. M. Saggioro
(continued)
References
Target compound/initial
concentration
Water
matrix
Process conditions
parameters
Scale
Measure of degradability
Summary results
MirallesCuevas et al.
(2014a)
CBZ and IBP at
15–150
μg/L
Natural
ground
water
NF (5.2 m
2
; 50 L/h) combined with solar photoFenton, photo-Fenton like Fe
(III)u
EDDS and O
3
[O
3 ]
¼ 8.82 g O
3
h
À1
Gas
flow: 0.2 Nm
3
h
À1
[Fe
+2
]
¼ 0.1 mM
[H
2 O
2 ]
¼ 25 mg/L
Fe
2 (SO
4 )
3 :EDDS 1:2 M
Pilot
plant
Organic compounds,
DOC, TIC, ions concentrations and toxicity test
by Vibrio
fischeri
Combined process
NF/AOP over direct
treatment reduced in the
total volume to be
treated; consequently, a
lower AOP treatment
time and more efficient
reagent consumption
were observed
MirallesCuevas et al.
(2014b)
CBZ and IBP at 15
μg/L Real
municipal
wastewater
NF (5.2 m
2
; 50 L/h) combined with mild solar photoFenton and complexing
agents (EDDS and citrate)
H
2 O
2 was added 1.5 mM
Fe: Complexing agents
(1:0.5 to 1:5 M)
Pilot
plant
Organic compounds,
DOC, TIC and ions
concentrations
Pharmaceuticals were
efficiently removed
(>90%), requiring low
accumulated solar energy
(2 kJ
uv L
À1
), and low iron
and H
2 O
2 concentrations
Giannakis
et al. (2015)
CBZ and DCF at range
6–18 ng/L
Real
wastewater
Secondary treatments
coupled at UV, UV/H
2 O
2 ,
solar irradiation, Fenton,
solar photo-Fenton
Secondary treatment: Activated sludge
Moving bed bioreactor
coagulation-flocculation
Bench
Target compounds
Municipal wastewater
subjected to biological
treatment followed by
UV/H
2 O
2 resulted in the
highest elimination levels
330
E. M. Saggioro